Potassium hydroxide

HKO

potassium hydroxide

CAS1310-58-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
1310-58-3
EC Number
215-181-3
UN Number
1813
Index Number
019-002-00-8
PubChem CID
14797

Physical-chemical properties

Molecular Formula
HKO
Molar Mass
56.11 g/mol
IUPAC Name
potassium hydroxide

Chemical Identifiers

InChI
InChI=1S/K.H2O/h;1H2/q+1;/p-1
InChI Key
KWYUFKZDYYNOTN-UHFFFAOYSA-M

Overview

Potassium hydroxide (CAS 1310-58-3) is a highly caustic inorganic compound with strong alkaline properties and excellent solubility in water. This white, deliquescent solid represents one of the most important alkali metal hydroxides in industrial chemistry. Also known by its chemical formula KOH, potassium hydroxide exhibits exceptional reactivity and serves as a fundamental building block in numerous chemical processes. The compound readily absorbs moisture and carbon dioxide from air, forming potassium carbonate, which necessitates careful storage under controlled conditions. The substance presents significant safety considerations due to its highly corrosive nature, classified as Skin Corr. 1A under GHS regulations. Direct contact can cause severe chemical burns to skin and eyes, while inhalation of dust or mist may lead to respiratory tract damage. Proper personal protective equipment, including chemical-resistant gloves, safety goggles, and adequate ventilation, is essential when handling this material. The compound's strong exothermic reaction with water requires controlled mixing procedures to prevent dangerous heat generation. Industrially, potassium hydroxide finds extensive application in soap and detergent manufacturing, where its saponification properties convert fats and oils into potassium soaps. The chemical industry utilizes it for pH adjustment and as a catalyst in various synthetic processes. Additionally, it serves in the production of potassium salts and plays a crucial role in battery manufacturing, particularly in alkaline and fuel cell technologies. Unlike substances such as phosphonic acid or sulfurofluoridic acid, potassium hydroxide's strong basic character makes it invaluable for neutralization reactions. OYSI maintains reliable supply chains for potassium hydroxide, ensuring consistent availability for European industrial customers requiring this essential chemical intermediate.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1813
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameKaliumhydroxid, fest
Marine PollutantNo

Frequently Asked Questions

What is potassium hydroxide?

Potassium hydroxide is a strong inorganic base with the chemical formula KOH and CAS number 1310-58-3. This alkaline compound has a molecular weight of 56.106 g/mol and is classified as a corrosive substance. It is commonly known as caustic potash and appears as white, deliquescent pellets, flakes, or powder that readily absorbs moisture from air.

What are the physico-chemical properties of potassium hydroxide?

Potassium hydroxide is a white crystalline solid at room temperature, appearing as pellets, flakes, or powder. It is odorless and highly soluble in water, generating significant heat upon dissolution. The compound is deliquescent, meaning it absorbs atmospheric moisture readily. It has a high melting point and is highly caustic, making it extremely corrosive to organic tissues.

What is potassium hydroxide used for?

Potassium hydroxide is used extensively in chemical manufacturing for soap production, biodiesel synthesis, and as a pH regulator. Industrial applications include battery manufacturing (alkaline batteries), textile processing, and metal cleaning. It serves as a catalyst in various chemical reactions and is used in the production of potassium salts, dyes, and pharmaceuticals in controlled industrial environments.

How to handle potassium hydroxide safely?

Potassium hydroxide requires careful handling due to its corrosive nature (Skin Corr. 1A classification). Always wear chemical-resistant gloves, safety goggles, face protection, and protective clothing when handling. Work in well-ventilated areas and avoid generating dust. Keep emergency eyewash stations and safety showers accessible. Never add water directly to solid KOH due to violent exothermic reactions.

How to store potassium hydroxide correctly?

Potassium hydroxide must be stored in a dry, well-ventilated area away from moisture and incompatible materials. Use tightly sealed, corrosion-resistant containers to prevent atmospheric moisture absorption. Store separately from acids, organic materials, and metals like aluminum. Maintain storage areas below 25°C and ensure adequate spill containment measures are in place.

What to do in case of contact with potassium hydroxide?

Immediate action is required for potassium hydroxide contact due to its corrosive properties. For skin contact, remove contaminated clothing and rinse affected area with copious amounts of water for at least 15 minutes. For eye contact, flush immediately with water for 15-20 minutes. If inhaled, move to fresh air. Seek immediate medical attention for all exposure incidents.

How to dispose of potassium hydroxide appropriately?

Potassium hydroxide disposal must comply with local and European waste regulations. The substance should be neutralized carefully with dilute acid under controlled conditions before disposal. Never dispose of in regular waste streams or sewage systems. Contact authorized waste management companies for proper collection and treatment. Follow waste classification codes and documentation requirements for hazardous waste disposal.

How to transport potassium hydroxide?

Potassium hydroxide is classified as ADR Class 8 (corrosive substances), Packing Group II, indicating moderate danger level. Transportation requires appropriate UN-approved packaging and hazard labeling with corrosive pictograms. Vehicles must carry proper documentation and emergency response information. Drivers need ADR certification for dangerous goods transport, and specific routing restrictions may apply in urban areas.

Is potassium hydroxide subject to specific regulations?

Potassium hydroxide is regulated under European CLP Regulation with classifications Acute Tox. 4 and Skin Corr. 1A, requiring danger signal word and GHS pictograms GHS05 and GHS07. It falls under REACH registration requirements but is not classified as SVHC (Substance of Very High Concern). Workplace exposure limits and safety data sheet provisions apply for industrial use.

Where to buy potassium hydroxide in Europe?

Potassium hydroxide is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. OYSI provides technical-grade potassium hydroxide with proper documentation, safety data sheets, and regulatory compliance support. Professional customers can access various packaging options and technical support for industrial applications through OYSI's distribution network.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.