(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide

C40H18BF20I

CAS178233-72-2
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Warning

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Identification

CAS Number
178233-72-2
EC Number
422-960-3
UN Number
3077
Index Number
053-005-00-5
PubChem CID
21967041

Physical-chemical properties

Molecular Formula
C40H18BF20I
Molar Mass
1016.30 g/mol
IUPAC Name
(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide

Chemical Identifiers

InChI
InChI=1S/C24BF20.C16H18I/c26-5-1(6(27)14(35)21(42)13(5)34)25(2-7(28)15(36)22(43)16(37)8(2)29,3-9(30)17(38)23(44)18(39)10(3)31)4-11(32)19(40)24(45)20(41)12(4)33;1-12(2)14-6-10-16(11-7-14)17-15-8-4-13(3)5-9-15/h;4-12H,1-3H3/q-1;+1
InChI Key
MJDBKUFRQPPWGN-UHFFFAOYSA-N

Overview

(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide (CAS 178233-72-2) is a specialized organoiodine photoinitiator compound featuring high molecular fluorine content and enhanced photochemical reactivity. This diaryliodonium salt represents an advanced class of photoinitiators specifically engineered for UV-induced polymerization processes. With its molecular formula C40H18BF20I and substantial molecular weight of 1016.3 g/mol, this compound demonstrates the sophisticated molecular architecture characteristic of modern photochemistry applications. The presence of the tetrakis(pentafluorophenyl)borate counterion provides exceptional thermal stability and solubility properties in organic media, while the substituted diaryliodonium cation ensures efficient photolysis under UV irradiation. The compound exhibits multiple hazard classifications including Acute Toxicity Category 4 and Specific Target Organ Toxicity (Repeated Exposure) Category 2, requiring appropriate handling protocols and personal protective equipment during industrial applications. Its aquatic toxicity classification necessitates careful environmental management and waste disposal procedures. Transport classification under ADR Class 9 indicates it as a miscellaneous dangerous substance requiring specialized shipping documentation. Primary industrial applications include advanced photopolymerization systems for high-performance coatings, electronic materials manufacturing, and specialized adhesive formulations where precise curing control is essential. Unlike simpler aromatic compounds such as 1,4-dichlorobenzene, this photoinitiator offers superior performance in demanding applications requiring rapid, controlled polymerization under UV exposure. The fluorinated borate structure provides enhanced compatibility with fluorinated polymer systems and improved performance in challenging environmental conditions. OYSI maintains reliable supply chains for this specialized photoinitiator to support European technical applications requiring consistent quality and regulatory compliance.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 2 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping Name(4-(1-Methylethyl)phenyl)-(4-methylphenyl)iodonium-tetrakis(pentafluorphenyl)borat(1-)
Marine PollutantNo

Frequently Asked Questions

What is (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide?

(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide is an iodonium salt with the molecular formula C40H18BF20I and CAS number 178233-72-2. This complex organometallic compound features an iodonium cation paired with a fluorinated borate anion, resulting in a high molecular weight of 1016.3 g/mol. The substance is classified as hazardous with moderate toxicity and environmental concerns.

What are the physicochemical properties of (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide?

This iodonium salt is a solid compound with a high molecular weight of 1016.3 g/mol, containing multiple fluorinated aromatic rings. The presence of the perfluorinated borate anion contributes to its chemical stability and unique solubility characteristics. Due to its organometallic nature and fluorinated structure, it typically exhibits limited water solubility but may be soluble in organic solvents.

What is (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide used for?

This iodonium salt is primarily used as a photoinitiator in advanced polymer chemistry and photolithography applications. The compound serves as a cationic photoinitiator, generating reactive species upon UV exposure to initiate polymerization reactions. It finds applications in specialty coatings, adhesives, and electronic materials manufacturing where precise photochemical control is required.

How to handle (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide safely?

Safe handling requires appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its Acute Tox. 4 classification. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact, and ensure proper hygiene practices. The GHS07 and GHS08 pictograms indicate health hazards requiring careful handling procedures.

How to store (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide correctly?

The compound should be stored in a cool, dry place away from direct light and heat sources, as it is light-sensitive due to its photoinitiator properties. Keep containers tightly sealed to prevent moisture absorption and contamination. Storage areas should be well-ventilated and equipped with appropriate spill containment measures. Avoid storage near incompatible materials and ensure proper labeling according to CLP requirements.

What to do in case of contact with (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide?

Immediate action is required upon contact due to its toxicity classification. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, flush immediately with plenty of clean water for at least 15 minutes. If inhaled, move to fresh air immediately. Seek medical attention if symptoms develop or persist, and provide safety data sheet information to medical personnel.

How to dispose of (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide appropriately?

Disposal must comply with local and European waste regulations due to its environmental hazard classification (Aquatic Acute 1, Aquatic Chronic 1). The substance cannot be disposed of through regular waste streams and requires treatment as hazardous chemical waste. Contact licensed waste disposal companies for proper collection and treatment. Never discharge into drains, soil, or water bodies due to its aquatic toxicity.

How to transport (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide?

Transportation is regulated under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III, indicating moderate danger during transport. Packages must be properly labeled with appropriate hazard markings and accompanied by transport documentation. Use approved packaging materials and ensure compliance with international shipping regulations. Professional logistics providers experienced in chemical transport should handle shipment to ensure regulatory compliance.

Is (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide subject to specific regulations?

The substance is subject to CLP regulation due to its hazard classification and requires appropriate labeling with Warning signal word and GHS pictograms. REACH registration requirements apply for importers and manufacturers. While not currently listed as SVHC, its environmental classification requires compliance with water protection legislation. Users must maintain safety data sheets and implement appropriate risk management measures.

Where to buy (4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide in Europe?

OYSI serves as a reliable European distributor for this specialized iodonium salt, offering professional chemical distribution services across Europe. As an established chemical supplier, OYSI ensures proper handling, documentation, and regulatory compliance for specialty chemicals. Contact OYSI directly for availability, technical specifications, and pricing information for this advanced photoinitiator compound.

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(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.