(Z)-but-2-enedioic acid
C4H4O4
Consulting for (Z)-but-2-enedioic acid
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Identification
- CAS Number
- 110-16-7
- EC Number
- 203-742-5
- UN Number
- Index Number
- 607-095-00-3
- PubChem CID
- 444266
Physical-chemical properties
- Molecular Formula
- C4H4O4
- Molar Mass
- 116.07 g/mol
- IUPAC Name
- (Z)-but-2-enedioic acid
Chemical Identifiers
- InChI
- InChI=1S/C4H4O4/c5-3(6)1-2-4(7)8/h1-2H,(H,5,6)(H,7,8)/b2-1-
- InChI Key
- VZCYOOQTPOCHFL-UPHRSURJSA-N
Overview
(Z)-but-2-enedioic acid (CAS 110-16-7) is a dicarboxylic acid with unsaturated double bond configuration and notable chemical reactivity properties. This organic compound, also known by its systematic IUPAC name (Z)-but-2-enedioic acid, represents a significant chemical intermediate in various industrial processes. With the molecular formula C4H4O4 and a molecular weight of 116.07 g/mol, this dicarboxylic acid features a distinctive Z-configuration around its central double bond, which influences both its physical properties and chemical behavior. The compound is assigned EC number 203-742-5 and is classified under multiple hazard categories including acute toxicity, skin and eye irritation, and skin sensitization, requiring appropriate safety measures during handling and storage. The substance presents moderate safety concerns with GHS07 pictogram classification and "Warning" signal word, indicating the need for proper personal protective equipment and ventilation systems in industrial applications. Its hazard profile includes Acute Tox. 4, STOT SE 3, Skin Irrit. 2, Eye Irrit. 2, and Skin Sens. 1 classifications, making it essential for users to implement comprehensive risk management protocols. Industrial applications of (Z)-but-2-enedioic acid include its use as a chemical intermediate in polymer synthesis, where its reactive double bond enables cross-linking reactions. The compound also serves as a building block in pharmaceutical manufacturing and specialty chemical production. Like other reactive compounds such as tetrachlorosilane used in silicon chemistry, this dicarboxylic acid requires careful handling due to its chemical reactivity and potential health hazards. OYSI maintains reliable supply chains for (Z)-but-2-enedioic acid to support European industrial customers with consistent quality and technical support.
Safety & Classification
Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Frequently Asked Questions
What is (Z)-but-2-enedioic acid?
(Z)-but-2-enedioic acid is a dicarboxylic acid compound with the molecular formula C4H4O4 and CAS number 110-16-7. Also known as maleic acid, it features a cis-configuration double bond between the two carbon atoms. With a molecular weight of 116.07 g/mol, this organic compound is classified as a hazardous substance requiring proper handling due to its irritant and sensitizing properties.
What are the physicochemical properties of (Z)-but-2-enedioic acid?
(Z)-but-2-enedioic acid appears as white crystalline solid at room temperature with high water solubility. The compound has a molecular weight of 116.07 g/mol and contains two carboxylic acid groups. It exhibits acidic properties due to its dicarboxylic nature and shows good solubility in polar solvents. The cis-configuration of the double bond makes it more reactive than its trans-isomer, fumaric acid.
What is (Z)-but-2-enedioic acid used for?
(Z)-but-2-enedioic acid serves as an important industrial intermediate in chemical synthesis and polymer production. It is widely used in manufacturing unsaturated polyester resins, alkyd resins, and as a curing agent for epoxy resins. The compound also finds applications in food industry as an acidulant, in pharmaceutical synthesis, and as a building block for various chemical reactions requiring dicarboxylic acid functionality.
How to handle (Z)-but-2-enedioic acid safely?
(Z)-but-2-enedioic acid requires careful handling with appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas to avoid inhalation exposure. The compound can cause skin and eye irritation and may cause skin sensitization. Avoid direct contact with skin and eyes, and prevent dust formation during handling. Always follow good industrial hygiene practices.
How to store (Z)-but-2-enedioic acid correctly?
(Z)-but-2-enedioic acid should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly closed and protect from moisture to prevent degradation. Store away from strong bases, oxidizing agents, and reducing agents. Use appropriate containment to prevent environmental release and ensure storage areas are equipped with suitable fire suppression systems and spill containment measures.
What to do in case of contact with (Z)-but-2-enedioic acid?
Immediate action is required upon contact with (Z)-but-2-enedioic acid. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. If eye contact occurs, flush immediately with water for at least 15 minutes and seek medical attention. In case of inhalation, move to fresh air immediately. If ingested, rinse mouth and seek immediate medical advice.
How to dispose of (Z)-but-2-enedioic acid appropriately?
(Z)-but-2-enedioic acid waste must be disposed of in accordance with local, national, and international regulations. The compound should be treated as hazardous waste and handled by licensed waste disposal companies. Never dispose of in regular trash or pour down drains. Neutralization may be possible under controlled conditions, but professional waste management is recommended to ensure environmental compliance and safety.
How to transport (Z)-but-2-enedioic acid?
(Z)-but-2-enedioic acid transport requirements depend on quantity and packaging specifications. While not explicitly classified under ADR dangerous goods regulations based on available data, proper packaging and labeling according to GHS requirements with Warning signal word and GHS07 pictogram are necessary. Consult current transport regulations and safety data sheets for specific shipping requirements and ensure compliance with applicable transport legislation.
Is (Z)-but-2-enedioic acid subject to specific regulations?
(Z)-but-2-enedioic acid is subject to REACH regulation for chemical registration and evaluation within the European Union. The compound must be classified and labeled according to CLP regulation with appropriate hazard classifications including Acute Tox. 4, STOT SE 3, Skin Irrit. 2, Eye Irrit. 2, and Skin Sens. 1. It is not currently listed as a SVHC substance, but users must comply with occupational safety regulations.
Where to buy (Z)-but-2-enedioic acid in Europe?
(Z)-but-2-enedioic acid is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As an established chemical distributor, OYSI ensures product quality and offers technical support for industrial applications, making it a trusted source for European businesses requiring this compound.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.