Hydrogen chloride

ClH

hydrogen chloride

CAS7647-01-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7647-01-0
EC Number
231-595-7
UN Number
1789
Index Number
017-001-00-7
PubChem CID
313

Physical-chemical properties

Molecular Formula
ClH
Molar Mass
36.46 g/mol
IUPAC Name
hydrogen chloride

Chemical Identifiers

InChI
InChI=1S/ClH/h1H
InChI Key
VEXZGXHMUGYJMC-UHFFFAOYSA-N

Overview

Hydrogen chloride (CAS 7647-01-0) is a highly corrosive inorganic gas with strong acidic properties and excellent solubility in water. This colorless, pungent gas represents one of the most important industrial chemicals in modern manufacturing processes. With the molecular formula ClH and a molar mass of 36.46 g/mol, hydrogen chloride demonstrates exceptional reactivity and serves as a fundamental building block for numerous chemical syntheses. The compound's classification under GHS pictograms GHS05 and GHS07 with the danger signal word reflects its significant corrosive potential and ability to cause severe skin burns and eye damage. Hydrogen chloride exhibits remarkable solubility in water, forming hydrochloric acid solutions that are extensively utilized across various industries. The gas displays typical characteristics of a strong acid, readily donating protons in aqueous solutions and participating in acid-base reactions. Its corrosive nature, classified as Skin Corr. 1B, necessitates stringent safety protocols during handling and storage. The ADR Class 8 designation underscores its classification as a corrosive substance requiring specialized transportation procedures. Primary industrial applications include metal surface treatment and pickling operations, where hydrogen chloride effectively removes oxide layers and prepares surfaces for further processing. The chemical industry extensively employs this compound in the production of chlorinated organic compounds and as a catalyst in various synthetic pathways. Additionally, it plays a crucial role in pH adjustment processes, similar to other acidic compounds like potassium hydrogen sulfate, though with significantly different handling requirements. The semiconductor industry also relies on high-purity hydrogen chloride for silicon wafer etching and cleaning procedures, demanding exceptional quality standards for electronic-grade applications. OYSI provides reliable access to hydrogen chloride for European industrial customers, supporting diverse manufacturing requirements across multiple sectors.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1789
ADR Class8
Packing GroupII
ADR Labels8
Tunnel CodeE
Proper Shipping NameSALZSÄURE
Marine PollutantNo

Frequently Asked Questions

What is hydrogen chloride?

Hydrogen chloride is a highly corrosive inorganic compound with the chemical formula ClH and CAS number 7647-01-0. This colorless gas has a molecular weight of 36.46 g/mol and is classified as a dangerous substance with corrosive properties (Skin Corr. 1B) and specific target organ toxicity (STOT SE 3). It readily dissolves in water to form hydrochloric acid and is characterized by its pungent, irritating odor that can be detected at very low concentrations.

What are the physicochemical properties of hydrogen chloride?

Hydrogen chloride is a colorless gas at room temperature with a sharp, pungent odor that is highly irritating to mucous membranes. It has excellent solubility in water, forming hydrochloric acid solutions, and is also soluble in alcohols and ethers. The compound has a boiling point of -85°C and a melting point of -114°C. It is heavier than air with a density of approximately 1.49 g/L at standard conditions and exhibits strong corrosive properties toward metals and organic materials.

What is hydrogen chloride used for?

Hydrogen chloride is primarily used in the production of hydrochloric acid, which serves numerous industrial applications including metal cleaning, ore processing, and chemical synthesis. It plays a crucial role in manufacturing PVC plastics, pharmaceuticals, and various organic compounds through chlorination reactions. The compound is also essential in semiconductor manufacturing for etching processes, oil well acidizing operations, and as a catalyst in petrochemical processes. Additionally, it's used in food processing as an acidifying agent.

How to handle hydrogen chloride safely?

Hydrogen chloride requires strict safety measures due to its corrosive nature and classification as Skin Corr. 1B and STOT SE 3. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection with appropriate gas filters. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Emergency eyewash stations and safety showers must be readily accessible. The danger signal and GHS pictograms GHS05 and GHS07 indicate serious corrosive and health hazards requiring careful handling protocols.

How to store hydrogen chloride correctly?

Hydrogen chloride must be stored in tightly sealed, corrosion-resistant containers in cool, dry, well-ventilated areas away from direct sunlight and heat sources. Storage areas should be equipped with appropriate ventilation systems and gas detection equipment. The compound should be kept separate from metals, bases, and organic materials to prevent dangerous reactions. Containers must be properly labeled with danger warnings and GHS pictograms. Storage facilities should comply with local regulations for corrosive substances and maintain temperatures below 25°C when possible.

What to do in case of contact with hydrogen chloride?

Hydrogen chloride exposure requires immediate emergency response due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush affected areas with large amounts of water for at least 15 minutes. In case of eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. For ingestion, do not induce vomiting and seek emergency medical care. All exposures require prompt medical evaluation due to potential serious tissue damage.

How to dispose of hydrogen chloride appropriately?

Hydrogen chloride disposal must comply with local and international waste regulations as it is classified as hazardous waste under ADR Class 8. Small quantities can be neutralized carefully with alkaline solutions under controlled conditions by trained personnel. Large quantities require disposal through licensed hazardous waste contractors. Never discharge directly into sewers, waterways, or soil. Waste containers must be properly labeled and stored in designated areas. Disposal methods should follow national waste management regulations and may require special permits for transportation and treatment.

How to transport hydrogen chloride?

Hydrogen chloride is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating high danger level during transport. It requires specialized packaging approved for corrosive gases and must be transported in vehicles equipped with appropriate safety equipment and ventilation systems. Transport documents must include proper shipping names, hazard classes, and emergency response information. Drivers must hold valid ADR certification for Class 8 substances. Emergency response equipment including neutralizing agents and protective equipment must be available during transport.

Is hydrogen chloride subject to specific regulations?

Hydrogen chloride is subject to comprehensive European regulations including REACH registration requirements and CLP classification as Skin Corr. 1B and STOT SE 3 with danger signal word. It is not currently listed as an SVHC (Substance of Very High Concern). The compound must comply with industrial emissions regulations, workplace exposure limits, and ADR transport requirements. Manufacturing and use may require specific permits and safety assessments. Companies handling hydrogen chloride must implement appropriate risk management measures and maintain safety data sheets compliant with current regulations.

Where to buy hydrogen chloride in Europe?

Hydrogen chloride is available through OYSI, a specialized European distributor of industrial chemicals serving various sectors across Europe. OYSI provides high-quality hydrogen chloride with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures reliable supply chains and technical support for industrial customers. For procurement, contact OYSI directly to discuss specific requirements, quantities, and delivery options. Professional buyers should provide appropriate documentation demonstrating legitimate industrial use and proper handling capabilities.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.