Sulfurofluoridic acid

FHO3S

sulfurofluoridic acid

CAS7789-21-1
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7789-21-1
EC Number
232-149-4
UN Number
1777
Index Number
016-018-00-7
PubChem CID
24603

Physical-chemical properties

Molecular Formula
FHO3S
Molar Mass
100.07 g/mol
IUPAC Name
sulfurofluoridic acid

Chemical Identifiers

InChI
InChI=1S/FHO3S/c1-5(2,3)4/h(H,2,3,4)
InChI Key
UQSQSQZYBQSBJZ-UHFFFAOYSA-N

Overview

Sulfurofluoridic acid (CAS 7789-21-1) is a highly corrosive inorganic acid with strong oxidizing properties and exceptional chemical reactivity. This specialized chemical compound, with the molecular formula FHO3S and a molecular weight of 100.07 g/mol, represents a unique class of fluorinated sulfur acids that combines the aggressive nature of both sulfur and fluorine chemistry. Sulfurofluoridic acid is characterized by its extreme corrosivity and acute toxicity, requiring stringent handling protocols and specialized storage conditions due to its classification as a skin corrosive substance (Class 1A) and acute toxicity hazard (Class 4). The compound exhibits remarkable chemical instability and high reactivity with most organic and inorganic materials, making it both a valuable industrial reagent and a substance requiring exceptional safety measures. Its transport classification under ADR Class 8 reflects its corrosive nature, necessitating specialized packaging and documentation for safe handling and distribution. Unlike more common acids such as phosphonic acid, sulfurofluoridic acid presents unique challenges due to its fluorine content, which imparts additional corrosive properties and environmental considerations. Primary industrial applications include specialized chemical synthesis processes, particularly in fluorine chemistry applications, advanced materials processing where its unique reactivity profile is essential, and as an intermediate in the production of specialized fluorinated compounds. The compound finds particular utility in research and development applications requiring precise chemical modifications. OYSI maintains technical expertise in handling and distributing sulfurofluoridic acid, providing comprehensive safety documentation and technical support to ensure proper industrial application of this specialized chemical reagent.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1777
ADR Class8
Packing GroupI
Tunnel CodeE
Proper Shipping NameFluorsulfonsäure
Marine PollutantNo

Frequently Asked Questions

What is sulfurofluoridic acid?

Sulfurofluoridic acid is a highly corrosive inorganic acid with the molecular formula FHO3S and CAS number 7789-21-1. This chemical compound has a molecular weight of 100.07 g/mol and is classified as a dangerous substance due to its acute toxicity and severe skin corrosion properties. It belongs to the class of fluorosulfonic acids and is characterized by its strong acidic nature and reactivity with various materials.

What are the physicochemical properties of sulfurofluoridic acid?

Sulfurofluoridic acid is typically a colorless to pale yellow liquid at room temperature with strong acidic properties. It exhibits high solubility in water and polar solvents, releasing heat upon dilution. The compound has a pungent, irritating odor and demonstrates strong corrosive behavior toward metals, organic materials, and biological tissues. Its high reactivity makes it unstable in the presence of moisture and bases.

What is sulfurofluoridic acid used for?

Sulfurofluoridic acid is primarily used as a strong acid catalyst in various chemical synthesis processes and as an intermediate in the production of fluorinated compounds. It serves applications in electroplating, metal surface treatment, and specialized cleaning operations in industrial settings. The compound is also utilized in research laboratories for analytical chemistry procedures and as a reagent in organic synthesis reactions requiring strong acidic conditions.

How to handle sulfurofluoridic acid safely?

Sulfurofluoridic acid requires strict safety protocols including full-face respirators, acid-resistant gloves, and complete body protection with chemical-resistant clothing. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Emergency eyewash stations and safety showers should be readily accessible. Personnel must be trained in acid handling procedures and emergency response protocols before working with this highly corrosive substance.

How to store sulfurofluoridic acid correctly?

Sulfurofluoridic acid must be stored in corrosion-resistant containers made of suitable materials like PTFE or specialized glass in cool, dry, well-ventilated areas away from heat sources and incompatible materials. Storage areas should be equipped with secondary containment systems and appropriate ventilation. The substance must be kept separated from bases, metals, and organic materials to prevent dangerous reactions and should be protected from moisture and temperature fluctuations.

What to do in case of contact with sulfurofluoridic acid?

Immediate action is critical upon contact with sulfurofluoridic acid. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention for all exposure routes as this substance causes severe chemical burns and tissue damage.

How to dispose of sulfurofluoridic acid properly?

Sulfurofluoridic acid must be disposed of as hazardous waste through licensed waste management companies in accordance with local and European waste regulations. The substance cannot be discharged into sewers, waterways, or regular waste streams. Neutralization should only be performed by trained professionals using appropriate techniques and safety measures. All disposal activities must comply with ADR transport regulations and waste classification requirements under European legislation.

How to transport sulfurofluoridic acid?

Sulfurofluoridic acid is classified under ADR as Class 8 (corrosive substances), Packing Group I, indicating maximum danger level for transport. Specialized corrosion-resistant packaging and labeling with appropriate hazard pictogrammes (GHS05, GHS07) and 'Danger' signal word are mandatory. Transport must comply with ADR regulations including proper documentation, vehicle requirements, and driver training. Only authorized carriers experienced in hazardous materials transport should handle shipments.

Is sulfurofluoridic acid subject to specific regulations?

Sulfurofluoridic acid is regulated under European REACH and CLP regulations due to its hazardous classification as Acute Tox. 4 and Skin Corr. 1A. While not classified as an SVHC (Substance of Very High Concern), it requires safety data sheets, proper labeling, and risk assessments for industrial use. Users must comply with occupational exposure limits, workplace safety regulations, and environmental protection requirements established by relevant European and national authorities.

Where to buy sulfurofluoridic acid in Europe?

Sulfurofluoridic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across Europe. As an established chemical distributor, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for hazardous substances. Professional buyers should contact OYSI directly to discuss specific requirements, quantities, and delivery arrangements while ensuring proper handling capabilities and regulatory compliance at their facilities.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.