Sulfuric Acid

H2O4S

sulphuric acid

CAS7664-93-9
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7664-93-9
EC Number
231-639-5
UN Number
1830
Index Number
016-011-00-9
PubChem CID
1118

Physical-chemical properties

Molecular Formula
H2O4S
Molar Mass
98.08 g/mol
IUPAC Name
sulphuric acid

Chemical Identifiers

InChI
InChI=1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)
InChI Key
QAOWNCQODCNURD-UHFFFAOYSA-N

Overview

Sulfuric Acid (CAS 7664-93-9) is a highly corrosive inorganic acid with exceptional dehydrating properties and strong oxidizing capabilities. As one of the most important industrial chemicals globally, sulfuric acid represents a cornerstone of modern chemical manufacturing. This colorless, oily liquid demonstrates remarkable versatility across numerous industrial applications, making it an essential component in chemical processing worldwide. The compound's molecular structure H2O4S contributes to its exceptional reactivity and corrosive nature, requiring specialized handling procedures and storage conditions. The substance exhibits extreme corrosive properties, classified under GHS05 pictogram with a "Danger" signal word and Skin Corr. 1A hazard classification. Its ADR Class 8 designation reflects its corrosive transport requirements. Unlike basic substances such as Sodium Hydroxide, sulfuric acid's acidic nature makes it particularly effective in metal processing and chemical synthesis applications. The compound's ability to act as both a dehydrating agent and proton donor enables its widespread industrial utility. Primary industrial applications include metal surface treatment and pickling operations, where its corrosive properties remove oxides and scale from metal surfaces. The chemical industry extensively utilizes sulfuric acid in manufacturing processes, particularly in the production of fertilizers, detergents, and other acids. Additionally, it serves as a crucial component in petroleum refining processes and battery manufacturing. Safety protocols demand appropriate personal protective equipment, adequate ventilation systems, and specialized storage facilities resistant to corrosive materials. The substance's reactivity with water generates significant heat, requiring careful dilution procedures. OYSI provides technical-grade sulfuric acid to European industrial customers, ensuring consistent quality standards for demanding chemical processing applications.

Safety & Classification

Danger
Classification:

Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1830
ADR Class8
Packing GroupII
ADR Labels8
Tunnel CodeE
Proper Shipping NameSCHWEFELSÄURE mit mehr als 51 % Säure
Marine PollutantNo

Frequently Asked Questions

What is Sulfuric Acid?

Sulfuric Acid is a highly corrosive mineral acid with the chemical formula H2SO4 and CAS number 7664-93-9. It is one of the most important industrial chemicals worldwide, characterized by its strong acidic properties and high reactivity. With a molecular weight of 98.08 g/mol, it is classified as a skin corrosive substance (Skin Corr. 1A) and presents significant safety hazards requiring careful handling and appropriate safety measures.

What are the physicochemical properties of Sulfuric Acid?

Sulfuric Acid is a dense, oily liquid that is colorless to slightly yellow when pure. It has no odor in its pure form but may emit irritating vapors. The substance is highly hygroscopic, meaning it readily absorbs moisture from air. It is completely miscible with water in all proportions, generating significant heat during dilution. Its high boiling point and strong dehydrating properties make it extremely reactive with organic materials.

What is Sulfuric Acid used for?

Sulfuric Acid serves as a fundamental chemical in numerous industrial applications. It is extensively used in battery manufacturing, metal processing, petroleum refining, and chemical synthesis. Other major applications include fertilizer production, wastewater treatment, textile processing, and pharmaceutical manufacturing. It also plays a crucial role in ore processing, dye manufacturing, and as a dehydrating agent in various chemical processes across multiple industries.

How to handle Sulfuric Acid safely?

Sulfuric Acid requires strict safety protocols due to its corrosive nature. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shields, and acid-resistant clothing. Work must be conducted in well-ventilated areas or under fume hoods. Always add acid to water, never water to acid, to prevent violent reactions. Emergency eyewash stations and safety showers must be readily accessible when handling this substance.

How to store Sulfuric Acid correctly?

Sulfuric Acid must be stored in corrosion-resistant containers made of materials like high-density polyethylene or glass. Storage areas should be cool, dry, and well-ventilated, away from heat sources and incompatible materials. It should be kept separate from metals, organic compounds, and bases to prevent dangerous reactions. Secondary containment is essential to manage potential spills, and storage areas must comply with local chemical storage regulations.

What to do in case of contact with Sulfuric Acid?

Immediate action is crucial for any contact with Sulfuric Acid. For skin contact, rinse immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. For eye contact, flush with water for at least 15 minutes and seek immediate medical attention. If inhaled, move to fresh air immediately. Never attempt to neutralize acid burns with bases. Always seek professional medical treatment for any exposure incident.

How to dispose of Sulfuric Acid appropriately?

Sulfuric Acid disposal must comply with local environmental regulations and waste management protocols. It cannot be disposed of in regular drains or waste streams. The acid should be neutralized by qualified professionals before disposal or collected by licensed hazardous waste contractors. Small quantities may be carefully neutralized with appropriate bases under controlled conditions, but this should only be performed by trained personnel following proper procedures.

How to transport Sulfuric Acid?

Sulfuric Acid is classified as ADR Class 8 (corrosive substances), Packing Group II, indicating its high corrosive hazard during transport. It requires specialized packaging meeting UN specifications and appropriate hazard labeling with GHS05 pictograms. Transportation must comply with ADR regulations, including proper documentation, vehicle marking, and driver certification. Only approved containers and certified carriers should handle the transportation of this corrosive material.

Is Sulfuric Acid subject to specific regulations?

Sulfuric Acid is regulated under multiple European frameworks including REACH and CLP regulations. It carries the danger signal word and must display GHS05 corrosive pictograms on packaging and safety data sheets. While not classified as a Substance of Very High Concern (SVHC), it requires proper registration, classification, and labeling. Industrial users must comply with occupational exposure limits and implement appropriate risk management measures according to regulatory requirements.

Where to buy Sulfuric Acid in Europe?

Sulfuric Acid is available through OYSI, a European chemical distributor specializing in technical chemical products. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality products meeting industrial standards and provides technical support for customers requiring Sulfuric Acid for their industrial applications and processes.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.