Hydrogen chloride

ClH

hydrogen chloride

CAS7647-01-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7647-01-0
EC Number
231-595-7
UN Number
1789
Index Number
017-001-00-7
PubChem CID
313

Physical-chemical properties

Molecular Formula
ClH
Molar Mass
36.46 g/mol
IUPAC Name
hydrogen chloride

Chemical Identifiers

InChI
InChI=1S/ClH/h1H
InChI Key
VEXZGXHMUGYJMC-UHFFFAOYSA-N

Overview

Hydrogen chloride (CAS 7647-01-0) is a diatomic gas with highly corrosive properties and strong acidic characteristics when dissolved in water. This colorless, pungent gas represents one of the most important inorganic compounds in industrial chemistry, serving as a fundamental building block for numerous chemical processes. With the molecular formula ClH and a molar mass of 36.46 g/mol, hydrogen chloride exhibits exceptional solubility in water, forming hydrochloric acid - a cornerstone chemical in various manufacturing applications. The compound's classification under STOT SE 3 and Skin Corr. 1B hazard classes, along with its "Danger" signal word and corresponding GHS pictogrammes (GHS05, GHS07), underscores the critical importance of proper handling protocols. Hydrogen chloride demonstrates highly corrosive properties toward metals, organic materials, and biological tissues. Its vapor forms dense white fumes in moist air due to the formation of hydrochloric acid droplets. The substance requires specialized storage and transport conditions, classified under ADR Class 8 for corrosive materials. Safety measures must include appropriate ventilation systems, corrosion-resistant equipment, and comprehensive personal protective equipment to prevent exposure through inhalation or skin contact. Industrial applications encompass steel pickling processes, where it removes oxide scales and rust from metal surfaces, pharmaceutical intermediate synthesis, and semiconductor manufacturing for silicon wafer cleaning. The compound also plays a crucial role in producing various chloride salts and serves as a pH adjustment agent in water treatment applications. Unlike more specialized compounds such as tribromophosphane used in specific synthesis reactions, hydrogen chloride maintains broad applicability across multiple industrial sectors. OYSI provides reliable access to high-quality hydrogen chloride for European industrial customers, ensuring consistent supply chain support for critical manufacturing processes.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1789
ADR Class8
Packing GroupII
ADR Labels8
Tunnel CodeE
Proper Shipping NameSALZSÄURE
Marine PollutantNo

Frequently Asked Questions

What is hydrogen chloride?

Hydrogen chloride is a highly corrosive inorganic compound with the chemical formula HCl and CAS number 7647-01-0. This colorless gas has a molecular weight of 36.46 g/mol and is classified as a dangerous substance with corrosive properties (Skin Corr. 1B) and specific target organ toxicity (STOT SE 3). It readily dissolves in water to form hydrochloric acid and is characterized by its pungent, irritating odor that can be detected at very low concentrations.

What are the physicochemical properties of hydrogen chloride?

Hydrogen chloride is a colorless gas at room temperature with an extremely pungent and suffocating odor. It has a boiling point of -85°C and is highly soluble in water, forming hydrochloric acid upon dissolution. The compound is heavier than air with a density of approximately 1.27 kg/m³ at standard conditions. It is non-flammable but highly reactive, particularly with metals and basic substances, producing hydrogen gas and corresponding chlorides.

What is hydrogen chloride used for?

Hydrogen chloride is primarily used in the production of hydrochloric acid, one of the most important industrial chemicals. It serves as a key intermediate in manufacturing PVC plastics, pharmaceuticals, and various organic compounds through hydrochlorination reactions. The compound is also utilized in metal processing for pickling and cleaning operations, in the production of chlorides, and as a catalyst in chemical synthesis. Additionally, it plays a role in semiconductor manufacturing and water treatment applications.

How to handle hydrogen chloride safely?

Hydrogen chloride requires strict safety measures due to its corrosive nature and toxicity. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Work should be conducted in fume hoods or with adequate ventilation systems to prevent inhalation. Emergency shower and eyewash stations must be readily accessible. All equipment should be made of compatible materials, and proper training on emergency procedures is essential before handling.

How to store hydrogen chloride correctly?

Hydrogen chloride must be stored in cool, dry, well-ventilated areas away from incompatible materials such as alkalis, metals, and oxidizing agents. Containers should be made of suitable materials like polyethylene or PTFE, and storage areas must be equipped with appropriate ventilation systems. The compound should be kept away from heat sources and moisture, as it readily absorbs water from air. Storage facilities must comply with local regulations and include emergency response equipment and spill containment measures.

What to do in case of contact with hydrogen chloride?

Hydrogen chloride exposure requires immediate emergency response due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. For ingestion, do not induce vomiting and seek immediate medical care. Always consult poison control centers promptly.

How to dispose of hydrogen chloride appropriately?

Hydrogen chloride disposal must comply with local environmental regulations and waste management protocols. The compound cannot be disposed of in regular waste streams due to its hazardous classification. Proper neutralization with appropriate alkaline solutions under controlled conditions may be required before disposal. Licensed waste management companies specializing in hazardous chemical disposal should handle the process. All disposal activities must be documented and reported according to regulatory requirements, ensuring environmental protection and legal compliance.

How to transport hydrogen chloride?

Hydrogen chloride is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating significant transport hazards. Transportation requires specialized containers meeting UN packaging standards and proper hazard labeling with GHS05 and GHS07 pictograms. Vehicles must carry appropriate emergency equipment and documentation including safety data sheets. Drivers need specialized training for dangerous goods transport, and routes should avoid populated areas when possible. Emergency response procedures must be readily available during transport.

Is hydrogen chloride subject to specific regulations?

Hydrogen chloride is subject to comprehensive European regulations including REACH registration requirements and CLP classification as a corrosive substance with danger signal word. It is not listed as a Substance of Very High Concern (SVHC), but strict workplace exposure limits apply under occupational health directives. The compound requires safety data sheets, proper labeling with GHS pictograms (GHS05, GHS07), and compliance with industrial emissions regulations. Users must implement appropriate risk management measures and report usage according to regulatory requirements.

Where to buy hydrogen chloride in Europe?

Hydrogen chloride is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality hydrogen chloride with complete regulatory documentation, safety data sheets, and technical support for industrial applications. As a professional chemical distributor, OYSI ensures compliance with European regulations and offers reliable supply chain solutions for businesses requiring this corrosive compound for their manufacturing processes and chemical operations.

Digital Product Passport available

EU DPP

A Digital Product Passport (DPP) compliant with EU regulations is available for this substance. The passport contains complete information on composition, safety, and sustainability.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.