Sulfurofluoridic acid

FHO3S

sulfurofluoridic acid

CAS7789-21-1
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7789-21-1
EC Number
232-149-4
UN Number
1777
Index Number
016-018-00-7
PubChem CID
24603

Physical-chemical properties

Molecular Formula
FHO3S
Molar Mass
100.07 g/mol
IUPAC Name
sulfurofluoridic acid

Chemical Identifiers

InChI
InChI=1S/FHO3S/c1-5(2,3)4/h(H,2,3,4)
InChI Key
UQSQSQZYBQSBJZ-UHFFFAOYSA-N

Overview

Sulfurofluoridic acid (CAS 7789-21-1) is a highly corrosive inorganic acid with strong acidic and fluorinating properties used in specialized chemical processes. This potent chemical compound, with the molecular formula FHO3S and a molecular weight of 100.07 g/mol, represents a critical reagent in advanced chemical synthesis and industrial applications. Sulfurofluoridic acid combines the aggressive nature of strong acids with unique fluorinating capabilities, making it particularly valuable in specialized manufacturing processes where conventional acids prove insufficient. The compound exhibits extreme corrosive properties, classified as Skin Corr. 1A under GHS regulations, requiring stringent safety protocols during handling and storage. Its acute toxicity rating (Acute Tox. 4) and classification under ADR Class 8 as a corrosive substance underscore the need for specialized equipment and trained personnel when working with this material. The associated GHS pictogrammes GHS07 and GHS05 clearly indicate both its health hazards and corrosive nature. In industrial applications, sulfurofluoridic acid serves primarily in fluorochemical synthesis, where its dual acidic and fluorinating properties enable unique reaction pathways unavailable with conventional acids like phosphonic acid or other standard reagents. It finds particular utility in the production of specialized fluorinated compounds and as an intermediate in advanced chemical manufacturing processes. The compound also plays a role in surface treatment applications where both etching and fluorination are required simultaneously. Unlike more common acids such as potassium hydroxide solutions, sulfurofluoridic acid offers distinct advantages in processes requiring precise fluorine incorporation while maintaining strong acidic conditions throughout the reaction sequence. OYSI provides sulfurofluoridic acid to qualified industrial customers across Europe, ensuring proper documentation and compliance with all relevant chemical regulations.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1777
ADR Class8
Packing GroupI
Tunnel CodeE
Proper Shipping NameFluorsulfonsäure
Marine PollutantNo

Frequently Asked Questions

What is sulfurofluoridic acid?

Sulfurofluoridic acid is an inorganic chemical compound with the molecular formula FHO3S and CAS number 7789-21-1. This highly corrosive acid has a molecular weight of 100.07 g/mol and represents a fluorinated derivative of sulfuric acid. It is classified as a skin corrosive substance (Skin Corr. 1A) and acute toxic material (Acute Tox. 4), requiring careful handling in industrial applications due to its aggressive chemical properties.

What are the physicochemical properties of sulfurofluoridic acid?

Sulfurofluoridic acid is a colorless to pale yellow liquid with strong acidic properties and a pungent, irritating odor. The compound has a molecular weight of 100.07 g/mol and demonstrates high reactivity due to its fluorine content. It is highly soluble in water, forming strongly acidic solutions. The substance exhibits excellent thermal stability under normal conditions but can decompose at elevated temperatures, releasing toxic fluorine-containing gases.

What is sulfurofluoridic acid used for?

Sulfurofluoridic acid is primarily used as a fluorinating agent in specialized chemical synthesis and industrial processes. It serves as an intermediate in the production of fluorinated organic compounds and pharmaceuticals. The compound finds applications in metal surface treatment, electroplating processes, and as a catalyst in certain chemical reactions. Its strong acidic properties make it valuable for specialized cleaning applications and etching processes in the electronics industry.

How to handle sulfurofluoridic acid safely?

Sulfurofluoridic acid requires strict safety protocols due to its corrosive and toxic nature. Essential personal protective equipment includes acid-resistant gloves, safety goggles, face shields, and chemical-resistant clothing. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Emergency shower and eyewash stations should be readily accessible. Never work alone when handling this substance, and ensure proper emergency procedures are established before beginning any work.

How to store sulfurofluoridic acid correctly?

Sulfurofluoridic acid must be stored in tightly sealed, corrosion-resistant containers made of compatible materials such as PTFE or specialized fluoropolymers. Storage areas should be cool, dry, and well-ventilated, away from incompatible materials including metals, bases, and organic compounds. Secondary containment is essential to prevent environmental contamination. The storage area must be clearly labeled and accessible only to trained personnel with appropriate safety equipment readily available.

What to do in case of contact with sulfurofluoridic acid?

Immediate action is critical in case of contact with sulfurofluoridic acid. For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. For eye contact, rinse continuously with clean water and seek immediate medical attention. If inhaled, move the person to fresh air immediately. In all cases of exposure, seek prompt medical attention and provide safety data sheets to medical personnel for proper treatment guidance.

How to dispose of sulfurofluoridic acid properly?

Sulfurofluoridic acid disposal requires compliance with local and European waste regulations as hazardous chemical waste. The substance cannot be disposed of through regular drainage systems or municipal waste streams. Proper disposal involves neutralization by qualified waste management professionals using appropriate bases under controlled conditions. Contact licensed hazardous waste disposal companies for collection and treatment. Maintain detailed records of disposal activities as required by environmental regulations.

How to transport sulfurofluoridic acid?

Sulfurofluoridic acid is classified under ADR transport regulations as Class 8 (corrosive substances), Packing Group I, indicating high danger level. Transportation requires specialized corrosion-resistant packaging meeting UN specification standards and proper hazard labeling with GHS05 and GHS07 pictograms. Vehicles must carry appropriate emergency equipment and documentation. Only trained personnel with ADR certification should handle transportation, following strict routing and emergency response protocols throughout the journey.

Is sulfurofluoridic acid subject to specific regulations?

Sulfurofluoridic acid is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification standards. The substance is not currently listed as an SVHC (Substance of Very High Concern) but requires proper safety data sheets and hazard communication. Workplace exposure limits and industrial emission controls may apply depending on usage. Companies must comply with national chemical safety regulations and maintain appropriate risk assessments for occupational health protection.

Where to buy sulfurofluoridic acid in Europe?

Sulfurofluoridic acid is available through specialized chemical distributors across Europe, including OYSI, a trusted supplier of technical chemicals. Purchase requires verification of legitimate industrial use and appropriate handling capabilities due to the substance's hazardous classification. Suppliers provide necessary documentation including safety data sheets, certificates of analysis, and regulatory compliance information. Professional chemical distributors ensure proper packaging, transportation, and regulatory compliance for safe delivery to qualified customers.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.