Potassium hydrogen sulfate
HKO4S
potassium hydrogen sulfate
Consulting for Potassium hydrogen sulfate
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Identification
- CAS Number
- 7646-93-7
- EC Number
- 231-594-1
- UN Number
- 2509
- Index Number
- 016-056-00-4
- PubChem CID
- 516920
Physical-chemical properties
- Molecular Formula
- HKO4S
- Molar Mass
- 136.17 g/mol
- IUPAC Name
- potassium hydrogen sulfate
Chemical Identifiers
- InChI
- InChI=1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
- InChI Key
- CHKVPAROMQMJNQ-UHFFFAOYSA-M
Overview
Potassium hydrogen sulfate (CAS 7646-93-7) is an inorganic acid salt with strong acidic properties and high solubility in water. This white crystalline compound, also known by its EC number 231-594-1, serves as a crucial intermediate in various industrial processes requiring controlled acidic conditions. With a molecular formula of HKO4S and molecular weight of 136.17 g/mol, potassium hydrogen sulfate exhibits unique bifunctional characteristics, acting both as a source of potassium ions and as an acid donor in aqueous solutions. The substance presents significant safety considerations due to its corrosive nature, classified under GHS pictograms GHS05 and GHS07 with a "Danger" signal word. Its classification as Skin Corr. 1B indicates severe skin corrosion potential, while STOT SE 3 designation warns of specific target organ toxicity. Transportation falls under ADR Class 8, reflecting its corrosive properties that require specialized handling protocols. In industrial applications, potassium hydrogen sulfate finds extensive use in analytical chemistry as a flux for decomposing silicate minerals and refractory materials at elevated temperatures. The compound serves as an acidifying agent in various manufacturing processes and acts as an intermediate in potassium sulfate production. Its controlled acidic properties make it valuable in specialized synthesis reactions where traditional mineral acids like hydrogen chloride might prove too aggressive or unsuitable. The compound's versatility extends to applications requiring precise pH control, where its buffering capacity provides advantages over stronger acids. Unlike more volatile corrosive substances such as tribromophosphane, potassium hydrogen sulfate offers stability under standard storage conditions while maintaining its reactive properties when needed. OYSI maintains reliable supply chains for potassium hydrogen sulfate, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.
Safety & Classification
STOT SE 3; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2509 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Kaliumhydrogensulfat, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is potassium hydrogen sulfate?
Potassium hydrogen sulfate is an inorganic chemical compound with the formula HKO4S and CAS number 7646-93-7. This acidic salt has a molecular weight of 136.17 g/mol and is classified as a corrosive substance. It appears as white crystalline solid and is highly soluble in water, forming acidic solutions. The compound is also known as potassium bisulfate and serves as an important industrial chemical for various applications requiring acidic properties.
What are the physicochemical properties of potassium hydrogen sulfate?
Potassium hydrogen sulfate is a white crystalline solid at room temperature with excellent water solubility, forming strongly acidic solutions. The compound has a molecular weight of 136.17 g/mol and is odorless. It is hygroscopic, meaning it absorbs moisture from air. When dissolved, it releases hydrogen ions, making solutions corrosive. The substance is stable under normal conditions but can decompose at high temperatures, releasing sulfur oxides.
What is potassium hydrogen sulfate used for?
Potassium hydrogen sulfate is used primarily as an acidifying agent in various industrial processes and laboratory applications. It serves as a flux in metallurgy, helping to remove oxides from metal surfaces during welding and soldering. The compound is also employed in analytical chemistry for sample digestion and pH adjustment. Additionally, it finds applications in the production of fertilizers, as a food additive for pH control, and in certain cleaning formulations where acidic properties are required.
How to handle potassium hydrogen sulfate safely?
Potassium hydrogen sulfate must be handled with appropriate personal protective equipment due to its corrosive nature (Skin Corr. 1B classification). Wear chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Ensure adequate ventilation in work areas and avoid inhalation of dust particles. Use non-sparking tools and equipment. Always work in well-ventilated areas and have eyewash stations and safety showers readily available. Handle containers carefully to prevent spills and dust generation.
How to store potassium hydrogen sulfate correctly?
Potassium hydrogen sulfate should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and store in original packaging or compatible containers made of corrosion-resistant materials. Separate from incompatible materials such as strong bases, metals, and organic compounds. Protect from moisture due to its hygroscopic nature. Ensure storage areas have appropriate spill containment measures and maintain temperatures below 25°C for optimal stability.
What to do in case of contact with potassium hydrogen sulfate?
In case of skin contact with potassium hydrogen sulfate, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes and seek medical attention promptly. If inhaled, move the person to fresh air and seek medical advice if respiratory irritation occurs. In case of ingestion, rinse mouth and drink water, but do not induce vomiting. Always seek medical attention for significant exposures.
How to dispose of potassium hydrogen sulfate properly?
Potassium hydrogen sulfate must be disposed of according to local, regional, and national waste regulations as it is classified as hazardous waste. Do not dispose of in regular trash or pour down drains. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities can be neutralized carefully with appropriate bases under controlled conditions by trained personnel, but this should only be done following proper procedures. Always consult with environmental authorities for specific disposal requirements in your region.
How to transport potassium hydrogen sulfate?
Potassium hydrogen sulfate is classified as ADR Class 8 (corrosive substances) with Packing Group II, indicating moderate danger level during transport. It requires appropriate hazardous goods packaging, labeling, and documentation according to ADR regulations. Use UN-approved containers and display proper hazard labels including corrosive symbols. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers need ADR certification for dangerous goods transport. Ensure compliance with routing restrictions and emergency response procedures during transportation.
Is potassium hydrogen sulfate subject to specific regulations?
Potassium hydrogen sulfate is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification as a corrosive substance with danger signal word. It is not listed as an SVHC (Substance of Very High Concern). The compound requires safety data sheets and proper hazard communication under GHS, displaying pictograms GHS05 and GHS07. Industrial users must comply with occupational safety regulations and may need permits for storage and use depending on quantities and local requirements.
Where to buy potassium hydrogen sulfate in Europe?
Potassium hydrogen sulfate is available through OYSI, a European distributor specializing in technical chemicals for industrial applications. OYSI provides quality chemical products with proper documentation, safety data sheets, and regulatory compliance support throughout Europe. As a professional chemical distributor, OYSI ensures reliable supply chains and technical support for industrial customers. Contact OYSI directly for pricing, availability, packaging options, and delivery information specific to your requirements and location within Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.