Lithium nitrate

LiNO3

lithium nitrate

CAS13453-76-4

Consulting for Lithium nitrate

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
13453-76-4
UN Number
2722
PubChem CID
10129889

Physical-chemical properties

Molecular Formula
LiNO3
Molar Mass
69.00 g/mol
IUPAC Name
lithium nitrate

Chemical Identifiers

InChI
InChI=1S/Li.NO3/c;2-1(3)4/q+1;-1
InChI Key
IIPYXGDZVMZOAP-UHFFFAOYSA-N

Overview

Lithium nitrate (CAS 13453-76-4) is an inorganic oxidizing salt with high solubility and hygroscopic properties used in industrial applications. This white crystalline compound represents one of the most water-soluble lithium salts available commercially, making it particularly valuable in applications requiring rapid dissolution and uniform distribution. With its molecular formula LiNO3 and molecular weight of 69 g/mol, lithium nitrate exhibits exceptional stability under normal storage conditions while maintaining its oxidizing characteristics that classify it under ADR class 5.1 for transportation purposes. The compound's hygroscopic nature allows it to readily absorb moisture from the atmosphere, necessitating proper storage in sealed containers to maintain product integrity. Unlike related oxidizing compounds such as magnesium diperchlorate, lithium nitrate offers a more manageable safety profile while still providing effective oxidizing properties. Its high solubility in water exceeds most comparable nitrate salts, reaching approximately 70g per 100g of water at room temperature. Primary industrial applications include its use as an oxidizing agent in pyrotechnic compositions, where it provides clean-burning characteristics and distinctive red coloration. The compound also serves as a precursor in lithium-ion battery electrolyte formulations and as a catalyst component in organic synthesis reactions. Additionally, lithium nitrate finds application in heat transfer salt mixtures for concentrated solar power systems, where its thermal stability and molten salt properties prove advantageous. The absence of specific GHS pictogram requirements under normal handling conditions reflects its relatively moderate hazard profile compared to other oxidizing salts, though standard safety protocols for oxidizing materials should always be observed. OYSI maintains reliable supply chains for technical-grade lithium nitrate to meet European industrial demand across various sectors.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2722
ADR Class5.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameLithiumnitrat-Trihydrat, fest
Marine PollutantNo

Frequently Asked Questions

What is lithium nitrate?

Lithium nitrate is an inorganic salt with the chemical formula LiNO3 and CAS number 13453-76-4. It belongs to the family of alkali metal nitrates and has a molecular weight of 69 g/mol. This compound appears as white crystalline solid and is highly soluble in water. Lithium nitrate is classified as an oxidizing agent and finds applications in various industrial processes, particularly in ceramics, glass manufacturing, and chemical synthesis where lithium compounds are required.

What are the physicochemical properties of lithium nitrate?

Lithium nitrate is a white crystalline solid that is highly hygroscopic, meaning it readily absorbs moisture from air. It has excellent water solubility and also dissolves in alcohols and other polar solvents. The compound is odorless and has a molecular weight of 69 g/mol. It melts at approximately 264°C and decomposes at higher temperatures, releasing oxygen and forming lithium oxide. Its high solubility and hygroscopic nature require careful storage to prevent clumping and degradation.

What is lithium nitrate used for?

Lithium nitrate is primarily used as an oxidizing agent in various industrial applications. It serves as a key ingredient in ceramic glazes and glass manufacturing, where it acts as a flux and helps reduce thermal expansion. The compound is also utilized in the production of other lithium compounds, in pyrotechnics for red flame coloration, and in specialty chemical synthesis. Additionally, it finds applications in heat transfer systems and as a component in certain types of batteries and electrochemical devices.

How to handle lithium nitrate safely?

Lithium nitrate should be handled with standard personal protective equipment including safety glasses, gloves, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas to avoid inhalation of dust particles. As an oxidizing agent, keep it away from combustible materials, reducing agents, and heat sources. Use non-sparking tools and equipment when handling. Ensure proper grounding to prevent static electricity buildup. Wash hands thoroughly after handling and avoid eating, drinking, or smoking in work areas.

How to store lithium nitrate correctly?

Lithium nitrate should be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly sealed to prevent moisture absorption due to its hygroscopic nature. Store away from combustible materials, organic compounds, and reducing agents as it is an oxidizing substance. Use appropriate secondary containment and ensure storage areas are equipped with proper fire suppression systems. Keep away from heat sources and direct sunlight. Regular inspection of containers for damage or deterioration is recommended.

What to do in case of contact with lithium nitrate?

Lithium nitrate contact requires immediate attention depending on the exposure route. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and monitor breathing. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific guidance.

How to dispose of lithium nitrate appropriately?

Lithium nitrate disposal must comply with local, national, and international waste regulations. The compound should not be disposed of in regular household waste due to its oxidizing properties. Contact licensed waste disposal companies that specialize in chemical waste management. Small quantities may be neutralized and disposed of according to local environmental regulations. Always check with local authorities for specific disposal requirements. Ensure proper documentation and tracking of waste disposal activities as required by applicable regulations.

How to transport lithium nitrate?

Lithium nitrate is classified under ADR Class 5.1 (Oxidizing substances) Packing Group III for transportation purposes. It must be packaged in UN-approved containers and properly labeled with appropriate hazard placards. Transport vehicles should be equipped with appropriate safety equipment and drivers must have proper training for hazardous materials transport. Ensure compliance with national and international transport regulations including proper documentation, shipping papers, and emergency response information during transit.

Is lithium nitrate subject to specific regulations?

Lithium nitrate is subject to various chemical regulations including REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) in Europe. It is not classified as a Substance of Very High Concern (SVHC) under REACH. The compound falls under CLP (Classification, Labelling and Packaging) regulations as an oxidizing substance. Transport is regulated under ADR/RID for road and rail transport. Users must comply with occupational safety regulations and may need to maintain safety data sheets and conduct risk assessments.

Where to buy lithium nitrate in Europe?

Lithium nitrate is available through OYSI, a European distributor of technical chemicals serving various industries across Europe. OYSI provides reliable supply chains and technical support for lithium nitrate procurement. When purchasing, ensure the supplier provides proper documentation including safety data sheets, certificates of analysis, and compliance certificates. Consider factors such as purity requirements, packaging options, and delivery logistics. Always verify that suppliers meet relevant quality standards and regulatory requirements for your specific application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.