Phosphonic acid
H3O3P
phosphonic acid
Consulting for Phosphonic acid
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Identification
- CAS Number
- 13598-36-2
- EC Number
- 237-066-7
- UN Number
- 2834
- Index Number
- 015-157-00-0
- PubChem CID
- 407
Physical-chemical properties
- Molecular Formula
- H3O3P
- Molar Mass
- 82.00 g/mol
- IUPAC Name
- phosphonic acid
Chemical Identifiers
- InChI
- InChI=1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)
- InChI Key
- ABLZXFCXXLZCGV-UHFFFAOYSA-N
Overview
Phosphonic acid (CAS 13598-36-2) is an organophosphorus compound with strong acidic properties and corrosive characteristics. Phosphonic acid represents a fundamental member of the organophosphorus family, distinguished by its unique molecular structure containing a phosphorus atom bonded to three oxygen atoms and one hydrogen atom. This inorganic acid exhibits remarkable versatility in industrial applications, making it an essential chemical intermediate for numerous manufacturing processes. The compound's molecular formula H3O3P reflects its simple yet highly reactive nature, with a molecular weight of 81.996 g/mol. The substance demonstrates significant corrosive properties, classified under GHS pictograms GHS05 and GHS07 with a "Danger" signal word. Its classification as Skin Corr. 1A and Acute Tox. 4 necessitates careful handling protocols and appropriate safety measures during storage and use. The ADR Class 8 designation confirms its corrosive nature for transport purposes. Unlike stronger acids such as sulfurofluoridic acid, phosphonic acid offers more manageable handling characteristics while maintaining effective chemical reactivity. Primary industrial applications include its use as a chemical intermediate in the synthesis of phosphonate compounds, flame retardants, and specialized cleaning formulations. The compound also serves as a crucial component in water treatment applications and metal surface preparation processes. Its acidic properties make it particularly valuable in industrial cleaning operations where controlled etching or surface modification is required. OYSI provides reliable access to phosphonic acid for European industrial customers, ensuring consistent quality and compliance with regional chemical regulations for diverse manufacturing applications.
Safety & Classification
Acute Tox. 4 *; Skin Corr. 1A
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2834 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Phosphorige Säure, wasserfrei, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is phosphonic acid?
Phosphonic acid is an organophosphorus compound with the molecular formula H3O3P and CAS number 13598-36-2. It has a molecular weight of 81.996 g/mol and serves as the parent compound of the phosphonic acid family. This chemical is classified as a corrosive substance with acute toxicity properties, requiring careful handling due to its hazardous nature and potential to cause severe skin burns and eye damage.
What are the physicochemical properties of phosphonic acid?
Phosphonic acid is typically a white crystalline solid at room temperature with high water solubility due to its polar phosphorus-oxygen bonds. The compound exhibits strong acidic properties with multiple ionizable hydrogen atoms, making it highly reactive with bases and metals. Its molecular structure contains a phosphorus atom bonded to three oxygen atoms and three hydrogen atoms, contributing to its corrosive characteristics and chemical stability.
What is phosphonic acid used for?
Phosphonic acid serves as a key intermediate in the production of various phosphonate compounds used in water treatment, metal surface treatment, and as corrosion inhibitors. It finds applications in the synthesis of chelating agents, flame retardants, and pharmaceutical intermediates. The compound is also utilized in industrial cleaning formulations and as a precursor for specialty chemicals in agriculture and electronics manufacturing.
How to handle phosphonic acid safely?
Phosphonic acid requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its Skin Corr. 1A classification. Work in well-ventilated areas or under fume hoods to avoid inhalation exposure. Always add the acid to water, never water to acid, to prevent violent reactions. Emergency eyewash stations and safety showers should be readily accessible when working with this corrosive material.
How to store phosphonic acid correctly?
Phosphonic acid should be stored in a cool, dry, well-ventilated area away from incompatible materials such as strong bases, metals, and oxidizing agents. Use corrosion-resistant containers made of appropriate materials and ensure proper labeling with hazard warnings. Storage areas must be equipped with spill containment measures and maintained at stable temperatures to prevent container degradation and accidental release of this corrosive substance.
What to do in case of contact with phosphonic acid?
Immediate action is critical due to phosphonic acid's corrosive nature. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15-20 minutes and remove contact lenses if present. Seek immediate medical attention for all exposure incidents as severe chemical burns may occur requiring professional treatment.
How to dispose of phosphonic acid appropriately?
Phosphonic acid disposal must comply with local and national hazardous waste regulations as it is classified as corrosive waste. Neutralization with appropriate alkaline materials under controlled conditions may be required before disposal. Contact licensed waste disposal companies specialized in handling corrosive chemicals. Never discharge directly into sewers, waterways, or soil as environmental contamination may result, and proper documentation of disposal activities is mandatory.
How to transport phosphonic acid?
Phosphonic acid is classified under ADR Class 8 (corrosive substances) Packing Group III for transportation purposes. Packaging must meet UN specification requirements for corrosive materials with appropriate labeling including GHS05 and GHS07 pictograms and 'Danger' signal word. Transport vehicles must carry proper documentation, emergency response information, and drivers require hazardous materials training certification for safe handling during transit.
Is phosphonic acid subject to particular regulations?
Phosphonic acid is subject to REACH regulation requiring registration for manufacturing or importing above one tonne per year in the EU. The substance is classified under CLP regulation with harmonized classification as Acute Tox. 4 and Skin Corr. 1A. While not currently listed as an SVHC substance, users must comply with safety data sheet requirements, workplace exposure limits, and proper risk assessment procedures.
Where to buy phosphonic acid in Europe?
Phosphonic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides quality chemical products with proper documentation, safety data sheets, and regulatory compliance support. For procurement inquiries, technical specifications, packaging options, and delivery arrangements, contact OYSI directly to discuss your phosphonic acid requirements and ensure proper handling throughout the supply chain.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.