Sulfur dioxide

O2S

sulfur dioxide

CAS7446-09-5
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

Consulting for Sulfur dioxide

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
7446-09-5
EC Number
231-195-2
UN Number
1079
Index Number
016-011-00-9
PubChem CID
1119

Physical-chemical properties

Molecular Formula
O2S
Molar Mass
64.07 g/mol
IUPAC Name
sulfur dioxide

Chemical Identifiers

InChI
InChI=1S/O2S/c1-3-2
InChI Key
RAHZWNYVWXNFOC-UHFFFAOYSA-N

Overview

Sulfur dioxide (CAS 7446-09-5) is a toxic inorganic gas compound with strong reducing properties and characteristic pungent odor. This colorless gas represents one of the most significant sulfur compounds in industrial chemistry, playing crucial roles across multiple sectors from food preservation to chemical manufacturing. With its molecular formula O2S and molecular weight of 64.07 g/mol, sulfur dioxide exhibits unique chemical properties that make it both valuable and hazardous in industrial applications. The compound's classification under multiple danger categories reflects its serious safety profile. As a pressurized gas with acute toxicity (Category 3), sulfur dioxide poses immediate respiratory risks and can cause severe chemical burns due to its corrosive nature (Skin Corr. 1B). The substance also presents specific target organ toxicity concerns (STOT SE 1), requiring stringent handling protocols and specialized safety equipment. Its ADR Class 2 classification mandates specific transportation and storage requirements under dangerous goods regulations. Industrially, sulfur dioxide serves primarily in sulfuric acid production, where it acts as a key intermediate in the contact process. The food and beverage industry utilizes its antimicrobial and antioxidant properties for preservation, particularly in wine production and dried fruit processing. Additionally, the compound functions as a bleaching agent in textile manufacturing and plays a role in metallurgical processes for ore treatment. Unlike related compounds such as ethylene oxide or sulfuryl difluoride, sulfur dioxide's high water solubility and reducing characteristics make it particularly suitable for specific chemical synthesis applications. Its reactivity profile differs significantly from these alternatives, offering unique advantages in targeted industrial processes. OYSI supplies sulfur dioxide to qualified industrial customers throughout Europe, ensuring compliance with all relevant safety and transportation regulations.

Safety & Classification

Danger
Classification:

Press. Gas; Acute Tox. 3; STOT SE 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H331

Toxic if inhaled.

H370

Causes damage to organs.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1079
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameSchwefeldioxid, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is sulfur dioxide?

Sulfur dioxide is a toxic gas with the chemical formula SO₂ and CAS number 7446-09-5. This compound has a molecular weight of 64.07 g/mol and is classified as a pressurized gas with acute toxicity. It's characterized by its pungent, irritating odor and is considered highly dangerous due to its corrosive properties and ability to cause severe respiratory damage upon inhalation.

What are the physicochemical properties of sulfur dioxide?

Sulfur dioxide is a colorless gas at room temperature with a characteristic sharp, suffocating odor. It's highly soluble in water, forming sulfurous acid, and can be liquefied under pressure. The gas is heavier than air with a density of approximately 2.6 kg/m³. It's non-flammable but supports combustion and can react violently with certain materials, particularly bases and oxidizing agents.

What is sulfur dioxide used for?

Sulfur dioxide serves primarily as a preservative in food and beverage industries, particularly in wine production. It's extensively used in chemical manufacturing for producing sulfuric acid, sulfites, and other sulfur compounds. Additional applications include bleaching of textiles and paper, fumigation processes, and as a reducing agent in various industrial processes. It's also used in metal refining and as a refrigerant.

How to handle sulfur dioxide safely?

Sulfur dioxide requires strict safety protocols including full respiratory protection with supplied air systems and chemical-resistant protective clothing. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin and eye contact completely, as it causes severe chemical burns. Emergency eyewash stations and safety showers must be immediately accessible. Only trained personnel should handle this substance.

How to store sulfur dioxide correctly?

Sulfur dioxide must be stored in pressurized containers in cool, dry, well-ventilated areas away from heat sources and direct sunlight. Keep containers upright and secure to prevent falling. Store separately from incompatible materials including strong bases, oxidizing agents, and reactive metals. Storage areas should have appropriate gas detection systems and emergency ventilation. Regular container inspection is essential.

What to do in case of contact with sulfur dioxide?

Immediate evacuation from the exposure area to fresh air is critical for inhalation exposure. Remove contaminated clothing and flush affected skin with copious amounts of water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes. Seek immediate medical attention for all exposures. Do not induce vomiting if ingested. Provide oxygen if breathing is difficult.

How to dispose of sulfur dioxide appropriately?

Sulfur dioxide disposal must comply with local environmental regulations as hazardous waste. Small quantities can be neutralized by bubbling through sodium hydroxide solution under controlled conditions. Larger quantities require professional hazardous waste disposal services. Never release directly into the environment. Empty containers must be properly decontaminated and disposed of through authorized waste management facilities following applicable waste codes.

How to transport sulfur dioxide?

Sulfur dioxide is classified under ADR Class 2 (gases) for transport purposes. It must be shipped in approved pressure vessels with proper hazard labels and documentation. Transport vehicles require appropriate placarding and emergency response information. Only authorized carriers with proper training and equipment should handle transportation. Special permits may be required for certain quantities or routes.

Is sulfur dioxide subject to particular regulations?

Sulfur dioxide is strictly regulated under CLP classification as Acute Tox. 3, STOT SE 1, and Skin Corr. 1B with 'Danger' signal word. It falls under REACH registration requirements but is not classified as an SVHC substance. Industrial use is subject to emission limits and workplace exposure controls. Food industry applications have specific maximum residue limits regulated by food safety authorities.

Where to buy sulfur dioxide in Europe?

Sulfur dioxide is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI provides sulfur dioxide with proper documentation, safety data sheets, and regulatory compliance support. Due to its hazardous nature, purchases typically require business credentials and proof of proper handling capabilities. Contact OYSI directly for availability, specifications, and technical support.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.