Potassium
K
potassium
Consulting for Potassium
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Identification
- CAS Number
- 7440-09-7
- EC Number
- 231-119-8
- UN Number
- 2257
- Index Number
- 019-001-00-2
- PubChem CID
- 5462222
Physical-chemical properties
- Molecular Formula
- K
- Molar Mass
- 39.10 g/mol
- IUPAC Name
- potassium
Chemical Identifiers
- InChI
- InChI=1S/K
- InChI Key
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N
Overview
Potassium (CAS 7440-09-7) is a highly reactive alkali metal with exceptional water reactivity and strong reducing properties. This silvery-white metallic element belongs to Group 1 of the periodic table and represents one of the most chemically active metals in industrial applications. With its atomic symbol K derived from the Latin "kalium," potassium exhibits remarkable characteristics that make it both valuable and challenging to handle in technical environments. The metal's extreme reactivity with water produces hydrogen gas and potassium hydroxide, generating significant heat that can lead to ignition of the evolved hydrogen. Potassium shares similar properties with other alkali metals, particularly sodium and lithium, though it demonstrates even greater reactivity than its lighter counterparts. This enhanced reactivity necessitates storage under inert atmospheres or mineral oil to prevent contact with moisture and oxygen. The metal's low melting point of 63.5°C and its tendency to form a characteristic violet flame when burned are distinctive physical properties utilized in various analytical applications. From a safety perspective, potassium requires careful handling protocols due to its classification as Water-react. 1 and Skin Corr. 1B under GHS regulations. The associated danger pictograms GHS02 and GHS05 indicate both fire hazard and corrosive properties, while its ADR classification 4.3 designates it as a substance that emits flammable gases when in contact with water. Industrial applications include organic synthesis as a powerful reducing agent, production of potassium compounds for fertilizers and specialty chemicals, and use in certain metallurgical processes. The pharmaceutical industry also utilizes potassium in various synthetic pathways where strong reducing conditions are required. OYSI maintains reliable supply chains for potassium and related alkali metals, ensuring consistent availability for European technical applications.
Safety & Classification
Water-react. 1; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2257 |
| ADR Class | 4.3 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Kalium |
| Marine Pollutant | No |
Frequently Asked Questions
What is potassium?
Potassium is a highly reactive alkali metal with the chemical symbol K and CAS number 7440-09-7. It is a soft, silvery-white metallic element that belongs to Group 1 of the periodic table. With a molecular weight of 39.0983 g/mol, potassium is essential for biological processes but extremely dangerous in its pure metallic form due to its violent reaction with water and air.
What are the physicochemical properties of potassium?
Potassium is a soft, silvery-white metal that can be easily cut with a knife at room temperature. It has a low melting point of 63.5°C and rapidly tarnishes when exposed to air, forming a dull oxide layer. The metal is highly reactive with water, producing hydrogen gas and potassium hydroxide in a vigorous exothermic reaction that can cause ignition.
What is potassium used for?
Potassium metal is primarily used in specialized chemical synthesis and as a reducing agent in organic chemistry reactions. It serves in the production of potassium compounds, acts as a catalyst in certain industrial processes, and is utilized in laboratory applications for preparing other alkali metal derivatives. Its high reactivity makes it valuable for specific metallurgical applications and research purposes.
How to handle potassium safely?
Potassium requires extreme caution during handling due to its Water-react. 1 and Skin Corr. 1B classifications. Always wear chemical-resistant gloves, safety goggles, and protective clothing. Handle only in inert atmosphere (nitrogen or argon) to prevent oxidation. Keep away from water, moisture, and oxidizing agents. Use appropriate fume hoods and ensure emergency shower/eyewash stations are accessible.
How to store potassium correctly?
Potassium must be stored under inert conditions, typically immersed in mineral oil or kerosene to prevent contact with air and moisture. Store in cool, dry areas away from water sources, acids, and oxidizing materials. Use appropriate containers that prevent oxygen ingress and maintain temperatures below 40°C. Ensure storage areas have proper ventilation and fire suppression systems.
What to do in case of contact with potassium?
Immediate action is crucial for potassium contact due to its corrosive nature. For skin contact, brush off any solid particles (do not use water initially), then rinse with copious amounts of water. For eye contact, flush immediately with water for at least 15 minutes. If ingested, do not induce vomiting and seek immediate medical attention. Remove contaminated clothing carefully.
How to dispose of potassium appropriately?
Potassium disposal requires specialized hazardous waste procedures due to its reactive nature. Never dispose of in regular waste streams or pour down drains. Small quantities can be carefully neutralized by trained personnel using appropriate alcohols under controlled conditions. Larger amounts must be handled by licensed hazardous waste disposal companies following local and EU waste regulations.
How to transport potassium?
Potassium is classified as ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating maximum danger level. It requires specialized packaging that prevents contact with moisture and air. Transportation must comply with ADR regulations, using appropriate labels, documentation, and trained personnel. Only authorized carriers can transport this highly regulated substance.
Is potassium subject to particular regulations?
Potassium is subject to strict regulations under CLP (Classification, Labelling and Packaging) with mandatory Danger signal word and GHS02/GHS05 pictograms. While not listed as SVHC under REACH, it requires safety data sheets and proper classification. National regulations may impose additional restrictions on purchase, storage, and use due to its extreme reactivity and potential safety hazards.
Where to buy potassium in Europe?
OYSI serves as a reliable European distributor for potassium and other specialty chemicals. As an established chemical distributor, OYSI can provide potassium with proper documentation, safety data sheets, and regulatory compliance support. Contact OYSI directly to discuss availability, specifications, and delivery options for your specific application requirements while ensuring all regulatory obligations are met.
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ADR Consulting for Potassium
Potassium is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.