Azanium nitrite

H4N2O2

azanium nitrite

CAS13446-48-5

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Identification

CAS Number
13446-48-5
EC Number
236-598-7
UN Number
2627
PubChem CID
26004

Physical-chemical properties

Molecular Formula
H4N2O2
Molar Mass
64.04 g/mol
IUPAC Name
azanium nitrite

Chemical Identifiers

InChI
InChI=1S/HNO2.H3N/c2-1-3;/h(H,2,3);1H3
InChI Key
CAMXVZOXBADHNJ-UHFFFAOYSA-N

Overview

Azanium nitrite (CAS 13446-48-5) is an inorganic ammonium salt compound with oxidizing properties and moderate chemical reactivity. This crystalline compound, also known by its IUPAC designation azanium nitrite, represents an important member of the nitrite salt family used in various industrial applications. With the molecular formula H4N2O2 and a molecular mass of 64.044 g/mol, azanium nitrite exhibits characteristic properties of both ammonium-based compounds and nitrite salts. The substance is classified under ADR transport regulations as Class 5.1, indicating its oxidizing nature, which requires appropriate handling and storage protocols to prevent unwanted reactions with combustible materials. The compound's chemical structure consists of azanium cations paired with nitrite anions, creating a stable ionic lattice under normal conditions. This configuration contributes to its solubility in polar solvents and its reactivity profile. Unlike stronger oxidizing agents such as barium(2+) dinitrate or magnesium diperchlorate, azanium nitrite offers a more moderate oxidizing potential, making it suitable for controlled chemical processes where gentle oxidation is required. In industrial applications, azanium nitrite serves primarily as a chemical intermediate in organic synthesis, particularly in diazotization reactions and the production of nitrogen-containing compounds. It also finds use in metallurgical processes as a corrosion inhibitor and in certain analytical chemistry procedures. The pharmaceutical industry occasionally employs this compound in the synthesis of specific drug intermediates where its unique reactivity profile proves advantageous. OYSI maintains reliable supply chains for azanium nitrite, ensuring consistent availability for European industrial customers requiring this specialized chemical compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2627
ADR Class5.1
Packing Group
Tunnel Code
Proper Shipping NameAmmoniumnitrit
Marine PollutantNo

Frequently Asked Questions

What is azanium nitrite?

Azanium nitrite is an inorganic compound with the molecular formula H4N2O2 and CAS number 13446-48-5. This chemical substance has a molecular weight of 64.044 g/mol and represents a salt formed between ammonium and nitrite ions. It appears as a crystalline solid at room temperature and is commonly used in various industrial applications requiring nitrite functionality.

What are the physicochemical properties of azanium nitrite?

Azanium nitrite is a white to pale yellow crystalline solid at room temperature with good water solubility. The compound has a molecular mass of 64.044 g/mol and contains both ammonium and nitrite functional groups. It typically exhibits hygroscopic properties, meaning it can absorb moisture from the atmosphere, and may have a slight ammonia-like odor due to its ammonium component.

What is azanium nitrite used for?

Azanium nitrite is primarily used as a chemical intermediate in organic synthesis and industrial manufacturing processes. It serves as a source of nitrite ions in various chemical reactions, particularly in diazotization reactions and the production of dyes and pharmaceuticals. The compound is also utilized in metal treatment applications and as a corrosion inhibitor in certain industrial systems.

How to handle azanium nitrite safely?

Azanium nitrite should be handled with standard laboratory safety precautions including wearing appropriate personal protective equipment such as safety glasses, gloves, and lab coats. Work in well-ventilated areas to avoid inhalation of dust or vapors. Avoid contact with skin and eyes, and prevent ingestion. Use proper handling techniques to minimize dust generation and ensure good housekeeping practices in the work area.

How to store azanium nitrite correctly?

Azanium nitrite should be stored in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. Keep containers tightly closed and protect from moisture due to its hygroscopic nature. Store away from incompatible materials such as strong acids, strong bases, and organic materials. Maintain storage temperatures below 25°C and ensure proper labeling of all containers.

What to do in case of contact with azanium nitrite?

In case of skin contact with azanium nitrite, immediately wash the affected area with plenty of water and soap for at least 15 minutes. For eye contact, flush eyes immediately with clean water for 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if symptoms persist. In case of ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of azanium nitrite properly?

Azanium nitrite disposal must comply with local, national, and EU waste regulations including the Waste Framework Directive. The compound should be treated as chemical waste and disposed of through licensed waste management companies. Do not discharge into drains, waterways, or soil. Contact specialized waste disposal services for proper treatment and disposal methods according to regional environmental regulations.

How to transport azanium nitrite?

Azanium nitrite is classified under ADR Class 5.1 as an oxidizing substance for transportation purposes. This classification requires specific packaging, labeling, and documentation requirements during transport. Use appropriate UN-approved packaging and ensure proper hazard labels are displayed. Transport should comply with ADR regulations for oxidizing substances and follow established dangerous goods transportation protocols.

Is azanium nitrite subject to specific regulations?

Azanium nitrite is subject to various European chemical regulations including REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) and CLP (Classification, Labelling and Packaging) regulations. The substance is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with safety data sheet requirements and proper classification obligations under EU chemical legislation.

Where to buy azanium nitrite in Europe?

Azanium nitrite is available through OYSI, a trusted European distributor of technical chemicals. OYSI provides high-quality chemical products to industrial customers across Europe with proper documentation and regulatory compliance. Contact OYSI directly for availability, specifications, and delivery options for azanium nitrite to meet your specific industrial or research requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.