Azanium nitrite

H4N2O2

azanium nitrite

CAS13446-48-5

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Identification

CAS Number
13446-48-5
EC Number
236-598-7
UN Number
2627
PubChem CID
26004

Physical-chemical properties

Molecular Formula
H4N2O2
Molar Mass
64.04 g/mol
IUPAC Name
azanium nitrite

Chemical Identifiers

InChI
InChI=1S/HNO2.H3N/c2-1-3;/h(H,2,3);1H3
InChI Key
CAMXVZOXBADHNJ-UHFFFAOYSA-N

Overview

Azanium nitrite (CAS 13446-48-5) is an inorganic ammonium salt compound with oxidizing properties and diverse industrial applications. This chemical substance, also known by its IUPAC designation azanium nitrite, represents a significant nitrogen-containing compound in industrial chemistry. With the molecular formula H4N2O2 and a molecular weight of 64.044 g/mol, this white crystalline salt demonstrates characteristic properties of both ammonium compounds and nitrite salts. The compound carries the European Community number 236-598-7 and is classified under ADR transport class 5.1, indicating its oxidizing nature. The oxidizing properties of azanium nitrite place it in a similar category to other industrial oxidizers such as barium(2+) dinitrate and magnesium diperchlorate, though each compound serves distinct applications based on their specific chemical characteristics. These oxidizing agents share the common feature of readily releasing oxygen under certain conditions, making them valuable in various chemical processes. From a safety perspective, azanium nitrite requires careful handling due to its oxidizing nature. While it does not carry specific GHS pictograms or signal words under standard classification, its ADR class 5.1 designation necessitates proper storage away from combustible materials and reducing agents. Industrial users must implement appropriate safety protocols including proper ventilation and protective equipment during handling operations. The compound finds application in several industrial sectors, particularly in chemical synthesis processes where controlled oxidizing conditions are required. It serves as an intermediate in various chemical manufacturing processes and finds use in specialized analytical applications. Additionally, azanium nitrite plays a role in certain metallurgical processes where precise oxidizing conditions are essential. OYSI maintains reliable supply chains for azanium nitrite to support European industrial customers requiring this specialized oxidizing compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2627
ADR Class5.1
Packing Group
Tunnel Code
Proper Shipping NameAmmoniumnitrit
Marine PollutantNo

Frequently Asked Questions

What is azanium nitrite?

Azanium nitrite is an inorganic chemical compound with the molecular formula H4N2O2 and CAS number 13446-48-5. It has a molecular weight of 64.044 g/mol and belongs to the family of nitrogen-containing compounds. This substance is formed by the combination of azanium (ammonium-like) cations with nitrite anions, creating a crystalline salt structure that is commonly used in various industrial applications requiring nitrogen-oxygen chemistry.

What are the physicochemical properties of azanium nitrite?

Azanium nitrite typically appears as a white to pale yellow crystalline solid at room temperature. The compound is highly soluble in water due to its ionic nature, forming clear solutions. It has a molecular weight of 64.044 g/mol and contains both nitrogen and oxygen functional groups. The substance may exhibit hygroscopic properties, meaning it can absorb moisture from the atmosphere, and should be stored in dry conditions to maintain its stability.

What is azanium nitrite used for?

Azanium nitrite is primarily used in chemical synthesis processes, particularly in reactions requiring nitrite functionality. It serves as a reagent in organic chemistry for diazotization reactions and as an intermediate in the production of various nitrogen-containing compounds. The substance finds applications in pharmaceutical manufacturing, dye production, and as a chemical intermediate in specialty chemical synthesis where controlled nitrite release is required.

How to handle azanium nitrite safely?

Azanium nitrite should be handled using appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and lab coats. Work in well-ventilated areas or under fume hoods to avoid inhalation of dust particles. Avoid contact with skin and eyes, and prevent ingestion. Use non-sparking tools and equipment when handling the substance. Always wash hands thoroughly after handling and ensure proper training on chemical safety procedures before use.

How to store azanium nitrite correctly?

Azanium nitrite should be stored in a cool, dry place away from direct sunlight and heat sources. Keep containers tightly sealed to prevent moisture absorption and contamination. Store separately from strong acids, bases, and incompatible materials. Maintain storage temperatures below 25°C and ensure adequate ventilation in storage areas. Use original containers or chemically compatible storage vessels, and implement proper inventory management with clear labeling and dating.

What to do in case of contact with azanium nitrite?

In case of skin contact with azanium nitrite, immediately flush the affected area with plenty of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse thoroughly with clean water for several minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific first aid measures.

How to dispose of azanium nitrite appropriately?

Azanium nitrite waste must be disposed of according to local and national hazardous waste regulations. Do not discharge into drains, waterways, or soil. Small quantities may be neutralized under controlled conditions by qualified personnel before disposal. Large quantities should be collected in appropriate containers and disposed of through licensed hazardous waste disposal companies. Always consult local environmental authorities for specific disposal requirements and maintain proper waste documentation.

How to transport azanium nitrite?

Azanium nitrite is classified under ADR Class 5.1 as an oxidizing substance for transportation purposes. It must be packaged in UN-approved containers with proper labeling and documentation. Transport vehicles should be equipped with appropriate safety equipment and drivers must hold valid dangerous goods licenses. Ensure packages are secured to prevent damage during transit and maintain temperature controls if required. Follow all applicable transportation regulations for oxidizing materials.

Is azanium nitrite subject to particular regulations?

Azanium nitrite is subject to standard chemical regulations including REACH registration requirements in Europe and CLP classification for hazard communication. While not currently listed as a Substance of Very High Concern (SVHC), users must comply with occupational safety regulations and maintain proper safety data sheets. Industrial users should implement appropriate risk management measures and ensure compliance with local chemical safety legislation and workplace exposure limits.

Where to buy azanium nitrite in Europe?

Azanium nitrite is available through OYSI, a European distributor specializing in technical chemicals and laboratory reagents. OYSI provides reliable supply chains across Europe with proper documentation, quality certificates, and regulatory compliance support. Contact OYSI's technical sales team for availability, packaging options, and delivery arrangements. They can also provide technical support and safety documentation to ensure proper handling and compliance with local regulations.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.