Disodium;peroxide

Na2O2

disodium;peroxide

CAS1313-60-6
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
1313-60-6
EC Number
215-209-4
UN Number
1504
Index Number
011-003-00-1
PubChem CID
14803

Physical-chemical properties

Molecular Formula
Na2O2
Molar Mass
77.98 g/mol
IUPAC Name
disodium;peroxide

Chemical Identifiers

InChI
InChI=1S/2Na.O2/c;;1-2/q2*+1;-2
InChI Key
PFUVRDFDKPNGAV-UHFFFAOYSA-N

Overview

Disodium peroxide (CAS 1313-60-6) is an inorganic peroxide compound with strong oxidizing properties and high alkalinity. This sodium-based peroxide represents a powerful industrial chemical characterized by its dual nature as both an oxidizing agent and alkaline substance. With the molecular formula Na2O2 and a molecular weight of 77.978 g/mol, disodium peroxide appears as a yellowish-white crystalline solid that demonstrates exceptional reactivity with water, organic materials, and various chemical compounds. The compound's classification under GHS standards includes Oxidizing Solid Category 1 and Skin Corrosion Category 1A, reflecting its significant safety considerations and corrosive nature. The substance exhibits remarkable oxidizing capabilities, making it particularly valuable in industrial processes requiring controlled oxidation reactions. Its strong alkaline properties complement its oxidizing function, creating a versatile chemical tool for specialized applications. Safety handling requires strict adherence to protective protocols due to its corrosive effects on skin and materials, as indicated by the GHS03 and GHS05 pictograms and "Danger" signal word. Primary industrial applications include textile bleaching processes, where its oxidizing properties effectively remove colorants and impurities from fabrics. The compound also serves as an oxygen source in various chemical syntheses and finds use in specialized cleaning formulations for industrial equipment. Unlike related chromium compounds such as trioxochromium, disodium peroxide offers a chromium-free alternative for certain oxidation processes, addressing environmental and regulatory concerns. As a established European chemical distributor, OYSI maintains reliable supply chains for disodium peroxide, ensuring consistent availability for industrial customers requiring this specialized oxidizing compound.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1504
ADR Class5.1
Packing GroupI
Tunnel CodeE
Proper Shipping NameNatriumperoxid, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is disodium peroxide?

Disodium peroxide is an inorganic chemical compound with the molecular formula Na2O2 and CAS number 1313-60-6. It belongs to the class of alkali metal peroxides and has a molecular weight of 77.978 g/mol. This compound is classified as a strong oxidizing solid (Ox. Sol. 1) and skin corrosive substance (Skin Corr. 1A), making it a hazardous chemical that requires careful handling and appropriate safety measures during use.

What are the physicochemical properties of disodium peroxide?

Disodium peroxide is a yellowish-white crystalline solid at room temperature with strong oxidizing properties. It readily decomposes in contact with water, releasing oxygen gas and forming sodium hydroxide. The compound is highly reactive and hygroscopic, meaning it absorbs moisture from air. Due to its peroxide structure, it contains an oxygen-oxygen single bond that makes it thermally unstable and prone to decomposition when heated or exposed to catalytic materials.

What is disodium peroxide used for?

Disodium peroxide is primarily used as a strong oxidizing agent in various industrial applications including bleaching processes, oxygen generation systems, and chemical synthesis reactions. It serves as a source of active oxygen in specialized cleaning formulations and disinfection processes. The compound is also utilized in analytical chemistry for oxidation reactions and in some metallurgical processes where controlled oxygen release is required under specific conditions.

How to handle disodium peroxide safely?

Disodium peroxide must be handled with extreme caution using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction due to potential oxygen release and corrosive properties. Avoid contact with skin, eyes, and clothing as it causes severe burns. Keep away from combustible materials, reducing agents, and moisture during handling to prevent dangerous reactions.

How to store disodium peroxide correctly?

Disodium peroxide should be stored in a cool, dry place away from heat sources, direct sunlight, and moisture. Use tightly sealed, compatible containers made of materials resistant to oxidation. Keep separated from incompatible substances including combustible materials, reducing agents, acids, and organic compounds. Storage areas must be well-ventilated and equipped with appropriate spill containment measures. Regular inspection of containers is essential due to the compound's reactive nature.

What to do in case of contact with disodium peroxide?

Immediate first aid is crucial due to the corrosive nature of disodium peroxide. In case of skin contact, remove contaminated clothing immediately and rinse affected area with plenty of water for at least 15 minutes. For eye contact, flush thoroughly with water and seek immediate medical attention. If inhaled, move to fresh air immediately. Do not induce vomiting if ingested. Seek medical attention promptly in all cases of exposure and provide safety data sheet to medical personnel.

How to dispose of disodium peroxide properly?

Disodium peroxide must be disposed of according to local and national hazardous waste regulations as it is classified as dangerous goods. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities can be carefully neutralized by trained personnel following established protocols, but this should only be done with proper safety equipment and procedures. Never dispose of this compound in regular waste streams or pour down drains due to its oxidizing and corrosive properties.

How to transport disodium peroxide?

Disodium peroxide is classified under ADR as Class 5.1 (Oxidizing substances) Packing Group I, indicating it presents high transport risks. It must be packaged in UN-approved containers with proper hazard labels including GHS03 (flame over circle) and GHS05 (corrosion) pictogrammes. Transport documentation must include the proper shipping name, UN number, and hazard class. Only authorized carriers experienced in handling dangerous goods should transport this substance following all ADR regulations.

Is disodium peroxide subject to specific regulations?

Disodium peroxide is subject to various European regulations including REACH registration requirements and CLP classification as Ox. Sol. 1 and Skin Corr. 1A with danger signal word. It is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations, proper labeling requirements, and safety data sheet provisions. Industrial users may need to implement risk management measures and report usage depending on quantities handled and local regulatory requirements.

Where to buy disodium peroxide in Europe?

Disodium peroxide is available through OYSI, a trusted European distributor of technical chemicals serving various industries across the continent. As a specialized chemical distributor, OYSI provides high-quality disodium peroxide with proper documentation, safety data sheets, and regulatory compliance support. Contact OYSI directly to inquire about availability, specifications, packaging options, and delivery to your location within Europe for your specific industrial or research applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.