Potassium molecular oxygen

KO2+

potassium molecular oxygen

CAS12030-88-5

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Identification

CAS Number
12030-88-5
EC Number
234-746-5
UN Number
2466
PubChem CID
61541

Physical-chemical properties

Molecular Formula
KO2+
Molar Mass
71.10 g/mol
IUPAC Name
potassium molecular oxygen

Chemical Identifiers

InChI
InChI=1S/K.O2/c;1-2/q+1;
InChI Key
CLSKHAYBTFRDOV-UHFFFAOYSA-N

Overview

Potassium molecular oxygen (CAS 12030-88-5) is an inorganic superoxide compound with strong oxidizing properties and oxygen-releasing capabilities. This chemical compound, also known by its CAS number 12030-88-5 and EC number 234-746-5, represents a significant member of the alkali metal superoxide family. With a molecular formula of KO2+ and a molecular weight of 71.097 g/mol, potassium molecular oxygen exhibits distinctive chemical behavior that sets it apart from conventional peroxides and oxides. The compound's classification under ADR Class 5.1 reflects its oxidizing nature, requiring careful handling and storage protocols despite the absence of specific GHS pictograms in standard classifications. The compound's primary characteristic lies in its ability to simultaneously consume carbon dioxide and release oxygen through chemical reactions, making it particularly valuable in controlled atmosphere applications. This dual functionality distinguishes it from related oxidizing agents such as magnesium diperchlorate or barium(2+) dinitrate, which primarily serve as oxidizers without the CO2 absorption capability. The superoxide structure contributes to its reactivity profile, necessitating proper storage conditions to maintain stability and prevent unwanted reactions with moisture or organic materials. Industrial applications for potassium molecular oxygen include specialized breathing apparatus systems, particularly in confined spaces where CO2 removal and oxygen generation are simultaneously required. The compound also finds use in chemical synthesis processes requiring controlled oxygen release and in certain analytical chemistry applications where its unique reactivity profile provides specific advantages. OYSI maintains reliable supply chains for potassium molecular oxygen to support diverse industrial requirements across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2466
ADR Class5.1
Packing GroupI
Tunnel CodeE
Proper Shipping NameKaliumsuperoxid
Marine PollutantNo

Frequently Asked Questions

What is potassium molecular oxygen?

Potassium molecular oxygen is an inorganic superoxide compound with the formula KO2+ and CAS number 12030-88-5. This chemical substance has a molecular weight of 71.097 g/mol and belongs to the class of alkali metal superoxides. It is characterized by its strong oxidizing properties and reactivity with water and organic materials, making it useful in specialized applications requiring oxygen generation or oxidation processes.

What are the physicochemical properties of potassium molecular oxygen?

Potassium molecular oxygen appears as a yellow to orange crystalline solid at room temperature. It exhibits strong oxidizing characteristics due to the presence of the superoxide ion. The compound is highly reactive with water, producing oxygen gas and potassium hydroxide. It demonstrates hygroscopic properties, readily absorbing moisture from air, and shows significant reactivity with organic compounds and reducing agents.

What is potassium molecular oxygen used for?

Potassium molecular oxygen serves primarily as an oxygen-generating agent in emergency breathing apparatus and closed-circuit systems. It finds applications in submarines, spacecraft, and mining rescue equipment where reliable oxygen supply is critical. The compound is also utilized in specialized chemical synthesis processes requiring controlled oxidation reactions and in research applications involving superoxide chemistry and oxygen transfer mechanisms.

How to handle potassium molecular oxygen safely?

Potassium molecular oxygen requires careful handling using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas away from combustible materials, reducing agents, and moisture sources. Use non-metallic tools when possible, avoid friction or impact, and ensure emergency eyewash and shower facilities are readily accessible during handling operations.

How to store potassium molecular oxygen correctly?

Potassium molecular oxygen must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and incompatible materials. Keep containers tightly sealed in original packaging, separated from organic materials, reducing agents, acids, and flammable substances. Storage areas should have appropriate fire suppression systems and be constructed of non-combustible materials to prevent accidental ignition or decomposition.

What to do in case of contact with potassium molecular oxygen?

Immediate removal from exposure is essential following contact with potassium molecular oxygen. For skin contact, brush off dry material carefully and rinse thoroughly with water. In case of eye contact, flush immediately with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately. Remove contaminated clothing and seek medical attention promptly for any exposure, especially if irritation or injury occurs.

How to dispose of potassium molecular oxygen appropriately?

Potassium molecular oxygen disposal must comply with local, national, and EU waste regulations as a hazardous chemical waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be carefully neutralized by slow addition to large amounts of water in controlled conditions, but this should only be performed by trained personnel following established safety protocols and regulatory requirements.

How to transport potassium molecular oxygen?

Potassium molecular oxygen is classified under ADR Class 5.1 (Oxidizing substances) Packing Group I, indicating high transport hazard. Transportation requires UN specification packaging, proper labeling with oxidizing substance placards, and compliance with ADR regulations. Vehicles must carry appropriate emergency equipment, drivers need hazardous materials training, and transport documents must include emergency response information and proper shipping names.

Is potassium molecular oxygen subject to particular regulations?

Potassium molecular oxygen is subject to EU chemical regulations including REACH registration requirements and CLP classification standards. It is not classified as a Substance of Very High Concern (SVHC) under current regulations. Suppliers must provide safety data sheets complying with REACH Annex II, and users must follow occupational exposure limits and risk management measures as specified in applicable safety assessments.

Where to buy potassium molecular oxygen in Europe?

Potassium molecular oxygen is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this compound to industrial customers, research institutions, and specialized applications across Europe. As a professional chemical distributor, OYSI ensures proper packaging, documentation, and regulatory compliance for safe delivery. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.