(E)-3-phenylprop-2-enal

C9H8O

CAS104-55-2
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Warning

Consulting for (E)-3-phenylprop-2-enal

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
104-55-2
EC Number
203-213-9
UN Number
Index Number
606-155-00-6
PubChem CID
637511

Physical-chemical properties

Molecular Formula
C9H8O
Molar Mass
132.16 g/mol
IUPAC Name
(E)-3-phenylprop-2-enal

Chemical Identifiers

InChI
InChI=1S/C9H8O/c10-8-4-7-9-5-2-1-3-6-9/h1-8H/b7-4+
InChI Key
KJPRLNWUNMBNBZ-QPJJXVBHSA-N

Overview

(E)-3-phenylprop-2-enal (CAS 104-55-2) is an α,β-unsaturated aldehyde featuring a phenyl group with characteristic aromatic properties and aldehyde reactivity. This aromatic aldehyde, also known by its IUPAC designation (E)-3-phenylprop-2-enal, represents a significant compound in organic chemistry with the molecular formula C9H8O and a molecular weight of 132.16 g/mol. The compound features a conjugated system combining a benzene ring with an α,β-unsaturated aldehyde functionality, which contributes to its unique chemical behavior and industrial applications. From a safety perspective, (E)-3-phenylprop-2-enal is classified under the GHS system with the pictogram GHS07 and carries a "Warning" signal word. The primary hazard classification is Skin Sens. 1A, indicating its potential as a skin sensitizer category 1A, requiring appropriate handling precautions and personal protective equipment during industrial processing and laboratory work. The compound's structural characteristics make it valuable in several industrial applications, particularly in the fragrance and flavor industry where its aromatic properties are utilized for creating specific scent profiles. Additionally, it serves as an important intermediate in organic synthesis, enabling the production of various pharmaceutical and specialty chemical compounds. The α,β-unsaturated aldehyde structure also makes it useful in polymer chemistry applications. Unlike simpler compounds such as 4-nitrophenol which primarily serves as a chemical intermediate, (E)-3-phenylprop-2-enal offers unique aromatic characteristics that expand its application range. The compound's reactivity profile differs significantly from materials like tetrachlorosilane, positioning it specifically within organic synthesis and aromatic chemistry applications. OYSI maintains reliable supply chains for (E)-3-phenylprop-2-enal, ensuring consistent availability for European industrial customers requiring this specialized aromatic aldehyde.

Safety & Classification

Warning
Classification:

Skin Sens. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is (E)-3-phenylprop-2-enal?

(E)-3-phenylprop-2-enal is an organic compound with the molecular formula C9H8O and CAS number 104-55-2. Also known as cinnamaldehyde, this aromatic aldehyde has a molecular weight of 132.16 g/mol. It belongs to the phenylpropene family and is characterized by its conjugated system linking a benzene ring to an aldehyde group through a double bond in E-configuration.

What are the physicochemical properties of (E)-3-phenylprop-2-enal?

(E)-3-phenylprop-2-enal is a pale yellow to colorless liquid at room temperature with a characteristic sweet, cinnamon-like odor. The compound has a density of approximately 1.05 g/cm³ and a boiling point around 248°C. It is slightly soluble in water but readily dissolves in organic solvents like ethanol, ether, and oils. The compound is sensitive to light and air oxidation.

What is (E)-3-phenylprop-2-enal used for?

(E)-3-phenylprop-2-enal is primarily used in the fragrance and flavor industry as a key component in cinnamon flavoring and perfumery. It serves as an intermediate in pharmaceutical synthesis and is employed in the production of various chemicals including α-amylcinnamaldehyde. The compound also finds applications in cosmetics, food additives, and as a starting material for organic synthesis reactions.

How to handle (E)-3-phenylprop-2-enal safely?

(E)-3-phenylprop-2-enal requires careful handling as it is classified as Skin Sens. 1A (skin sensitizer). Operators must wear appropriate personal protective equipment including nitrile gloves, safety goggles, and protective clothing. Ensure adequate ventilation to avoid inhalation exposure. Avoid direct skin and eye contact. Work in well-ventilated areas or under fume hoods when handling larger quantities.

How to store (E)-3-phenylprop-2-enal correctly?

(E)-3-phenylprop-2-enal should be stored in tightly sealed containers in a cool, dry, and dark place away from heat sources and direct sunlight. The storage temperature should be below 25°C to prevent degradation. Keep away from strong oxidizing agents and bases. Use amber glass bottles or other light-protective containers to minimize photodegradation. Ensure proper labeling and maintain inventory rotation.

What to do in case of contact with (E)-3-phenylprop-2-enal?

In case of skin contact with (E)-3-phenylprop-2-enal, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air. Given its skin sensitizing properties, monitor for allergic reactions and consult a physician if symptoms develop.

How to dispose of (E)-3-phenylprop-2-enal appropriately?

(E)-3-phenylprop-2-enal waste must be disposed of according to local and national hazardous waste regulations. The compound should not be discharged into drains, sewers, or the environment. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities can often be incinerated at high temperatures in appropriate facilities. Maintain proper documentation of waste disposal activities as required by regulations.

How to transport (E)-3-phenylprop-2-enal?

(E)-3-phenylprop-2-enal transport requirements depend on quantity and local regulations. While not specifically classified under ADR dangerous goods regulations, it should be transported in properly labeled, leak-proof containers. Ensure compliance with GHS labeling requirements including the Warning signal word and GHS07 pictogram. Use appropriate packaging materials resistant to the chemical and follow carrier-specific guidelines for chemical shipments.

Is (E)-3-phenylprop-2-enal subject to specific regulations?

(E)-3-phenylprop-2-enal is subject to CLP regulation requiring classification as Skin Sens. 1A with appropriate labeling including Warning signal word and GHS07 pictogram. It falls under REACH registration requirements for chemical substances. The compound is not currently listed as a SVHC (Substance of Very High Concern). Food and cosmetic applications may be subject to additional sector-specific regulations regarding purity and usage levels.

Where to buy (E)-3-phenylprop-2-enal in Europe?

(E)-3-phenylprop-2-enal is available through OYSI, a specialized European distributor of chemical products. OYSI provides this compound to various industries including fragrance, pharmaceutical, and chemical manufacturing sectors. The company ensures proper packaging, labeling, and documentation compliance with European regulations. Contact OYSI directly for product availability, technical specifications, and delivery options across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.