Sulfuryl dichloride

Cl2O2S

sulfuryl dichloride

CAS7791-25-5
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7791-25-5
EC Number
232-245-6
UN Number
1834
Index Number
016-016-00-6
PubChem CID
24648

Physical-chemical properties

Molecular Formula
Cl2O2S
Molar Mass
134.97 g/mol
IUPAC Name
sulfuryl dichloride

Chemical Identifiers

InChI
InChI=1S/Cl2O2S/c1-5(2,3)4
InChI Key
YBBRCQOCSYXUOC-UHFFFAOYSA-N

Overview

Sulfuryl dichloride (CAS 7791-25-5) is an inorganic sulfur compound with strong chlorinating properties and high reactivity toward organic molecules. This colorless to pale yellow liquid serves as a versatile chlorinating agent in industrial chemistry, particularly valued for its selective reactivity and clean reaction profile. With the molecular formula Cl2O2S and a molecular weight of 134.97 g/mol, sulfuryl dichloride exhibits distinct chemical behavior that makes it indispensable in various synthetic applications. The compound belongs to the sulfur oxychloride family and demonstrates exceptional utility in organic synthesis due to its ability to introduce chlorine atoms into organic substrates under controlled conditions. Safety considerations are paramount when handling sulfuryl dichloride, as it carries significant hazard classifications including Skin Corr. 1B and STOT SE 3, requiring appropriate protective equipment and ventilation systems. The substance releases hydrogen chloride upon contact with moisture, creating additional safety concerns in humid environments. Its ADR classification as Class 6.1 reflects its toxic nature and necessitates specialized transportation protocols. Primary industrial applications include pharmaceutical intermediate synthesis, where sulfuryl dichloride enables the preparation of complex chlorinated compounds, and polymer chemistry for surface modification processes. The compound also finds use in the production of specialty chemicals and as a reagent in fine chemical manufacturing, often serving similar chlorinating functions to hydrogen chloride but with enhanced selectivity. Unlike related compounds such as potassium hydrogen sulfate, sulfuryl dichloride provides direct chlorination capabilities without requiring additional activation steps. OYSI maintains reliable supply chains for sulfuryl dichloride to support European industrial customers requiring this specialized chlorinating agent.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1834
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameSulfurylchlorid
Marine PollutantNo

Frequently Asked Questions

What is sulfuryl dichloride?

Sulfuryl dichloride is an inorganic chemical compound with the formula Cl2O2S and CAS number 7791-25-5. This substance has a molecular weight of 134.97 g/mol and is classified as a corrosive and toxic chemical. It belongs to the sulfur oxychloride family and is considered a dangerous substance requiring special handling precautions due to its corrosive properties and potential health hazards.

What are the physicochemical properties of sulfuryl dichloride?

Sulfuryl dichloride is a colorless to pale yellow liquid at room temperature with a pungent, acrid odor. It has a boiling point of approximately 69°C and readily decomposes in the presence of moisture, releasing toxic gases including hydrogen chloride and sulfur dioxide. The substance is highly reactive with water and alcohols, making it moisture-sensitive and requiring anhydrous storage conditions.

What is sulfuryl dichloride used for?

Sulfuryl dichloride is primarily used as a chlorinating agent in organic synthesis and pharmaceutical manufacturing. It serves as an important intermediate in the production of various chemicals, including pesticides, dyes, and specialty chemicals. The compound is also utilized in laboratory settings for specific chemical reactions requiring controlled chlorination processes and in the synthesis of sulfonyl chlorides.

How to handle sulfuryl dichloride safely?

Sulfuryl dichloride requires strict safety measures including wearing full personal protective equipment: chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods due to toxic vapor release. Avoid contact with skin, eyes, and respiratory system. Keep away from moisture and incompatible materials, and ensure emergency shower and eyewash stations are readily accessible.

How to store sulfuryl dichloride correctly?

Sulfuryl dichloride must be stored in tightly sealed, moisture-proof containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep separate from water, alcohols, bases, and metals to prevent dangerous reactions. Storage areas should be equipped with appropriate spill containment measures and maintained at stable temperatures to prevent decomposition and pressure buildup.

What to do in case of contact with sulfuryl dichloride?

Skin contact with sulfuryl dichloride requires immediate removal of contaminated clothing and thorough washing with plenty of water for at least 15 minutes. For eye contact, flush immediately with water for 15-20 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases of exposure, as this substance can cause severe chemical burns and respiratory irritation.

How to dispose of sulfuryl dichloride appropriately?

Sulfuryl dichloride disposal must comply with local and national hazardous waste regulations as it is classified as dangerous waste. The substance should never be poured down drains or released into the environment. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized carefully under controlled conditions by qualified personnel before disposal through approved channels.

How to transport sulfuryl dichloride?

Sulfuryl dichloride is classified under ADR as Class 6.1 (toxic substances), Packing Group I, indicating high toxicity requiring stringent transport regulations. It must be shipped in approved UN specification packaging with proper hazard labels and documentation. Transportation requires trained personnel and vehicles equipped for dangerous goods, following strict routing and emergency response protocols established by international transport regulations.

Is sulfuryl dichloride subject to specific regulations?

Sulfuryl dichloride is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification as STOT SE 3 and Skin Corr. 1B. It carries the 'Danger' signal word with GHS pictograms GHS05 and GHS07. While not listed as an SVHC substance, it requires compliance with occupational safety standards and may be subject to additional national restrictions regarding use and handling.

Where to buy sulfuryl dichloride in Europe?

Sulfuryl dichloride is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers. As a professional chemical supplier, OYSI ensures proper handling, packaging, and documentation compliance with European regulations. Contact OYSI directly for availability, technical specifications, and regulatory documentation required for your specific application and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.