Methyl 2-hydroxybenzoate
C8H8O3
methyl 2-hydroxybenzoate
Consulting for Methyl 2-hydroxybenzoate
Our experts support you with application, dosage, and compliance.
Identification
- CAS Number
- 119-36-8
- EC Number
- 204-317-7
- UN Number
- Index Number
- 607-749-00-8
- PubChem CID
- 4133
Physical-chemical properties
- Molecular Formula
- C8H8O3
- Molar Mass
- 152.15 g/mol
- IUPAC Name
- methyl 2-hydroxybenzoate
Chemical Identifiers
- InChI
- InChI=1S/C8H8O3/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5,9H,1H3
- InChI Key
- OSWPMRLSEDHDFF-UHFFFAOYSA-N
Overview
Methyl 2-hydroxybenzoate (CAS 119-36-8) is an aromatic ester compound with hydroxyl functionality and notable UV-absorbing properties. This organic compound, also known by its IUPAC designation methyl 2-hydroxybenzoate, represents a significant chemical intermediate in various industrial applications. With the molecular formula C8H8O3 and a molecular weight of 152.15 g/mol, this aromatic ester combines the structural features of benzoic acid derivatives with methyl ester functionality, providing unique chemical properties that make it valuable across multiple sectors. The compound exhibits characteristic properties of phenolic esters, including UV absorption capabilities and moderate solubility in organic solvents. Safety considerations are paramount when handling this material, as it carries a GHS08 health hazard pictogram and GHS07 exclamation mark, reflecting its classification as Repr. 2 (reproductive toxicity category 2), Acute Tox. 4 (acute toxicity category 4), and Skin Sens. 1B (skin sensitization category 1B). Additionally, it presents Aquatic Chronic 3 environmental hazards, requiring appropriate handling protocols and waste management procedures. Industrial applications primarily focus on its use as a chemical intermediate in pharmaceutical synthesis and specialty chemical manufacturing. The compound serves as a key building block in the production of various organic compounds, particularly in processes requiring aromatic hydroxyl functionality. Similar to other phenolic compounds like 4-nitrophenol, it finds applications in analytical chemistry and materials science, where its UV-absorbing properties prove beneficial. OYSI maintains reliable availability of methyl 2-hydroxybenzoate for European customers, supporting diverse industrial requirements with comprehensive technical documentation and regulatory compliance assistance.
Safety & Classification
Repr. 2; Acute Tox. 4; Skin Sens. 1B; Aquatic Chronic 3
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Frequently Asked Questions
What is methyl 2-hydroxybenzoate?
Methyl 2-hydroxybenzoate is an organic chemical compound with the molecular formula C8H8O3 and CAS number 119-36-8. Also known as methyl salicylate or oil of wintergreen, it is an ester derived from salicylic acid and methanol. With a molecular weight of 152.15 g/mol, this compound appears as a colorless to pale yellow liquid with a characteristic sweet, minty odor reminiscent of wintergreen.
What are the physicochemical properties of methyl 2-hydroxybenzoate?
Methyl 2-hydroxybenzoate is a colorless to pale yellow liquid at room temperature with a distinctive sweet, wintergreen-like odor. It has a molecular weight of 152.15 g/mol and is slightly soluble in water but readily soluble in alcohol, ether, and other organic solvents. The compound has a boiling point around 223°C and a density of approximately 1.17 g/cm³ at 20°C.
What is methyl 2-hydroxybenzoate used for?
Methyl 2-hydroxybenzoate is primarily used as a flavoring agent in food products, cosmetics, and pharmaceutical preparations due to its wintergreen scent. It serves as an intermediate in organic synthesis and is employed in the production of perfumes, liniments, and topical analgesic formulations. Additionally, it finds applications as a UV filter in some cosmetic products and as a fragrance component in various consumer goods.
How to handle methyl 2-hydroxybenzoate safely?
Methyl 2-hydroxybenzoate requires careful handling due to its classification as Acute Tox. 4, Repr. 2, and Skin Sens. 1B. Use appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation in work areas and avoid skin contact and inhalation. Handle in well-ventilated areas away from heat sources, and wash hands thoroughly after use to prevent sensitization reactions.
How to store methyl 2-hydroxybenzoate correctly?
Methyl 2-hydroxybenzoate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers upright and properly labeled according to CLP regulations with appropriate warning pictogrammes (GHS07, GHS08). Store away from incompatible materials such as strong oxidizing agents and bases. Maintain storage temperature below 25°C to prevent degradation and ensure container integrity.
What to do in case of contact with methyl 2-hydroxybenzoate?
In case of skin contact with methyl 2-hydroxybenzoate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse immediately with plenty of clean water for 15 minutes and seek medical attention. In case of inhalation, move to fresh air immediately. If ingested, do not induce vomiting and seek immediate medical attention due to its acute toxicity classification.
How to dispose of methyl 2-hydroxybenzoate properly?
Methyl 2-hydroxybenzoate must be disposed of as hazardous waste according to local and European waste regulations. Do not discharge into drains, waterways, or soil due to its Aquatic Chronic 3 classification. Contact authorized waste disposal companies for proper treatment and disposal. Small quantities may be incinerated at approved high-temperature facilities. Always consult local environmental authorities for specific disposal requirements and waste codes.
How to transport methyl 2-hydroxybenzoate?
Methyl 2-hydroxybenzoate can be transported without specific ADR dangerous goods classification for road transport within Europe. However, packages must be properly labeled with appropriate GHS pictogrammes (GHS07, GHS08) and safety information according to CLP regulation. Use appropriate packaging materials resistant to the chemical and ensure containers are tightly sealed to prevent leakage during transport. Follow general chemical transport safety guidelines.
Is methyl 2-hydroxybenzoate subject to specific regulations?
Methyl 2-hydroxybenzoate is subject to REACH regulation and must be registered for import/manufacture above one tonne annually. It is classified under CLP regulation with hazard classes Repr. 2, Acute Tox. 4, Skin Sens. 1B, and Aquatic Chronic 3, requiring appropriate labeling with warning signal word. While not currently listed as SVHC, its reproductive toxicity classification may require special attention in workplace risk assessments and safety data sheets.
Where to buy methyl 2-hydroxybenzoate in Europe?
Methyl 2-hydroxybenzoate is available through OYSI, a European chemical distributor specializing in technical and specialty chemicals. OYSI provides this compound with full regulatory compliance including safety data sheets, CLP labeling, and REACH registration support. As an established European supplier, OYSI ensures product quality and regulatory conformity for industrial and professional applications across European markets.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.