Sodium 2-phenylphenolate

C12H9NaO

sodium 2-phenylphenolate

CAS132-27-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
132-27-4
EC Number
205-055-6
UN Number
3077
Index Number
604-021-00-1
PubChem CID
23675735

Physical-chemical properties

Molecular Formula
C12H9NaO
Molar Mass
192.19 g/mol
IUPAC Name
sodium 2-phenylphenolate

Chemical Identifiers

InChI
InChI=1S/C12H10O.Na/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;/h1-9,13H;/q;+1/p-1
InChI Key
KSQXVLVXUFHGJQ-UHFFFAOYSA-M

Overview

Sodium 2-phenylphenolate (CAS 132-27-4) is an aromatic sodium salt with antimicrobial and preservative properties widely used in industrial applications. This organic sodium compound, also known by its IUPAC designation sodium 2-phenylphenolate, represents an important class of phenolic preservatives utilized across various industrial sectors. With the molecular formula C12H9NaO and a molecular weight of 192.19 g/mol, this white to off-white crystalline substance exhibits excellent solubility in water and polar solvents, making it particularly valuable for aqueous formulations requiring antimicrobial protection. The compound's phenolic structure provides potent biocidal activity against bacteria, fungi, and other microorganisms, while its sodium salt form ensures enhanced stability and handling characteristics compared to its free acid counterpart. Safety considerations are paramount when working with sodium 2-phenylphenolate, as it carries acute toxicity classification (Acute Tox. 4), skin irritation potential (Skin Irrit. 2), and serious eye damage classification (Eye Dam. 1). The substance also presents environmental concerns with its Aquatic Acute 1 classification, requiring careful handling and disposal protocols. Transport regulations classify it under ADR Class 9 (miscellaneous dangerous substances). Primary industrial applications include use as a preservative in metalworking fluids, where it prevents microbial growth and extends fluid life, and as an antimicrobial agent in industrial cleaning formulations. The compound also finds application in textile processing as a biocide for fabric treatments. Unlike simpler compounds such as benzene-1,4-diol, sodium 2-phenylphenolate offers superior antimicrobial efficacy in alkaline conditions. OYSI maintains reliable supply chains for sodium 2-phenylphenolate to support European industrial customers' technical requirements.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNatriumbiphenyl-2-yloxid
Marine PollutantNo

Frequently Asked Questions

What is sodium 2-phenylphenolate?

Sodium 2-phenylphenolate is an organic sodium salt derived from 2-phenylphenol, with the molecular formula C12H9NaO and CAS number 132-27-4. This chemical compound has a molecular weight of 192.19 g/mol and appears as a white to off-white crystalline powder. It belongs to the phenolic compound family and exhibits antimicrobial properties, making it valuable in various industrial applications requiring preservation and disinfection capabilities.

What are the physicochemical properties of sodium 2-phenylphenolate?

Sodium 2-phenylphenolate is a white to off-white crystalline solid at room temperature with good water solubility due to its ionic nature. The compound is stable under normal conditions but may decompose when exposed to strong acids or high temperatures. It has a characteristic phenolic odor and exhibits hygroscopic properties, meaning it readily absorbs moisture from the atmosphere. The substance maintains its stability in alkaline conditions.

What is sodium 2-phenylphenolate used for?

Sodium 2-phenylphenolate is primarily used as a antimicrobial agent and preservative in various industrial applications. It serves as an effective biocide in water treatment systems, metalworking fluids, and industrial cleaning formulations. The compound is also utilized in the production of disinfectants and sanitizers for industrial facilities. Additionally, it finds application in textile processing and as a preservation agent in certain industrial formulations.

How to handle sodium 2-phenylphenolate safely?

Sodium 2-phenylphenolate requires careful handling due to its classification as Acute Tox. 4, Skin Irrit. 2, and Eye Dam. 1. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles with side shields, and protective clothing. Ensure adequate ventilation in work areas and avoid generating dust. Never eat, drink, or smoke when handling this substance. Wash hands thoroughly after handling and before eating or drinking.

How to store sodium 2-phenylphenolate correctly?

Sodium 2-phenylphenolate should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed to prevent moisture absorption and contamination. Store away from incompatible materials such as strong acids, oxidizing agents, and food products. Maintain storage temperatures below 25°C and ensure proper labeling according to GHS requirements. Use appropriate containment measures to prevent environmental release.

What to do in case of contact with sodium 2-phenylphenolate?

Sodium 2-phenylphenolate exposure requires immediate action due to its irritant and toxic properties. For skin contact, immediately remove contaminated clothing and wash affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes and seek medical attention due to potential eye damage. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of sodium 2-phenylphenolate appropriately?

Sodium 2-phenylphenolate disposal must comply with local environmental regulations due to its Aquatic Acute 1 classification. The substance cannot be disposed of in regular waste streams and requires treatment as hazardous waste. Contact licensed waste disposal companies for proper handling and disposal. Small quantities should be neutralized and treated according to local authority guidelines. Never discharge into sewers, waterways, or soil as it poses significant environmental risks to aquatic organisms.

How to transport sodium 2-phenylphenolate?

Sodium 2-phenylphenolate is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transport purposes. This classification requires specific packaging, labeling, and documentation according to ADR regulations. Containers must be properly sealed, labeled with appropriate hazard markings including GHS pictogrammes GHS05, GHS07, and GHS09. Transport vehicles must carry appropriate emergency equipment and documentation. Professional carriers experienced in chemical transport should handle shipments.

Is sodium 2-phenylphenolate subject to specific regulations?

Sodium 2-phenylphenolate is regulated under European REACH and CLP regulations, requiring registration for commercial use above specified tonnages. The substance is not currently listed as an SVHC (Substance of Very High Concern), but its hazard classifications require compliance with worker protection standards. Users must maintain safety data sheets, implement risk management measures, and ensure proper classification and labeling. Industrial users may need to notify relevant authorities depending on usage volumes.

Where to buy sodium 2-phenylphenolate in Europe?

Sodium 2-phenylphenolate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this substance with complete regulatory documentation, safety data sheets, and technical support. As a professional chemical distributor, OYSI ensures compliance with all European regulations including REACH registration requirements. Contact OYSI directly for availability, technical specifications, and pricing information for your specific industrial application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.