GHS07 – Exclamation Mark
Harmful. May cause irritation, allergic reactions, or drowsiness.
Hazard Classes
- Acute toxicity cat. 4
- Skin irritation
- Eye irritation
- Skin sensitization
Associated H-Statements
The following hazard statements (H-Statements) are associated with this pictogram:
H302Harmful if swallowed.H303May be harmful if swallowed.H312Harmful in contact with skin.H313May be harmful in contact with skin.H315Causes skin irritation.H316Causes mild skin irritation.H317May cause an allergic skin reaction.H319Causes serious eye irritation.H320Causes eye irritation.H332Harmful if inhaled.H333May be harmful if inhaled.H335May cause respiratory irritation.H336May cause drowsiness or dizziness.H420Harms public health and the environment by destroying ozone in the upper atmosphere.
Affected Substances
The following substances in our database carry the pictogram GHS07:
(1,2-dibromo-2,2-dichloroethyl) dimethyl phosphateCAS 300-76-5C4H7Br2Cl2O4P(1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylateCAS 7696-12-0C19H25NO4(1E)-2-(ethylcarbamoylamino)-N-methoxy-2-oxoethanimidoyl cyanideCAS 57966-95-7C7H10N4O3(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-eneCAS 57-74-9C10H6Cl8(1R)-1-[(2R,3aR,5R,6S,6aR)-6-hydroxy-2-(trichloromethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diolCAS 15879-93-3C8H11Cl3O6(1S,2R,4R)-1-methyl-2-[(2-methylphenyl)methoxy]-4-propan-2-yl-7-oxabicyclo[2.2.1]heptaneCAS 87818-31-3C18H26O2(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,4'-cyclohex-2-ene]-1'-oneCAS 133636-82-5C15H22O(1S,6R,13S)-16,17-dimethoxy-6-prop-1-en-2-yl-2,7,20-trioxapentacyclo[11.8.0.03,11.04,8.014,19]henicosa-3(11),4(8),9,14,16,18-hexaen-12-oneCAS 83-79-4C23H22O6(2-butan-2-yl-4,6-dinitrophenyl) 3-methylbut-2-enoateCAS 485-31-4C15H18N2O6(2-butan-2-yl-4,6-dinitrophenyl) acetateCAS 2813-95-8C12H14N2O6(2-butan-2-ylphenyl) N-methylcarbamateCAS 3766-81-2C12H17NO2(2-butyl-5-nitro-1-benzofuran-3-yl)-[4-[3-(dibutylamino)propoxy]phenyl]methanoneCAS 141645-23-0C30H40N2O5(2-methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl) 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylateCAS 84030-86-4C19H26O3(2-methyl-4-oxo-3-prop-2-ynylcyclopent-2-en-1-yl) 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylateCAS 23031-36-9C19H24O3(2-nitrophenyl) (E)-but-2-enoate;nitrous acid;octaneCAS 39300-45-3C18H28N2O6(2-propan-2-ylphenyl) N-methylcarbamateCAS 2631-40-5C11H15NO2(2,2-dimethyl-3H-1-benzofuran-7-yl) N-(dibutylamino)sulfanyl-N-methylcarbamateCAS 55285-14-8C20H32N2O3S(2,2-dimethyl-3H-1-benzofuran-7-yl) N-[butoxycarbonyl(methyl)amino]sulfanyl-N-methylcarbamateCAS 65907-30-4C18H26N2O5S(2,4-dichlorophenoxy)-diethoxy-sulfanylidene-lambda5-phosphaneCAS 97-17-6C10H13Cl2O3PS(2,4-dinitro-6-octan-3-ylphenyl) methyl carbonate;(2,4-dinitro-6-octan-4-ylphenyl) methyl carbonateCAS 8069-76-9C32H44N4O14(2,6-dibromo-4-cyanophenyl) heptanoateCAS 56634-95-8C14H15Br2NO2(2,6-dibromo-4-cyanophenyl) octanoateCAS 1689-99-2C15H17Br2NO2(2,6-dichloro-4-methylphenoxy)-dimethoxy-sulfanylidene-lambda5-phosphaneCAS 