Potassium

K

potassium

CAS7440-09-7
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7440-09-7
EC Number
231-119-8
UN Number
2257
Index Number
019-001-00-2
PubChem CID
5462222

Physical-chemical properties

Molecular Formula
K
Molar Mass
39.10 g/mol
IUPAC Name
potassium

Chemical Identifiers

InChI
InChI=1S/K
InChI Key
ZLMJMSJWJFRBEC-UHFFFAOYSA-N

Overview

Potassium (CAS 7440-09-7) is a highly reactive alkali metal with exceptional water reactivity and corrosive properties. This silvery-white metallic element belongs to Group 1 of the periodic table and represents one of the most chemically active metals in industrial applications. With its molecular formula K and molar mass of 39.0983 g/mol, potassium exhibits extreme reactivity with water, producing hydrogen gas and potassium hydroxide in a vigorous exothermic reaction. The metal's high reactivity necessitates storage under inert conditions, typically in mineral oil or inert atmosphere environments. Potassium shares similar chemical behavior with other alkali metals such as lithium and sodium, though it demonstrates even greater reactivity than sodium. The metal appears as a soft, silvery material that can be cut with a knife, revealing a bright metallic surface that quickly tarnishes upon air exposure. Its classification as Water-react. 1 and Skin Corr. 1B under GHS regulations, along with the danger signal word and corresponding pictogrammes GHS02 and GHS05, emphasizes the critical safety considerations required for handling this substance. Primary industrial applications include specialized chemical synthesis where potassium metal serves as a powerful reducing agent, production of potassium compounds for various industrial processes, and use in certain metallurgical applications requiring strong reducing conditions. The metal's ADR class 4.3 classification reflects its dangerous goods status for transportation, requiring specialized handling protocols and packaging requirements. Due to its highly reactive nature and specialized applications, potassium metal finds use primarily in controlled industrial environments where proper safety infrastructure and expertise are available. OYSI supplies high-quality potassium metal to qualified industrial customers across Europe, ensuring compliance with all relevant safety and transportation regulations.

Safety & Classification

Danger
Classification:

Water-react. 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H260

In contact with water releases flammable gases which may ignite spontaneously.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2257
ADR Class4.3
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameKalium
Marine PollutantNo

Frequently Asked Questions

What is potassium?

Potassium is a highly reactive alkali metal with the chemical symbol K and CAS number 7440-09-7. This soft, silvery-white metallic element has a molecular weight of 39.0983 g/mol and belongs to Group 1 of the periodic table. Potassium is classified as a water-reactive substance (Water-react. 1) and skin corrosive material (Skin Corr. 1B), requiring careful handling due to its extreme reactivity with water and moisture.

What are the physicochemical properties of potassium?

Potassium is a soft, silvery-white metal that can be cut with a knife at room temperature. It has a low melting point of 63.5°C and readily oxidizes in air, forming a dull oxide layer. The metal is extremely reactive with water, producing hydrogen gas and potassium hydroxide in a violent exothermic reaction. It must be stored under inert conditions to prevent oxidation and moisture contact.

What is potassium used for?

Potassium metal is primarily used in specialized industrial applications including organic synthesis as a reducing agent, production of potassium compounds, and in certain alloy formations. It serves as a reagent in pharmaceutical manufacturing and chemical research. Due to its high reactivity, metallic potassium is mainly used in controlled laboratory and industrial settings where its unique reducing properties are specifically required for synthetic processes.

How to handle potassium safely?

Potassium requires extreme caution during handling due to its water-reactive and corrosive properties. Essential PPE includes chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in a dry, inert atmosphere using nitrogen or argon gas. Never allow contact with water or moisture. Use appropriate tools to handle the metal and ensure adequate ventilation. Emergency shower and eyewash stations should be readily accessible.

How to store potassium correctly?

Potassium must be stored under mineral oil or in an inert atmosphere (nitrogen or argon) in tightly sealed containers to prevent contact with air and moisture. Storage areas should be cool, dry, and well-ventilated. The substance is incompatible with water, alcohols, acids, and oxidizing agents. Storage containers should be made of appropriate materials and clearly labeled with hazard warnings according to GHS requirements.

What to do in case of contact with potassium?

Potassium contact requires immediate action due to its corrosive nature. For skin contact, immediately brush off any solid particles (do not use water initially), then flush with large amounts of water and seek medical attention. For eye contact, flush immediately with water for at least 15 minutes and get medical help. In case of ingestion, do not induce vomiting and seek immediate medical assistance. Never use water on potassium fires.

How to dispose of potassium appropriately?

Potassium disposal must follow strict hazardous waste regulations and should only be performed by qualified personnel. Small quantities can be carefully reacted with appropriate alcohols under controlled conditions to neutralize reactivity. Larger amounts require specialized waste disposal companies licensed for hazardous materials. Never dispose of potassium in regular waste streams or pour down drains. Contact local environmental authorities for specific disposal requirements in your region.

How to transport potassium?

Potassium is classified under ADR Class 4.3 (substances which in contact with water emit flammable gases), Packing Group I, indicating highest danger level. It requires specialized packaging that prevents moisture ingress and appropriate labeling with GHS02 (flame) and GHS05 (corrosion) pictogrammes. Transportation must comply with dangerous goods regulations, using approved containers and documentation. Only qualified carriers experienced in hazardous materials should handle potassium shipments.

Is potassium subject to specific regulations?

Potassium is regulated under multiple European frameworks including CLP Regulation for classification and labeling, requiring 'Danger' signal word and specific hazard pictogrammes. REACH registration applies for commercial use. Transport falls under ADR dangerous goods regulations (Class 4.3). While not currently listed as an SVHC substance, its water-reactive and corrosive properties subject it to strict occupational safety requirements and waste disposal regulations across EU member states.

Where to buy potassium in Europe?

Potassium metal is available through specialized chemical distributors like OYSI, a European supplier of technical chemicals. Due to its hazardous nature and regulatory requirements, potassium is typically sold only to qualified industrial users, research institutions, and laboratories with appropriate handling capabilities. Purchasers must demonstrate proper storage facilities, safety protocols, and regulatory compliance. Contact OYSI for availability, technical specifications, and regulatory documentation for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.