Calcium peroxide

CaO2

calcium peroxide

CAS1305-79-9

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Identification

CAS Number
1305-79-9
EC Number
215-139-4
UN Number
1457
PubChem CID
14779

Physical-chemical properties

Molecular Formula
CaO2
Molar Mass
72.08 g/mol
IUPAC Name
calcium peroxide

Chemical Identifiers

InChI
InChI=1S/Ca.O2/c;1-2/q+2;-2
InChI Key
LHJQIRIGXXHNLA-UHFFFAOYSA-N

Overview

Calcium peroxide (CAS 1305-79-9) is an inorganic oxidizing agent with strong oxygen-releasing properties and excellent stability in dry conditions. This white to yellowish crystalline compound serves as a versatile chemical intermediate in various industrial applications. With the molecular formula CaO2 and a molar mass of 72.08 g/mol, calcium peroxide belongs to the family of alkaline earth metal peroxides, distinguished by its controlled oxygen release mechanism when exposed to moisture or acidic conditions. Unlike more reactive oxidizers such as magnesium diperchlorate, calcium peroxide offers a more manageable and safer handling profile while maintaining effective oxidizing capabilities. The compound exhibits remarkable thermal stability and can be stored under proper conditions without significant degradation. Its classification under ADR class 5.1 reflects its oxidizing nature, requiring appropriate handling protocols during transportation and storage. When calcium peroxide comes into contact with water or acids, it decomposes to release nascent oxygen and calcium hydroxide, making it particularly valuable in applications requiring controlled oxygen generation. Primary industrial applications include its use as an oxygen source in aquaculture and wastewater treatment systems, where it provides sustained oxygenation without the need for mechanical aeration. The compound also finds extensive use in soil remediation projects, where its oxygen-releasing properties help restore contaminated environments. Additionally, calcium peroxide serves as a bleaching agent in textile processing and as a dough conditioner in commercial baking applications. As a leading European distributor of technical chemicals, OYSI maintains reliable supplies of high-quality calcium peroxide to meet diverse industrial requirements across multiple sectors.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1457
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameCalciumperoxid, wasserfrei
Marine PollutantNo

Frequently Asked Questions

What is calcium peroxide?

Calcium peroxide is an inorganic chemical compound with the molecular formula CaO2 and CAS number 1305-79-9. It belongs to the family of alkaline earth metal peroxides and has a molecular weight of 72.08 g/mol. This white to yellowish crystalline solid serves as a stable source of oxygen release when it comes into contact with water or acids, making it valuable in various industrial applications requiring controlled oxygen generation.

What are the physicochemical properties of calcium peroxide?

Calcium peroxide appears as a white to pale yellow crystalline powder that is odorless under normal conditions. It is slightly soluble in water, where it decomposes to release oxygen and form calcium hydroxide. The compound is stable under dry conditions but readily decomposes in the presence of moisture, acids, or heat. It has a density of approximately 2.9 g/cm³ and decomposes at temperatures above 275°C.

What is calcium peroxide used for?

Calcium peroxide serves multiple industrial and commercial purposes as an oxidizing agent and oxygen source. It is commonly used in environmental remediation for soil and groundwater treatment, in agriculture as a soil conditioner and seed treatment, and in aquaculture to maintain oxygen levels. Additional applications include its use in dental care products, food processing as a dough conditioner, and in various chemical processes requiring controlled oxygen release.

How to handle calcium peroxide safely?

Calcium peroxide should be handled with appropriate personal protective equipment including safety goggles, dust masks, and protective gloves to prevent skin and eye contact. Work in well-ventilated areas to avoid dust inhalation and prevent accumulation of released oxygen. Avoid contact with combustible materials, acids, and moisture during handling. Use non-sparking tools and equipment, and ensure proper grounding to prevent static electricity buildup during transfer operations.

How to store calcium peroxide correctly?

Calcium peroxide must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and moisture. Keep containers tightly sealed in original packaging and separate from incompatible materials such as combustible substances, acids, and reducing agents. Storage areas should be equipped with appropriate fire suppression systems and maintained at stable temperatures below 25°C to prevent decomposition and ensure product stability.

What to do in case of contact with calcium peroxide?

Calcium peroxide contact requires immediate action depending on exposure type. For skin contact, remove contaminated clothing and rinse affected areas with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. For ingestion, rinse mouth and seek immediate medical attention without inducing vomiting.

How to dispose of calcium peroxide appropriately?

Calcium peroxide disposal must comply with local, national, and European waste regulations as it is classified as hazardous waste. Small quantities can be neutralized by gradual addition to large amounts of water under controlled conditions, allowing complete decomposition. Larger quantities should be disposed of through licensed hazardous waste contractors. Never dispose of in regular waste streams, sewers, or waterways without proper treatment and regulatory approval.

How to transport calcium peroxide?

Calcium peroxide is classified under ADR as Class 5.1 (Oxidizing substances) Packing Group II, requiring specific transport regulations compliance. It must be packed in approved UN specification packaging with proper labeling and documentation. Transport vehicles need appropriate placarding and drivers require ADR certification. The substance should be kept dry during transport and separated from incompatible materials according to segregation tables.

Is calcium peroxide subject to specific regulations?

Calcium peroxide is regulated under European REACH regulation and must comply with CLP classification requirements for oxidizing substances. While not classified as an SVHC (Substance of Very High Concern), it falls under ADR transport regulations as Class 5.1. Suppliers must provide safety data sheets and ensure proper classification. Users must follow occupational exposure limits and workplace safety requirements established by national authorities.

Where to buy calcium peroxide in Europe?

Calcium peroxide is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides calcium peroxide in various packaging sizes with full regulatory compliance including safety data sheets and transport documentation. As a professional chemical distributor, OYSI ensures product quality, proper handling, and reliable supply chain management for industrial applications throughout Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.