Tribromophosphane

Br3P

tribromophosphane

CAS7789-60-8
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7789-60-8
EC Number
232-178-2
UN Number
1808
Index Number
015-103-00-6
PubChem CID
24614

Physical-chemical properties

Molecular Formula
Br3P
Molar Mass
270.69 g/mol
IUPAC Name
tribromophosphane

Chemical Identifiers

InChI
InChI=1S/Br3P/c1-4(2)3
InChI Key
IPNPIHIZVLFAFP-UHFFFAOYSA-N

Overview

Tribromophosphane (CAS 7789-60-8) is a phosphorus trihalide compound characterized by its highly reactive nature and corrosive properties. This inorganic compound, with the molecular formula Br3P and a molecular weight of 270.69 g/mol, represents one of the key phosphorus halides used in specialized chemical synthesis applications. Tribromophosphane exhibits significant reactivity due to the presence of three bromine atoms bonded to a central phosphorus atom, making it a valuable reagent in organophosphorus chemistry and advanced materials synthesis. The compound is classified under multiple hazard categories, including skin corrosion (Skin Corr. 1B) and specific target organ toxicity (STOT SE 3), requiring careful handling protocols and appropriate safety equipment. Its corrosive nature necessitates storage in suitable containment systems and handling by trained personnel following strict safety procedures. The substance carries GHS pictograms GHS05 and GHS07, indicating both corrosive and harmful properties, with "Danger" as the signal word. Tribromophosphane finds primary applications in the synthesis of organophosphorus compounds, particularly in pharmaceutical intermediate production and specialty chemical manufacturing. It serves as a brominating agent in organic synthesis and plays a crucial role in the preparation of phosphine derivatives. The compound is also utilized in advanced materials research, particularly in the development of flame retardant systems, where its phosphorus-bromine combination provides enhanced fire suppression properties. Unlike simpler inorganic compounds such as hydrogen chloride, tribromophosphane offers unique selectivity in bromination reactions due to its phosphorus center. OYSI maintains reliable supply chains for tribromophosphane to support European industrial customers requiring this specialized reagent.

Safety & Classification

Danger
Classification:

STOT SE 3; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1808
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NamePhosphortribromid
Marine PollutantNo

Frequently Asked Questions

What is tribromophosphane?

Tribromophosphane is an inorganic phosphorus compound with the molecular formula Br3P and CAS number 7789-60-8. This chemical substance has a molecular weight of 270.69 g/mol and belongs to the family of phosphorus trihalides. It is classified as a corrosive substance that can cause severe skin burns and eye damage, as well as specific target organ toxicity. Tribromophosphane is primarily used in specialized chemical synthesis and industrial applications requiring phosphorus-bromine chemistry.

What are the physicochemical properties of tribromophosphane?

Tribromophosphane is typically a liquid or solid at room temperature, depending on conditions, with a molecular weight of 270.69 g/mol. It is highly reactive with water and moisture, leading to hydrolysis reactions that produce phosphorous acid and hydrogen bromide. The compound has a pungent, irritating odor and is sensitive to air and humidity. Due to its reactive nature, it must be handled under inert atmosphere conditions to prevent decomposition and maintain product integrity.

What is tribromophosphane used for?

Tribromophosphane is primarily used as a reagent in organic and inorganic synthesis, particularly for bromination reactions and the preparation of phosphorus-containing compounds. It serves as an important intermediate in pharmaceutical synthesis, specialty chemical manufacturing, and research applications. The compound is utilized in the production of organophosphorus compounds and as a brominating agent in various industrial processes. Its specific reactivity makes it valuable for specialized chemical transformations in laboratory and industrial settings.

How to handle tribromophosphane safely?

Tribromophosphane requires careful handling due to its corrosive properties and classification as Skin Corr. 1B and STOT SE 3. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shield, and protective clothing covering all exposed skin. Work must be conducted in a well-ventilated area or under a fume hood to prevent inhalation exposure. Handle containers carefully to avoid spills, and ensure emergency eyewash and shower facilities are readily accessible during use.

How to store tribromophosphane correctly?

Tribromophosphane must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from moisture and incompatible materials. Storage should occur under inert gas atmosphere when possible to prevent hydrolysis and degradation. Keep away from heat sources, direct sunlight, and areas with temperature fluctuations. The storage area should be equipped with appropriate spill containment measures and emergency response equipment. Ensure containers are properly labeled and segregated from incompatible substances like water and oxidizing agents.

What to do in case of contact with tribromophosphane?

Tribromophosphane contact requires immediate emergency response due to its corrosive nature. For skin contact, immediately remove contaminated clothing and flush the affected area with large amounts of water for at least 15 minutes, then seek medical attention. In case of eye contact, rinse immediately with water for at least 15 minutes and get medical help urgently. If inhaled, move the person to fresh air and seek medical attention. Never induce vomiting if ingested; rinse mouth and seek immediate medical care.

How to dispose of tribromophosphane appropriately?

Tribromophosphane disposal must comply with local, national, and international hazardous waste regulations due to its corrosive classification. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal facilities. Small quantities may be neutralized carefully under controlled conditions by trained personnel, but this should only be done following established safety protocols. Contact certified waste disposal companies for proper collection, treatment, and disposal to ensure environmental protection and regulatory compliance.

How to transport tribromophosphane?

Tribromophosphane is classified under ADR Class 8 (corrosive substances), Packing Group II, indicating it requires specific transport regulations for dangerous goods. Packaging must meet UN specification requirements for corrosive liquids, with appropriate labeling including the corrosive hazard pictogram. Transport vehicles must carry proper documentation, emergency response information, and appropriate safety equipment. Only authorized carriers trained in dangerous goods transport should handle shipments, and specific routing restrictions may apply depending on local regulations.

Is tribromophosphane subject to specific regulations?

Tribromophosphane is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification as a corrosive substance with danger signal word. The compound is not currently listed as a Substance of Very High Concern (SVHC), but its corrosive properties require compliance with occupational health and safety regulations. Users must follow proper risk assessment procedures, maintain safety data sheets, and implement appropriate risk management measures. Export/import may require additional permits depending on destination countries and local chemical control laws.

Where to buy tribromophosphane in Europe?

Tribromophosphane is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemical products to industrial and research customers. As a regulated corrosive substance, purchases typically require proper business credentials and end-use documentation. OYSI can provide technical support, safety documentation, and ensure compliance with transport and handling regulations. Contact OYSI directly for availability, specifications, and delivery options, as this specialized chemical may require custom ordering and specific packaging arrangements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.