(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene

C10H6Cl8

CAS57-74-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Warning

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Identification

CAS Number
57-74-9
EC Number
200-349-0
UN Number
2761
Index Number
602-047-00-8
PubChem CID
11954021

Physical-chemical properties

Molecular Formula
C10H6Cl8
Molar Mass
409.80 g/mol
IUPAC Name
(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene

Chemical Identifiers

InChI
InChI=1S/C10H6Cl8/c11-3-1-2-4(5(3)12)9(16)7(14)6(13)8(2,15)10(9,17)18/h2-5H,1H2/t2?,3?,4?,5?,8-,9+/m0/s1
InChI Key
BIWJNBZANLAXMG-YQELWRJZSA-N

Overview

(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene (CAS 57-74-9) is an organochlorine compound with persistent environmental properties and significant toxicological concerns. This highly chlorinated tricyclic compound, commonly known by its historical applications, represents a complex organochlorine structure with eight chlorine atoms attached to a rigid tricyclic framework. With a molecular formula of C10H6Cl8 and molecular weight of 409.8 g/mol, this substance exhibits the characteristic stability and persistence associated with heavily chlorinated organic compounds. The compound's unique stereochemistry, indicated by its (1R,7S) configuration, influences its biological activity and environmental behavior. From a safety perspective, this substance is classified as a Category 2 carcinogen and presents acute toxicity risks (Category 4), requiring careful handling protocols. Its environmental profile is particularly concerning, with Aquatic Acute 1 and Aquatic Chronic 1 classifications indicating severe hazards to aquatic ecosystems. The compound falls under ADR Class 6.1 for transport purposes and displays GHS pictograms for health hazards (GHS08), acute toxicity (GHS07), and environmental dangers (GHS09). The compound's industrial applications have historically centered around specialized chemical processes where its unique structure provided specific functionality. Its stability and chlorine content made it valuable in certain technical applications, though regulatory restrictions have significantly limited its contemporary use. Unlike more commonly used industrial chemicals such as 4-aminophenol, this compound requires specialized handling expertise and regulatory compliance measures. Due to its classification and regulatory status, this substance is available through OYSI's specialized chemical division with appropriate documentation, safety data sheets, and regulatory compliance support for qualified industrial customers.

Safety & Classification

Warning
Classification:

Carc. 2; Acute Tox. 4 *; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2761
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameChlordan (ISO)
Marine PollutantNo

Frequently Asked Questions

What is (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene?

(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene is a highly chlorinated organic compound commonly known as chlordane. This persistent organochlorine pesticide has the molecular formula C10H6Cl8 and a molecular weight of 409.8 g/mol. It features a complex tricyclic structure with eight chlorine atoms, making it extremely stable and resistant to degradation. Due to its toxicity and environmental persistence, its use has been severely restricted or banned in many countries.

What are the physicochemical properties of (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene?

This compound is a viscous, amber-colored liquid at room temperature with a characteristic chlorine-like odor. It has very low water solubility but is readily soluble in organic solvents such as alcohols, ketones, and aromatic hydrocarbons. The substance has a high boiling point and low vapor pressure due to its heavy chlorination. Its lipophilic nature allows it to bioaccumulate in fatty tissues, contributing to its environmental persistence and biological effects.

What is (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene used for?

This substance was historically used as a broad-spectrum insecticide for termite control, agricultural pest management, and household pest elimination. Its applications included soil treatment, structural pest control, and crop protection. However, due to its classification as a probable carcinogen (Carc. 2) and severe environmental impact, its use has been largely discontinued. Today, it may only be used in very specific, highly regulated applications or for research purposes under strict safety protocols.

How to handle (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene safely?

Safe handling requires comprehensive personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection to prevent inhalation exposure. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid skin contact and inhalation as the substance is classified as Acute Tox. 4 for both dermal and oral routes. Use only trained personnel familiar with handling toxic chemicals, and ensure emergency procedures are readily available.

How to store (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene properly?

Store this substance in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Use chemically resistant containers and ensure secondary containment to prevent environmental release. Keep away from strong oxidizers and bases. Storage areas should be equipped with spill containment measures and restricted access. Regular container inspection is essential due to the substance's potential for environmental contamination if released.

What to do in case of contact with (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene?

In case of skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air and seek medical attention if breathing difficulties occur. For eye contact, rinse immediately with clean water for 15 minutes. Do not induce vomiting if ingested. Seek immediate medical attention in all cases of exposure, informing medical personnel of the substance's carcinogenic classification.

How to dispose of (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene appropriately?

Disposal must be conducted through licensed hazardous waste disposal facilities due to the substance's toxic and environmentally persistent nature. High-temperature incineration in specialized facilities is typically required to ensure complete destruction. Never dispose of in regular waste streams, sewers, or soil due to its Aquatic Acute 1 and Aquatic Chronic 1 classifications. Contaminated containers and materials must also be treated as hazardous waste following local and national environmental regulations.

How to transport (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene?

Transportation is regulated under ADR Class 6.1 (Toxic substances), Packing Group III. Appropriate UN packaging specifications must be used with proper hazard labels and documentation. Vehicles must carry emergency response information and drivers require ADR training for dangerous goods transport. The shipment must include proper shipping papers identifying the substance and emergency contact information. Ensure compliance with all international transport regulations for toxic substances.

Is (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene subject to special regulations?

Yes, this substance is subject to extensive regulatory oversight under REACH, CLP, and Stockholm Convention regulations. Its carcinogenic classification (Carc. 2) and environmental persistence trigger strict handling and reporting requirements. Many jurisdictions have banned or severely restricted its use due to health and environmental concerns. Users must comply with occupational exposure limits, environmental monitoring requirements, and may need special permits for possession or use of this regulated substance.

Where to buy (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene in Europe?

OYSI serves as a specialized European distributor for regulated chemical substances including this compound. Due to its restricted status and safety requirements, procurement requires proper licensing and justification for legitimate research or industrial applications. OYSI ensures full regulatory compliance and provides necessary documentation for legal acquisition. Contact OYSI directly to discuss specific requirements, regulatory compliance, and availability for your authorized application, as standard commercial availability is extremely limited.

Services for (1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene

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(1R,7S)-1,3,4,7,8,9,10,10-octachlorotricyclo[5.2.1.02,6]dec-8-ene is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.