Pentane

C5H12

pentane

CAS109-66-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
109-66-0
EC Number
203-692-4
UN Number
1265
Index Number
601-006-00-1
PubChem CID
8003

Physical-chemical properties

Molecular Formula
C5H12
Molar Mass
72.15 g/mol
IUPAC Name
pentane

Chemical Identifiers

InChI
InChI=1S/C5H12/c1-3-5-4-2/h3-5H2,1-2H3
InChI Key
OFBQJSOFQDEBGM-UHFFFAOYSA-N

Overview

Pentane (CAS 109-66-0) is a straight-chain alkane hydrocarbon with five carbon atoms, characterized by high flammability and low boiling point properties. This linear saturated hydrocarbon belongs to the paraffin family and serves as an essential industrial solvent and chemical intermediate in various manufacturing processes. With its molecular formula C5H12 and molar mass of 72.15 g/mol, pentane exists as a colorless, volatile liquid at room temperature with a characteristic petroleum-like odor. The compound exhibits excellent solvent properties for non-polar substances and demonstrates rapid evaporation rates, making it valuable in specialized industrial applications. From a safety perspective, pentane presents significant hazard considerations requiring careful handling protocols. Classified as a Category 2 flammable liquid under GHS regulations, it poses serious fire and explosion risks due to its low flash point and wide flammability range. The substance also carries aspiration toxicity warnings (Category 1) and can cause specific target organ toxicity affecting the central nervous system. Additionally, pentane exhibits chronic aquatic toxicity, necessitating proper environmental protection measures during storage and use. Industrial applications of pentane primarily include its use as a blowing agent in expanded polystyrene foam production, as a solvent in adhesive formulations, and as a component in specialty fuel blends. Unlike more complex hydrocarbons such as propylbenzene or branched alkanes like 3-ethyl-3-methylpentane, pentane's simple linear structure provides unique volatility characteristics essential for foam manufacturing processes. The compound also finds applications in laboratory extraction procedures and as a reference standard in analytical chemistry. OYSI maintains reliable supplies of technical-grade pentane to support European industrial customers across various sectors requiring high-quality hydrocarbon solvents.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1265
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NamePentan, flüssig
Marine PollutantNo

Frequently Asked Questions

What is pentane?

Pentane is an organic compound with the molecular formula C5H12, belonging to the alkane family of hydrocarbons. It has a molecular weight of 72.15 g/mol and CAS number 109-66-0. This saturated hydrocarbon consists of five carbon atoms connected in a straight chain with hydrogen atoms. Pentane is classified as a highly flammable liquid with aspiration toxicity properties, making it a hazardous chemical requiring careful handling in industrial applications.

What are the physicochemical properties of pentane?

Pentane is a colorless, volatile liquid at room temperature with a characteristic gasoline-like odor. It has a low boiling point of approximately 36°C and is highly volatile, evaporating rapidly when exposed to air. The compound is practically insoluble in water but readily miscible with most organic solvents. Its low viscosity and density (around 0.626 g/cm³) make it an excellent solvent for various applications requiring quick evaporation and minimal residue.

What is pentane used for?

Pentane is primarily used as a blowing agent in the production of polystyrene foam and other expanded plastic materials. It serves as an extraction solvent in laboratories and industrial processes, particularly for oils and fats. The chemical industry utilizes pentane as a solvent for various reactions and as a component in specialty fuel blends. Additionally, it finds application in aerosol propellants and as a working fluid in certain refrigeration systems due to its volatility.

How to handle pentane safely?

Pentane requires strict safety measures including wearing appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods to prevent vapor accumulation. Eliminate all ignition sources including static electricity, sparks, and open flames. Use explosion-proof electrical equipment and ensure proper grounding of containers. Avoid skin contact and inhalation, as pentane poses aspiration toxicity risks if ingested.

How to store pentane correctly?

Pentane must be stored in a cool, well-ventilated area away from heat sources, sparks, and open flames in tightly sealed, grounded containers. Storage areas should be equipped with explosion-proof ventilation and electrical systems. Keep containers in upright position and protect from physical damage. Store separately from oxidizing agents, acids, and other incompatible materials. Maintain storage temperature below 25°C and ensure adequate fire suppression systems are available in the storage facility.

What to do in case of contact with pentane?

Pentane exposure requires immediate action depending on the route of contact. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes. If inhaled, move the person to fresh air and monitor breathing. Never induce vomiting if pentane is accidentally ingested due to aspiration toxicity risks. Seek immediate medical attention for any significant exposure, especially inhalation or ingestion.

How to dispose of pentane appropriately?

Pentane disposal must comply with local and national hazardous waste regulations as it is classified as flammable and potentially harmful to aquatic environments. Do not pour down drains, sewers, or onto the ground. Collect waste pentane in appropriate containers for professional hazardous waste disposal. Consider recovery and recycling options where feasible. Disposal should only be performed by licensed waste management companies equipped to handle flammable liquids according to environmental protection standards.

How to transport pentane?

Pentane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations compliance. Use UN-approved packaging and containers designed for flammable liquids. Transport vehicles must carry appropriate hazard placards and emergency response information. Drivers require ADR training certification for dangerous goods transport. Ensure proper documentation including transport documents and safety data sheets. Avoid transport during extreme temperatures and ensure adequate ventilation in transport compartments to prevent vapor accumulation.

Is pentane subject to particular regulations?

Pentane is subject to various European regulations including CLP regulation for classification, labeling, and packaging due to its hazardous properties. Under REACH regulation, it requires registration for commercial use. The substance is not currently listed as SVHC (Substance of Very High Concern). National and local regulations may impose additional restrictions on storage quantities, workplace exposure limits, and emission controls. Users must comply with industrial emissions directives and workplace safety regulations specific to flammable substances.

Where to buy pentane in Europe?

Pentane is available through OYSI, a European distributor specializing in technical chemicals for industrial applications. OYSI provides pentane in various packaging sizes suitable for different industrial needs, ensuring compliance with European safety and quality standards. As a specialized chemical distributor, OYSI offers technical support and proper documentation including safety data sheets and certificates of analysis. Contact OYSI directly for specific product grades, packaging options, and availability in your region across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.