Benzene

C6H6

benzene

CAS71-43-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

Consulting for Benzene

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Identification

CAS Number
71-43-2
EC Number
200-753-7
UN Number
1114
Index Number
601-020-00-8
PubChem CID
241

Physical-chemical properties

Molecular Formula
C6H6
Molar Mass
78.11 g/mol
IUPAC Name
benzene

Chemical Identifiers

InChI
InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H
InChI Key
UHOVQNZJYSORNB-UHFFFAOYSA-N

Overview

Benzene (CAS 71-43-2) is an aromatic hydrocarbon with a characteristic ring structure and high flammability properties. This fundamental aromatic compound serves as one of the most important building blocks in the chemical industry. With its distinctive hexagonal ring structure of six carbon atoms, benzene exhibits unique chemical stability due to electron delocalization, making it an essential intermediate for countless industrial processes. The colorless liquid possesses a sweet aromatic odor and demonstrates excellent solvent properties for various organic compounds. From a safety perspective, benzene requires careful handling due to its significant health hazards. Classified as a Category 1A carcinogen and Category 1B mutagen, it poses serious long-term health risks including potential blood disorders and cancer. The substance is highly flammable (Flammability Category 2) and can cause skin and eye irritation upon contact. Additionally, its aspiration toxicity and specific target organ toxicity necessitate proper ventilation and personal protective equipment during handling. Industrially, benzene finds primary applications in the production of styrene, where it serves as a precursor alongside related compounds like ethylbenzene in the manufacturing chain. The petrochemical industry utilizes benzene extensively for synthesizing plastics, synthetic rubbers, and various chemical intermediates. It also functions as a high-octane component in gasoline formulations, though this application has decreased due to environmental regulations. The pharmaceutical and chemical industries rely on benzene for manufacturing phenol, cyclohexane, and numerous aromatic derivatives. Its role as a solvent in chemical reactions and extraction processes remains significant despite increasing regulatory restrictions. OYSI maintains reliable supply chains for benzene, ensuring consistent availability for European industrial customers requiring this essential aromatic compound.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 1A; Muta. 1B; Asp. Tox. 1; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H350

May cause cancer.

H340

May cause genetic defects.

H304

May be fatal if swallowed and enters airways.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1114
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameBenzen
Marine PollutantNo

Frequently Asked Questions

What is benzene?

Benzene is an aromatic hydrocarbon compound with the molecular formula C6H6 and a molecular weight of 78.11 g/mol. It is a fundamental chemical building block consisting of six carbon atoms arranged in a hexagonal ring structure with alternating double bonds. Benzene is classified as a highly hazardous substance due to its carcinogenic, mutagenic, and flammable properties, requiring careful handling in industrial applications.

What are the physicochemical properties of benzene?

Benzene is a colorless liquid at room temperature with a characteristic sweet aromatic odor. It has a boiling point of 80.1°C and a melting point of 5.5°C. The compound is relatively insoluble in water but miscible with most organic solvents such as alcohol, ether, and acetone. Its vapor is heavier than air and can accumulate in low-lying areas, creating potential fire and health hazards.

What is benzene used for?

Benzene is primarily used as a raw material in the chemical industry for producing other chemicals including styrene, phenol, and cyclohexane. It serves as a precursor for manufacturing plastics, synthetic rubber, dyes, detergents, and pharmaceuticals. In industrial processes, benzene is also used as a solvent, though this application has decreased significantly due to health concerns and regulatory restrictions on exposure.

How to handle benzene safely?

Benzene handling requires strict safety measures including wearing appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods to minimize vapor exposure. Avoid skin contact and inhalation, as benzene is carcinogenic. Use only explosion-proof equipment due to its flammable nature and maintain emergency procedures for spill response.

How to store benzene correctly?

Benzene must be stored in tightly sealed containers made of compatible materials in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Storage areas should be equipped with appropriate fire suppression systems and spill containment measures. Keep away from incompatible materials such as strong oxidizing agents. Temperature control is essential to prevent vapor buildup and maintain container integrity.

What to do in case of contact with benzene?

Benzene contact requires immediate action: for skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. For ingestion, do not induce vomiting and seek immediate medical care.

How to dispose of benzene appropriately?

Benzene disposal must comply with local, national, and international waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or disposed of in regular waste streams. Disposal must be performed by licensed waste management companies specializing in hazardous chemical disposal, typically through controlled incineration at high temperatures or other approved treatment methods.

How to transport benzene?

Benzene is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport protocols. Containers must meet UN specification standards and be properly labeled with appropriate hazard pictograms. Transport vehicles must be equipped with appropriate safety equipment and drivers must hold valid ADR certification. Shipping documentation must include proper shipping names, hazard classifications, and emergency response information.

Is benzene subject to specific regulations?

Benzene is subject to extensive regulatory oversight under REACH, CLP, and various national regulations due to its carcinogenic classification (Carc. 1A). It faces strict exposure limits in workplace environments and restrictions on consumer use. Companies must comply with registration requirements, safety data sheet provisions, and worker protection standards. Regular monitoring and reporting may be required depending on usage quantities and applications.

Where to buy benzene in Europe?

Benzene is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemical products to industrial customers across the European market. Due to its hazardous classification, purchases typically require proper documentation, end-use declarations, and compliance with regulatory requirements. Professional buyers should ensure suppliers provide appropriate safety data sheets and technical support for safe handling and storage.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.