57018-04-9C9H11Cl2O3PS(2,6-dinitro-4-octan-3-ylphenyl) methyl carbonate;(2,6-dinitro-4-octan-4-ylphenyl) methyl carbonateCAS 63919-26-6C32H44N4O14(2E)-2-[2-[(2,5-dimethylphenoxy)methyl]phenyl]-2-methoxyimino-N-methylacetamideCAS 149961-52-4C19H22N2O3(2E)-3,7-dimethylocta-2,6-dienalCAS 5392-40-5C10H16O(2S,3S)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pentan-3-olCAS 76738-62-0C15H20ClN3O(2S,6R)-1-(3-chloropropyl)-2,6-dimethylpiperidine;hydrochlorideCAS 63645-17-0C10H21Cl2N(2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholineCAS 67564-91-4C20H33NO(2S)-2-hydroxy-2-(3-phenoxyphenyl)acetonitrileCAS 61826-76-4C14H11NO2(3-azaniumyl-4-methylphenyl)azanium sulfateCAS 65321-67-7C7H12N2O4S(3-chloro-4-nitrophenoxy)-dimethoxy-sulfanylidene-lambda5-phosphaneCAS 500-28-7C8H9ClNO5PS(3-dodecyl-1,4-dioxonaphthalen-2-yl) acetateCAS 57960-19-7C24H32O4(3-methylphenyl) N-methylcarbamateCAS 1129-41-5C9H11NO2(3-methylsulfanylbutan-2-ylideneamino) N-methylcarbamateCAS 34681-10-2C7H14N2O2S(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylateCAS 52645-53-1C21H20Cl2O3(3,4-dimethylphenyl) N-methylcarbamateCAS 2425-10-7C10H13NO2(4-bromo-2,5-dichlorophenoxy)-diethoxy-sulfanylidene-lambda5-phosphaneCAS 4824-78-6C10H12BrCl2O3PS(4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-lambda5-phosphaneCAS 2104-96-3C8H8BrCl2O3PS(4-bromo-2,5-dichlorophenoxy)-methoxy-phenyl-sulfanylidene-lambda5-phosphaneCAS 21609-90-5C13H10BrCl2O2PS(4-chlorophenyl) 4-chlorobenzenesulfonateCAS 80-33-1C12H8Cl2O3S(4-chlorophenyl) benzenesulfonateCAS 80-38-6C12H9ClO3S(4-cyano-2,6-diiodophenyl) octanoateCAS 3861-47-0C15H17I2NO2(4-methyl-8-methylidene-2-adamantyl) acetateCAS 122760-85-4C14H20O2(4-methylphenyl) 4-chlorobenzoateCAS 15024-10-9C14H11ClO2(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuideCAS 178233-72-2C40H18BF20I(4aS,7aS)-6-benzyl-1,2,3,4,4a,5,7,7a-octahydropyrrolo[3,4-b]pyridineCAS 151213-39-7C14H20N2(4R)-1-methyl-4-prop-1-en-2-ylcyclohexeneCAS 5989-27-5C10H16(5-acetyl-2-acetyloxyphenyl)methyl acetateCAS 24085-06-1C13H14O5(5-amino-2-butyl-1-benzofuran-3-yl)-[4-[3-(dibutylamino)propoxy]phenyl]methanone;oxalic acidCAS 500791-70-8C32H44N2O7
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Frequently Asked Questions
What does GHS07 (Exclamation Mark) mean?
The GHS pictogram GHS07 (Exclamation Mark) identifies substances that present certain hazards according to CLP regulation. It is used on labels and safety data sheets of chemical products.
What hazards does GHS07 indicate?
GHS07 indicates specific hazard classes to which 14 different H-Statements are assigned. The exact hazard classes can be found in the "Hazard Classes" section on this page.
Which substances carry GHS07?
In our database, 1107 substances carry the pictogram GHS07. The complete list can be found in the "Affected Substances" section on this page.
According to CLP Regulation (EC) No 1272/2008. Information is for guidance only – for legally binding data, refer to the Safety Data Sheet (SDS).