Phosphonic acid
H3O3P
phosphonic acid
Consulting for Phosphonic acid
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Identification
- CAS Number
- 13598-36-2
- EC Number
- 237-066-7
- UN Number
- 2834
- Index Number
- 015-157-00-0
- PubChem CID
- 407
Physical-chemical properties
- Molecular Formula
- H3O3P
- Molar Mass
- 82.00 g/mol
- IUPAC Name
- phosphonic acid
Chemical Identifiers
- InChI
- InChI=1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)
- InChI Key
- ABLZXFCXXLZCGV-UHFFFAOYSA-N
Overview
Phosphonic acid (CAS 13598-36-2) is an organophosphorus compound with strong acidic properties and corrosive characteristics. This fundamental phosphorus-containing acid serves as a crucial building block in various industrial applications and chemical synthesis processes. With its molecular formula H3O3P and molecular weight of 81.996 g/mol, phosphonic acid represents the simplest member of the phosphonic acid family, featuring a direct carbon-phosphorus bond that distinguishes it from phosphoric acid derivatives. The compound exhibits significant corrosive properties, classified under GHS pictograms GHS05 and GHS07 with a "Danger" signal word. Its classification as Skin Corr. 1A indicates severe skin corrosion potential, while the Acute Tox. 4 rating requires careful handling protocols. The ADR class 8 designation confirms its corrosive nature for transportation purposes, necessitating specialized packaging and handling procedures. Phosphonic acid demonstrates excellent chelating properties and thermal stability, making it valuable in industrial formulations. Unlike simpler acids such as 2-chloropropanoic acid, phosphonic acid offers unique coordination chemistry due to its phosphorus center, enabling formation of stable metal complexes. Key industrial applications include water treatment formulations where it acts as a scale and corrosion inhibitor, agricultural chemicals as a component in herbicide and fungicide formulations, and industrial cleaning products where its chelating properties prove essential. The compound also serves as an intermediate in pharmaceutical synthesis and specialty chemical manufacturing. OYSI maintains reliable supply chains for phosphonic acid, ensuring consistent availability for European industrial customers requiring this specialized organophosphorus compound.
Safety & Classification
Acute Tox. 4 *; Skin Corr. 1A
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2834 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Phosphorige Säure, wasserfrei, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is phosphonic acid?
Phosphonic acid is an organophosphorus compound with the molecular formula H3O3P and CAS number 13598-36-2. It has a molecular weight of 81.996 g/mol and serves as the parent compound of the phosphonate family. This chemical is classified as corrosive to skin (Skin Corr. 1A) and acutely toxic (Acute Tox. 4), requiring careful handling in industrial applications. It plays a crucial role in various chemical processes and manufacturing operations.
What are the physicochemical properties of phosphonic acid?
Phosphonic acid is typically a white crystalline solid at room temperature with high water solubility due to its polar phosphorus-oxygen bonds. The compound exhibits strong acidic properties with multiple ionizable hydrogen atoms. It demonstrates thermal stability under normal conditions but can decompose at elevated temperatures. Its molecular structure contains a phosphorus atom bonded to three hydroxyl groups, making it highly reactive and capable of forming stable complexes with metal ions.
What is phosphonic acid used for?
Phosphonic acid is used primarily as a building block in the synthesis of phosphonate esters and metal phosphonates. It serves as a precursor for producing flame retardants, corrosion inhibitors, and scale prevention agents in water treatment applications. The compound is also utilized in the pharmaceutical industry for drug development and in agriculture for the production of herbicides and plant growth regulators. Additionally, it finds applications in surface treatment and metal finishing processes.
How to handle phosphonic acid safely?
Phosphonic acid requires careful handling due to its corrosive nature and acute toxicity classification. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation. Emergency eyewash stations and safety showers should be readily accessible, and personnel should be trained in proper handling procedures before working with this substance.
How to store phosphonic acid correctly?
Phosphonic acid should be stored in a cool, dry, well-ventilated area away from incompatible materials and ignition sources. The storage area must be equipped with appropriate containment measures to prevent environmental release. Containers should be kept tightly closed and properly labeled according to GHS requirements. Due to its corrosive properties, storage facilities should have acid-resistant construction materials and appropriate emergency response equipment. Regular inspection of containers for signs of corrosion or leakage is essential.
What to do in case of contact with phosphonic acid?
Skin contact with phosphonic acid requires immediate removal of contaminated clothing and thorough washing with plenty of water for at least 15 minutes. Eye contact necessitates immediate flushing with clean water for at least 15 minutes while holding eyelids open. If ingested, rinse mouth with water but do not induce vomiting. In case of inhalation, move the person to fresh air immediately. Seek medical attention promptly in all cases of exposure, especially given the substance's corrosive classification.
How to dispose of phosphonic acid appropriately?
Phosphonic acid disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. The substance should never be disposed of down drains or in regular waste streams due to its corrosive properties. Disposal should be handled through licensed hazardous waste contractors who can ensure proper treatment or neutralization. Small quantities may be neutralized carefully by qualified personnel following established protocols, but large amounts require professional waste management services.
How to transport phosphonic acid?
Phosphonic acid is classified under ADR Class 8 (Corrosive substances), Packing Group III for transportation purposes. This classification requires appropriate hazardous goods packaging, labeling, and documentation during transport. Vehicles must carry proper emergency equipment and drivers need hazardous materials training certification. The substance must be transported in approved containers with corrosion-resistant properties and appropriate secondary containment. Transport documents must include the proper shipping name and UN identification number.
Is phosphonic acid subject to specific regulations?
Phosphonic acid is subject to various European regulations including REACH registration requirements and CLP classification standards. The substance is classified with GHS pictograms GHS05 (corrosion) and GHS07 (harmful), requiring appropriate safety data sheets and labeling. While not currently listed as a SVHC (Substance of Very High Concern), it must comply with occupational exposure limits and workplace safety regulations. Importers and users must ensure full regulatory compliance including proper registration and classification.
Where to buy phosphonic acid in Europe?
Phosphonic acid is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality phosphonic acid with complete documentation including safety data sheets, certificates of analysis, and regulatory compliance information. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical support for customers requiring this corrosive substance for their industrial applications and manufacturing processes.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.