Sulfur dioxide

O2S

sulfur dioxide

CAS7446-09-5
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7446-09-5
EC Number
231-195-2
UN Number
1079
Index Number
016-011-00-9
PubChem CID
1119

Physical-chemical properties

Molecular Formula
O2S
Molar Mass
64.07 g/mol
IUPAC Name
sulfur dioxide

Chemical Identifiers

InChI
InChI=1S/O2S/c1-3-2
InChI Key
RAHZWNYVWXNFOC-UHFFFAOYSA-N

Overview

Sulfur dioxide (CAS 7446-09-5) is an inorganic gas compound with strong reducing properties and characteristic pungent odor. This colorless gas with the molecular formula O2S represents one of the most significant sulfur compounds in industrial chemistry. With a molecular weight of 64.07 g/mol, sulfur dioxide exhibits high solubility in water and polar solvents, forming sulfurous acid solutions. The compound's distinctive sharp, irritating smell makes it easily detectable even at low concentrations, serving as a natural warning system for potential exposure risks. From a safety perspective, sulfur dioxide presents multiple hazards requiring careful handling protocols. Classified as a pressurized gas with acute toxicity category 3, it poses serious respiratory risks and can cause severe skin and eye corrosion. The compound's classification as STOT SE 1 indicates its potential for specific target organ toxicity, particularly affecting the respiratory system. Like other reactive gases such as ethylene oxide, proper containment and ventilation systems are essential for safe industrial handling. Industrial applications of sulfur dioxide span several key sectors. The compound serves as a crucial intermediate in sulfuric acid production through the contact process, representing one of the largest volume chemical manufacturing operations globally. In food processing, it functions as an effective preservative and antioxidant, particularly in wine production and dried fruit preservation. Additionally, sulfur dioxide plays important roles in pulp and paper bleaching processes and serves as a reducing agent in various metallurgical applications. OYSI provides high-quality sulfur dioxide to European industrial customers, ensuring compliance with stringent safety and purity standards for diverse technical applications.

Safety & Classification

Danger
Classification:

Press. Gas; Acute Tox. 3; STOT SE 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H331

Toxic if inhaled.

H370

Causes damage to organs.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1079
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameSchwefeldioxid, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is sulfur dioxide?

Sulfur dioxide is a toxic gas with the chemical formula O2S and CAS number 7446-09-5. This compound has a molecular weight of 64.07 g/mol and is classified as a pressurized gas with acute toxicity properties. It causes severe skin corrosion and specific target organ toxicity. The substance is widely recognized for its pungent, irritating odor and is considered hazardous, requiring careful handling and appropriate safety measures in industrial applications.

What are the physicochemical properties of sulfur dioxide?

Sulfur dioxide is a colorless gas at room temperature with a characteristic sharp, suffocating odor. It is highly soluble in water, forming sulfurous acid, and can be easily liquefied under pressure. The gas is heavier than air with a density approximately twice that of air. It is non-flammable but supports combustion of certain materials. The substance readily dissolves in polar solvents and exhibits strong reducing properties in chemical reactions.

What is sulfur dioxide used for?

Sulfur dioxide serves multiple industrial purposes, primarily as a preservative in food and beverage industries, particularly wine production. It is extensively used in paper and pulp bleaching processes, as a refrigerant in industrial cooling systems, and in the production of sulfuric acid. The chemical also functions as a disinfectant and fumigant, and plays a crucial role in metal ore processing and petroleum refining operations.

How to handle sulfur dioxide safely?

Sulfur dioxide requires strict safety protocols including full-face respiratory protection, chemical-resistant gloves, and protective clothing due to its corrosive nature. Work must be conducted in well-ventilated areas or under fume extraction systems. Personnel should be trained in emergency procedures and have access to emergency eyewash stations. Gas detection equipment is essential to monitor concentration levels and prevent exposure above permissible limits.

How to store sulfur dioxide correctly?

Sulfur dioxide must be stored in cool, dry, well-ventilated areas away from heat sources and incompatible materials such as strong bases, oxidizing agents, and metals. Pressurized containers should be secured upright and protected from physical damage. Storage areas require gas detection systems and emergency ventilation. The substance should be kept separate from food products and living areas, with restricted access to authorized personnel only.

What to do in case of contact with sulfur dioxide?

Sulfur dioxide exposure requires immediate action: move the victim to fresh air and seek medical attention. For skin contact, remove contaminated clothing and rinse affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, flush immediately with water and seek urgent medical care. If inhaled, provide oxygen if available and monitor for respiratory distress. Never induce vomiting if ingested.

How to dispose of sulfur dioxide appropriately?

Sulfur dioxide disposal must comply with local and European waste regulations as hazardous waste. The substance cannot be released directly into the environment and requires specialized treatment facilities. Small quantities can be neutralized with alkaline solutions under controlled conditions. Containers must be completely emptied and properly decontaminated before disposal. Professional waste management services specializing in hazardous gases should handle larger quantities and contaminated equipment.

How to transport sulfur dioxide?

Sulfur dioxide is classified under ADR Class 2 for transport as a compressed gas. It requires specialized pressure vessels and proper labeling with appropriate hazard placards. Vehicles must be equipped with emergency equipment and drivers need hazardous materials certification. Transport documentation must include proper shipping names, hazard classes, and emergency response information. Only authorized carriers with appropriate equipment and training should handle the transportation.

Is sulfur dioxide subject to specific regulations?

Sulfur dioxide is subject to comprehensive European regulations including REACH registration requirements and CLP classification obligations. It is not listed as a Substance of Very High Concern (SVHC) but requires safety data sheets and hazard communication. Industrial emissions are regulated under environmental legislation, and occupational exposure limits apply in workplace settings. Food industry use is governed by specific additive regulations with maximum permitted concentrations.

Where to buy sulfur dioxide in Europe?

Sulfur dioxide is available through OYSI, a trusted European chemical distributor specializing in industrial chemicals. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional distributor, OYSI ensures quality standards and can assist with technical specifications, safety requirements, and logistics coordination for sulfur dioxide procurement throughout European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.