Sulfurochloridic acid

ClHO3S

sulfurochloridic acid

CAS7790-94-5
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7790-94-5
EC Number
232-234-6
UN Number
1754
Index Number
016-017-00-1
PubChem CID
24638

Physical-chemical properties

Molecular Formula
ClHO3S
Molar Mass
116.53 g/mol
IUPAC Name
sulfurochloridic acid

Chemical Identifiers

InChI
InChI=1S/ClHO3S/c1-5(2,3)4/h(H,2,3,4)
InChI Key
XTHPWXDJESJLNJ-UHFFFAOYSA-N

Overview

Sulfurochloridic acid (CAS 7790-94-5) is a highly corrosive inorganic acid with strong oxidizing and chlorinating properties. Also known by its IUPAC designation, this chemical compound with molecular formula ClHO3S represents a critical intermediate in various industrial chemical processes. This colorless to pale yellow liquid demonstrates exceptional reactivity due to its dual nature as both a sulfur-containing acid and a chlorine donor. With a molecular weight of 116.53 g/mol and EC number 232-234-6, sulfurochloridic acid requires careful handling protocols due to its classification as a skin corrosive substance (Skin Corr. 1A) and specific target organ toxicant (STOT SE 3). The associated GHS pictograms GHS05 and GHS07, along with the danger signal word, emphasize the serious safety considerations required when working with this material. The compound's primary industrial applications include its use as a chlorinating agent in organic synthesis, where it serves as an effective reagent for introducing chlorine atoms into organic molecules. It also functions as an intermediate in the production of various sulfonyl chlorides and finds application in specialized analytical chemistry procedures. Unlike more commonly handled amines such as phenylmethanamine or N-cyclohexylcyclohexanamine, sulfurochloridic acid requires specialized storage conditions and enhanced safety protocols due to its corrosive nature. Transportation falls under ADR Class 8, reflecting its corrosive properties and requiring appropriate packaging and labeling for safe handling throughout the supply chain. The compound's high reactivity necessitates storage in compatible containers away from moisture and incompatible materials. OYSI maintains reliable supply chains for sulfurochloridic acid, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1754
ADR Class8
Packing GroupI
Tunnel CodeE
Proper Shipping NameChlorsulfonsäure, frei von Schwefeltrioxid
Marine PollutantNo

Frequently Asked Questions

What is sulfurochloridic acid?

Sulfurochloridic acid is a highly corrosive inorganic compound with the molecular formula ClHO3S and CAS number 7790-94-5. This chemical substance has a molecular weight of 116.53 g/mol and is classified as a dangerous material requiring special handling precautions. It belongs to the skin corrosion category 1A and specific target organ toxicity category 3, making it essential to follow strict safety protocols during use and storage.

What are the physicochemical properties of sulfurochloridic acid?

Sulfurochloridic acid is a liquid chemical compound that typically appears as a colorless to slightly yellow solution. It is highly soluble in water and exhibits strong acidic properties due to its chemical structure. The substance has corrosive characteristics and can release harmful vapors. Its density and boiling point vary depending on concentration, but it generally maintains stability under normal storage conditions when properly contained.

What is sulfurochloridic acid used for?

Sulfurochloridic acid is primarily used in industrial chemical processes as a strong acid catalyst and reagent. It finds applications in organic synthesis reactions, particularly in sulfonation processes and as an intermediate in pharmaceutical manufacturing. The compound is also utilized in analytical chemistry laboratories for specific testing procedures and in the production of specialty chemicals where its unique acidic and chlorinating properties are required.

How to handle sulfurochloridic acid safely?

Sulfurochloridic acid requires extensive personal protective equipment including acid-resistant gloves, chemical-resistant clothing, and face protection with respiratory equipment. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Personnel should be trained in proper handling techniques and emergency procedures. All equipment must be compatible with corrosive substances, and emergency shower and eyewash stations should be readily accessible in work areas.

How to store sulfurochloridic acid correctly?

Sulfurochloridic acid must be stored in corrosion-resistant containers made of appropriate materials such as PTFE or glass-lined vessels. Storage areas should be cool, dry, and well-ventilated, away from incompatible materials including metals, bases, and organic compounds. Secondary containment is essential to prevent environmental contamination. Storage facilities must comply with local regulations for corrosive substances and include proper ventilation systems and spill control measures.

What to do in case of contact with sulfurochloridic acid?

Immediate removal from exposure and fresh air access are critical first steps for sulfurochloridic acid contact. For skin contact, rinse immediately with copious amounts of water for at least 15 minutes while removing contaminated clothing. Eye contact requires immediate irrigation with water or saline solution for at least 15 minutes. Seek immediate medical attention for all exposure routes. Never induce vomiting if ingested and provide medical personnel with the safety data sheet.

How to dispose of sulfurochloridic acid appropriately?

Sulfurochloridic acid disposal must follow hazardous waste regulations and cannot be disposed of through regular waste streams. The substance requires neutralization by qualified professionals using appropriate neutralizing agents under controlled conditions. Disposal must be conducted through licensed hazardous waste management companies that specialize in corrosive materials. Empty containers also require special handling as they may retain corrosive residues and are subject to hazardous waste regulations.

How to transport sulfurochloridic acid?

Sulfurochloridic acid is classified under ADR Class 8 (corrosive substances) Packing Group I, indicating high danger level for transport. Specialized corrosion-resistant packaging and proper labeling with GHS pictograms GHS05 and GHS07 are mandatory. Transport vehicles must comply with ADR regulations for corrosive materials, including proper ventilation and emergency equipment. Only trained personnel with dangerous goods certification should handle the transportation, and proper documentation must accompany all shipments.

Is sulfurochloridic acid subject to specific regulations?

Sulfurochloridic acid is subject to REACH registration requirements and CLP classification as a corrosive substance with skin corrosion 1A and STOT SE 3 classifications. While not classified as an SVHC substance, it requires proper hazard communication through safety data sheets and appropriate labeling. Industrial users must implement risk management measures and comply with occupational exposure limits. Import and use may require additional permits depending on specific national regulations within EU member states.

Where to buy sulfurochloridic acid in Europe?

Sulfurochloridic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial and laboratory customers. OYSI provides this corrosive substance with proper documentation, safety data sheets, and regulatory compliance support throughout Europe. As a professional chemical distributor, OYSI ensures appropriate packaging, handling, and delivery services for hazardous materials while maintaining quality standards and regulatory compliance for industrial chemical applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.