Molecular oxygen

O2

molecular oxygen

CAS7782-44-7
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
Danger

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Identification

CAS Number
7782-44-7
EC Number
231-956-9
UN Number
1073
Index Number
008-001-00-8
PubChem CID
977

Physical-chemical properties

Molecular Formula
O2
Molar Mass
32.00 g/mol
IUPAC Name
molecular oxygen

Chemical Identifiers

InChI
InChI=1S/O2/c1-2
InChI Key
MYMOFIZGZYHOMD-UHFFFAOYSA-N

Overview

Molecular oxygen (CAS 7782-44-7) is a diatomic gas essential for combustion and oxidation processes, classified as an oxidizing gas under pressure. Molecular oxygen represents one of the most fundamental and widely utilized industrial gases in chemical processing and manufacturing operations. This colorless, odorless diatomic molecule constitutes approximately 21% of Earth's atmosphere and serves as a critical oxidizing agent across numerous industrial applications. With the molecular formula O2 and a molar mass of 31.999 g/mol, oxygen exhibits strong oxidizing properties that make it invaluable for combustion enhancement, chemical synthesis, and various metallurgical processes. As a compressed gas classified under ADR Class 2, molecular oxygen requires careful handling protocols due to its dual classification as both an oxidizing gas (Ox. Gas 1) and pressurized gas (Press. Gas). The associated GHS pictograms GHS03 and GHS04 indicate flame-over-circle and gas cylinder hazards respectively, emphasizing the need for proper storage away from combustible materials and secure cylinder handling. Unlike highly reactive halogens such as molecular fluorine or molecular chlorine, oxygen's reactivity is more controlled, making it safer to handle while maintaining its powerful oxidizing capabilities. Industrial applications of molecular oxygen span steel production and metal cutting operations, where it enhances combustion efficiency and enables high-temperature processes. In chemical manufacturing, oxygen serves as a key reactant in oxidation reactions and assists in wastewater treatment through biological processes. The pharmaceutical and medical industries rely heavily on high-purity oxygen for respiratory therapy and various synthesis procedures. OYSI maintains reliable supply chains for molecular oxygen across European markets, ensuring consistent availability for industrial customers requiring this essential oxidizing gas for their manufacturing operations.

Safety & Classification

Danger
Classification:

Ox. Gas 1; Press. Gas

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H270

May cause or intensify fire; oxidiser.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1073
ADR Class2
Packing Group
Tunnel CodeC/E
Proper Shipping NameSauerstoff, tiefgekühlt, flüssig
Marine PollutantNo

Frequently Asked Questions

What is molecular oxygen?

Molecular oxygen is a diatomic gas with the chemical formula O2 and CAS number 7782-44-7. It is an essential element for life and combustion processes, consisting of two oxygen atoms covalently bonded together. With a molecular weight of 31.999 g/mol, it is classified as an oxidizing gas and pressurized gas under GHS regulations, requiring careful handling due to its reactive nature and ability to support combustion.

What are the physicochemical properties of molecular oxygen?

Molecular oxygen is a colorless, odorless gas at room temperature and pressure. It has a boiling point of -183°C and a melting point of -218°C. The gas is slightly denser than air and has limited solubility in water. As a strong oxidizing agent, it readily supports combustion and can react vigorously with organic materials and reducing agents, making it highly reactive in many chemical processes.

What is molecular oxygen used for?

Molecular oxygen is used extensively in industrial processes including steel production, chemical manufacturing, and welding operations. It serves as an oxidizing agent in combustion processes, supports respiratory therapy in medical applications, and is essential in wastewater treatment facilities. Additionally, it is used in glass manufacturing, metal cutting, and various oxidation reactions in the chemical industry, making it a crucial industrial gas.

How to handle molecular oxygen safely?

Molecular oxygen requires careful handling due to its oxidizing properties and pressurized nature. Personnel should wear appropriate PPE including safety glasses and protective clothing, avoid contact with oils, greases, and combustible materials. Work areas must be well-ventilated, and smoking or open flames should be prohibited. Equipment should be oxygen-compatible and properly grounded to prevent static electricity, as oxygen significantly increases fire and explosion risks.

How to store molecular oxygen correctly?

Molecular oxygen must be stored in properly designed pressure vessels away from heat sources, combustible materials, and reducing agents. Storage areas should be well-ventilated, dry, and secure with appropriate warning signage. Cylinders should be stored upright, properly secured, and separated from incompatible substances like flammable gases and organic materials. Temperature should be controlled to prevent excessive pressure buildup in containers.

What to do in case of contact with molecular oxygen?

Molecular oxygen exposure typically occurs through inhalation of oxygen-enriched atmospheres. If exposed to high concentrations, move the person to fresh air immediately and seek medical attention if breathing difficulties occur. For oxygen-enriched clothing or skin contact, remove contaminated clothing and flush affected areas with water. In case of fire involving oxygen, evacuate the area and contact emergency services, as oxygen greatly intensifies combustion.

How to dispose of molecular oxygen properly?

Molecular oxygen disposal involves controlled venting to the atmosphere in well-ventilated areas away from ignition sources and personnel. Empty cylinders should be returned to suppliers or authorized gas distributors for proper handling. Never dispose of pressurized containers in regular waste streams. Follow local environmental regulations and coordinate with waste management authorities for proper disposal procedures, ensuring all safety protocols are maintained during the process.

How to transport molecular oxygen?

Molecular oxygen is classified under ADR Class 2 for transport of gases, requiring specialized handling and documentation. It must be transported in approved pressure vessels with proper labeling including GHS03 and GHS04 pictograms and 'Danger' signal word. Vehicles must be properly ventilated, drivers appropriately trained, and transport documentation must accompany shipments. Emergency response information should be readily available during transport operations.

Is molecular oxygen subject to specific regulations?

Molecular oxygen is regulated under various European directives including CLP regulation for classification as Oxidizing Gas Category 1 and Pressurized Gas. It requires safety data sheets and proper labeling with GHS pictograms GHS03 and GHS04. While not listed as an SVHC under REACH, it is subject to industrial emissions regulations and workplace exposure limits. Transport regulations under ADR also apply for commercial movements.

Where to buy molecular oxygen in Europe?

Molecular oxygen is available through OYSI, a specialized European distributor of technical chemicals and industrial gases. As an established supplier in the European market, OYSI can provide molecular oxygen in various purities and packaging formats suitable for different industrial applications. Contact OYSI directly for specific grade requirements, technical specifications, and availability in your region to ensure compliance with local regulations and application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.