2-methylpropyl prop-2-enoate

C7H12O2

CAS106-63-8
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
106-63-8
EC Number
203-417-8
UN Number
2527
Index Number
607-115-00-0
PubChem CID
7819

Physical-chemical properties

Molecular Formula
C7H12O2
Molar Mass
128.17 g/mol
IUPAC Name
2-methylpropyl prop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C7H12O2/c1-4-7(8)9-5-6(2)3/h4,6H,1,5H2,2-3H3
InChI Key
CFVWNXQPGQOHRJ-UHFFFAOYSA-N

Overview

2-methylpropyl prop-2-enoate (CAS 106-63-8) is an acrylic ester monomer with polymerization properties and moderate flammability characteristics. This chemical compound, also known by its IUPAC designation 2-methylpropyl prop-2-enoate, represents an important member of the acrylic ester family used extensively in polymer chemistry and industrial applications. With the molecular formula C7H12O2 and a molecular weight of 128.17 g/mol, this colorless liquid exhibits typical characteristics of acrylic monomers, including the ability to undergo rapid polymerization under appropriate conditions. The substance is classified under multiple hazard categories, requiring careful handling protocols. It presents as a flammable liquid (Class 3) with moderate acute toxicity potential and known skin sensitization properties. The GHS classification includes Flam. Liq. 3, Acute Tox. 4, Skin Irrit. 2, and Skin Sens. 1, necessitating appropriate personal protective equipment and ventilation systems during handling. Storage should comply with ADR Class 3 requirements to ensure safe transportation and warehousing. Primary industrial applications include the production of acrylic polymers and copolymers for coatings, adhesives, and sealants. The compound serves as a key building block in formulating specialty polymers with enhanced flexibility and weather resistance properties. Its reactivity profile makes it valuable in UV-curing formulations and pressure-sensitive adhesive systems. Unlike related compounds such as 4-methoxy-4-methylpentan-2-one, which serves primarily as a solvent, this acrylic ester functions predominantly as a reactive monomer in polymerization processes. The European Chemical Agency registration (EC 203-417-8) ensures regulatory compliance across EU markets. OYSI maintains reliable supply chains for this technical chemical, supporting diverse industrial applications throughout Europe.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; Acute Tox. 4 *; Acute Tox. 4 *; Skin Irrit. 2; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2527
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameIsobutylacrylat, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-methylpropyl prop-2-enoate?

2-methylpropyl prop-2-enoate is an acrylic ester monomer with the molecular formula C7H12O2 and CAS number 106-63-8. This chemical compound has a molecular weight of 128.17 g/mol and belongs to the family of acrylate esters. It is classified as a flammable liquid with moderate toxicity and skin sensitization properties, requiring careful handling in industrial applications.

What are the physicochemical properties of 2-methylpropyl prop-2-enoate?

2-methylpropyl prop-2-enoate is a colorless to pale yellow liquid at room temperature with a characteristic acrylic odor. It has limited solubility in water but is miscible with most organic solvents. The compound exhibits typical ester properties and can undergo polymerization reactions. Its molecular structure consists of an acrylate group attached to a branched propyl chain, giving it specific reactivity patterns.

What is 2-methylpropyl prop-2-enoate used for?

2-methylpropyl prop-2-enoate is primarily used as a monomer in polymer synthesis and copolymerization reactions. It serves as a building block for producing acrylic resins, coatings, adhesives, and sealants. The compound is valuable in manufacturing specialty polymers with improved flexibility and weather resistance. It finds applications in the paint, coating, and adhesive industries where specific polymer properties are required.

How to handle 2-methylpropyl prop-2-enoate safely?

2-methylpropyl prop-2-enoate requires careful handling due to its flammable and sensitizing properties. Use appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation. Avoid contact with skin and eyes, and prevent inhalation of vapors. Keep away from heat sources, sparks, and open flames. Work in well-ventilated areas or under fume hoods.

How to store 2-methylpropyl prop-2-enoate correctly?

2-methylpropyl prop-2-enoate should be stored in a cool, dry, well-ventilated area away from heat sources and ignition sources. Keep containers tightly closed and protected from light to prevent polymerization. Store away from oxidizing agents and incompatible materials. Maintain storage temperature below 25°C and consider adding polymerization inhibitors. Use appropriate secondary containment and ensure storage areas comply with flammable liquid storage requirements.

What to do in case of contact with 2-methylpropyl prop-2-enoate?

2-methylpropyl prop-2-enoate contact requires immediate action due to its irritating and sensitizing properties. For skin contact, immediately remove contaminated clothing and wash affected area with plenty of soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. Seek medical attention if symptoms persist or worsen.

How to dispose of 2-methylpropyl prop-2-enoate appropriately?

2-methylpropyl prop-2-enoate must be disposed of as hazardous waste according to local and national regulations. Do not pour down drains or dispose of with regular waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be allowed for incineration at high temperatures in approved facilities. Always check current waste disposal regulations and obtain proper waste codes before disposal.

How to transport 2-methylpropyl prop-2-enoate?

2-methylpropyl prop-2-enoate is classified as ADR Class 3, Packing Group III for transportation purposes. It must be transported as a flammable liquid with appropriate packaging, labeling, and documentation. Use approved containers and ensure proper segregation from incompatible materials. Transport vehicles must comply with ADR requirements for flammable liquids, including appropriate placarding and emergency equipment. Follow all applicable transportation regulations for hazardous materials.

Is 2-methylpropyl prop-2-enoate subject to specific regulations?

2-methylpropyl prop-2-enoate is subject to REACH regulation in Europe and must comply with CLP classification requirements. It is classified with multiple hazard classes including flammable liquid and skin sensitizer, requiring appropriate safety data sheets and labeling. The substance is not currently listed as SVHC under REACH. Users must comply with occupational exposure limits and workplace safety regulations in their respective jurisdictions.

Where to buy 2-methylpropyl prop-2-enoate in Europe?

2-methylpropyl prop-2-enoate is available through OYSI, a trusted European distributor of specialty chemicals and industrial raw materials. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality and provides technical support for industrial applications requiring this acrylic monomer in various industries and applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.