Chloro thiohypochlorite

Cl2S

chloro thiohypochlorite

CAS10545-99-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for Chloro thiohypochlorite

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
10545-99-0
EC Number
234-129-0
UN Number
1828
Index Number
016-013-00-X
PubChem CID
25353

Physical-chemical properties

Molecular Formula
Cl2S
Molar Mass
102.97 g/mol
IUPAC Name
chloro thiohypochlorite

Chemical Identifiers

InChI
InChI=1S/Cl2S/c1-3-2
InChI Key
FWMUJAIKEJWSSY-UHFFFAOYSA-N

Overview

Chloro thiohypochlorite (CAS 10545-99-0) is an inorganic sulfur-chlorine compound with corrosive properties and significant chemical reactivity. This specialized chemical compound, with the molecular formula Cl2S and a molecular weight of 102.97 g/mol, represents an important class of halogenated sulfur compounds used in various industrial applications. The substance is classified under EC number 234-129-0 and falls within ADR transport class 8, reflecting its corrosive nature and requiring careful handling protocols. The compound exhibits multiple hazard classifications including skin corrosion (Skin Corr. 1B), specific target organ toxicity following single exposure (STOT SE 3), and acute aquatic toxicity (Aquatic Acute 1). These properties are indicated by GHS pictograms GHS05, GHS07, and GHS09, with a danger signal word emphasizing the need for appropriate safety measures during handling and storage. The corrosive characteristics of chloro thiohypochlorite distinguish it from related compounds such as N-cyclohexylcyclohexanamine, which has different reactivity profiles and applications. Industrial applications of chloro thiohypochlorite primarily include its use as a chemical intermediate in organic synthesis reactions, particularly in processes requiring selective chlorination or sulfur incorporation. The compound also finds application in specialized water treatment processes where its oxidizing properties are beneficial, and serves as a reagent in certain analytical chemistry procedures requiring precise halogen-sulfur interactions. The reactive nature of this compound, similar to other specialized reagents like 2-(2-carbonochloridoyloxyethoxy)ethyl carbonochloridate, makes it valuable for specific synthetic pathways in pharmaceutical and fine chemical manufacturing. OYSI maintains reliable supply chains for chloro thiohypochlorite, ensuring consistent availability for European industrial customers requiring this specialized chemical reagent.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1828
ADR Class8
Packing GroupI
Tunnel CodeE
Proper Shipping NameSchwefeldichlorid
Marine PollutantNo

Frequently Asked Questions

What is chloro thiohypochlorite?

Chloro thiohypochlorite is an inorganic chemical compound with the molecular formula Cl2S and CAS number 10545-99-0. This compound has a molecular weight of 102.97 g/mol and belongs to the family of sulfur-chlorine compounds. It is classified as a hazardous substance with corrosive properties and poses risks to skin contact and aquatic environments. The compound requires careful handling due to its dangerous classification under GHS regulations with multiple hazard classes including skin corrosion and specific target organ toxicity.

What are the physicochemical properties of chloro thiohypochlorite?

Chloro thiohypochlorite is a sulfur-chlorine compound with the molecular formula Cl2S and a molecular weight of 102.97 g/mol. As a reactive inorganic compound containing both chlorine and sulfur atoms, it typically exists as a volatile substance at ambient conditions. The compound exhibits strong oxidizing properties characteristic of hypochlorite derivatives and shows high reactivity due to the presence of active chlorine. Its chemical structure makes it unstable in aqueous solutions and sensitive to light and heat.

What is chloro thiohypochlorite used for?

Chloro thiohypochlorite is primarily used as a specialized oxidizing agent and disinfectant in industrial applications. The compound serves as an intermediate in chemical synthesis processes, particularly in the production of other sulfur-chlorine compounds. Its strong oxidizing properties make it valuable in water treatment applications and as a bleaching agent in specific industrial processes. Due to its hazardous nature and specialized properties, its use is typically limited to professional and industrial settings where proper safety measures can be implemented.

How to handle chloro thiohypochlorite safely?

Chloro thiohypochlorite requires extensive safety precautions due to its corrosive nature and classification as Skin Corr. 1B. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation exposure. Emergency eyewash stations and safety showers should be readily accessible. Handle containers carefully to prevent spills and avoid contact with incompatible materials.

How to store chloro thiohypochlorite correctly?

Chloro thiohypochlorite must be stored in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. The compound should be kept in tightly sealed, corrosion-resistant containers to prevent moisture absorption and decomposition. Storage areas must be equipped with appropriate containment measures and separated from incompatible materials such as organic compounds, reducing agents, and metals. Access should be restricted to trained personnel only, and storage facilities should comply with local regulations for corrosive substances.

What to do in case of contact with chloro thiohypochlorite?

Immediate action is required for any contact with chloro thiohypochlorite due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush the affected area with large amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical help if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of chloro thiohypochlorite appropriately?

Chloro thiohypochlorite waste must be disposed of according to local and national hazardous waste regulations due to its corrosive properties and environmental hazard classification (Aquatic Acute 1). The compound cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal companies. Small quantities should be neutralized by trained personnel using appropriate neutralizing agents before disposal. Empty containers must be properly cleaned and disposed of as hazardous waste. Consult local environmental authorities for specific disposal requirements.

How to transport chloro thiohypochlorite?

Chloro thiohypochlorite is classified under ADR as Class 8 (corrosive substances), Packing Group I, indicating high danger level during transport. Transportation must comply with dangerous goods regulations including proper packaging in UN-approved containers, appropriate labeling with corrosive hazard symbols, and accompanying transport documents. Vehicles must be equipped with appropriate emergency equipment and drivers must hold valid dangerous goods transport certificates. The shipment requires proper segregation from incompatible materials and adherence to quantity limitations for different transport modes.

Is chloro thiohypochlorite subject to specific regulations?

Chloro thiohypochlorite is subject to various European and international chemical regulations including REACH registration requirements and CLP classification obligations. The compound is classified under multiple hazard categories (STOT SE 3, Skin Corr. 1B, Aquatic Acute 1) requiring specific labeling with GHS pictograms GHS05, GHS07, and GHS09. It is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Users must comply with occupational safety regulations, environmental protection laws, and transport regulations for dangerous goods.

Where to buy chloro thiohypochlorite in Europe?

Chloro thiohypochlorite is available through specialized chemical distributors in Europe, including OYSI, a professional distributor of technical chemicals. As a hazardous substance requiring proper handling and regulatory compliance, it is typically sold only to qualified industrial customers with appropriate facilities and safety measures. Purchases may require verification of intended use and compliance with relevant regulations. Contact OYSI or other certified chemical suppliers for availability, technical specifications, and regulatory documentation required for your specific application.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.