Pentane

C5H12

pentane

CAS109-66-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
109-66-0
EC Number
203-692-4
UN Number
1265
Index Number
601-006-00-1
PubChem CID
8003

Physical-chemical properties

Molecular Formula
C5H12
Molar Mass
72.15 g/mol
IUPAC Name
pentane

Chemical Identifiers

InChI
InChI=1S/C5H12/c1-3-5-4-2/h3-5H2,1-2H3
InChI Key
OFBQJSOFQDEBGM-UHFFFAOYSA-N

Overview

Pentane (CAS 109-66-0) is a straight-chain alkane hydrocarbon with five carbon atoms, characterized by high flammability and low boiling point properties. This saturated hydrocarbon belongs to the paraffin family and serves as an essential industrial solvent and chemical intermediate across multiple sectors. With its molecular formula C5H12 and molecular weight of 72.15 g/mol, pentane exists as a colorless, volatile liquid at room temperature with a characteristic gasoline-like odor. The compound exhibits excellent solvent properties for non-polar substances, making it particularly valuable in extraction processes and specialized industrial applications. From a safety perspective, pentane requires careful handling due to its classification as a highly flammable liquid (Flam. Liq. 2) and aspiration toxicant (Asp. Tox. 1). The substance carries a "Danger" signal word and displays multiple GHS pictograms including flame, health hazard, exclamation mark, and environmental symbols. Its low flash point and high vapor pressure necessitate appropriate ventilation systems and ignition source controls in work environments. The compound also presents specific target organ toxicity concerns and chronic aquatic toxicity, requiring proper environmental protection measures during use and disposal. Industrial applications of pentane include its use as a blowing agent in expanded polystyrene foam production, as a solvent in laboratory extractions, and as a component in specialized cleaning formulations. The chemical industry also utilizes pentane in the manufacturing of other hydrocarbons, where its properties complement those of related compounds such as propylbenzene and 3-ethyl-3-methylpentane in various synthetic processes. OYSI supplies high-quality pentane to meet diverse industrial requirements across European markets, ensuring consistent product specifications and reliable delivery schedules.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1265
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NamePentan, flüssig
Marine PollutantNo

Frequently Asked Questions

What is pentane?

Pentane is an alkane hydrocarbon with the molecular formula C5H12 and CAS number 109-66-0. It is a straight-chain saturated hydrocarbon consisting of five carbon atoms linked by single bonds. With a molecular weight of 72.15 g/mol, pentane belongs to the family of light hydrocarbons and serves as an important industrial solvent and chemical intermediate in various applications.

What are the physicochemical properties of pentane?

Pentane is a colorless, volatile liquid at room temperature with a characteristic gasoline-like odor. It has a low boiling point of approximately 36°C and is highly flammable. Pentane is practically insoluble in water but miscible with most organic solvents including alcohols, ethers, and other hydrocarbons. Its low density (around 0.626 g/cm³) makes it lighter than water.

What is pentane used for?

Pentane is primarily used as a solvent in industrial processes and as a blowing agent in the production of polystyrene foam. It serves as a component in gasoline blends, a laboratory solvent for extractions and chromatography, and as a raw material in petrochemical synthesis. Additionally, pentane is used in the production of synthetic rubber and as a refrigerant in specialized cooling applications.

How to handle pentane safely?

Pentane requires careful handling due to its high flammability and potential health hazards. Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and work in well-ventilated areas. Eliminate all ignition sources as pentane vapors can form explosive mixtures with air. Avoid skin contact and inhalation, as it can cause central nervous system depression and aspiration hazards.

How to store pentane correctly?

Pentane must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use only approved containers and ensure proper grounding to prevent static electricity buildup. Store separately from oxidizing agents and strong acids. Maintain storage temperature below 25°C and ensure adequate fire suppression systems are in place due to its Class II flammable liquid classification.

What to do in case of contact with pentane?

In case of skin contact, immediately remove contaminated clothing and wash the affected area with soap and water for at least 15 minutes. If pentane is inhaled, move the person to fresh air immediately and seek medical attention if breathing difficulties occur. For eye contact, rinse thoroughly with clean water for 15 minutes. Never induce vomiting if swallowed due to aspiration toxicity risks.

How to dispose of pentane appropriately?

Pentane disposal must comply with local environmental regulations as it is classified as hazardous waste. Never pour pentane down drains or onto soil. Collect waste pentane in appropriate containers and arrange disposal through licensed hazardous waste management companies. Small quantities can be recovered through distillation for reuse, while contaminated pentane requires professional treatment or incineration at approved facilities.

How to transport pentane?

Pentane is classified as ADR Class 3 (flammable liquids), Packing Group II, requiring specialized transport procedures. It must be transported in UN-approved containers with proper hazard labels including GHS02, GHS07, GHS08, and GHS09 pictograms. Vehicles must be equipped with appropriate fire extinguishers and drivers require ADR certification. Transport documentation must include proper shipping names and emergency response information.

Is pentane subject to particular regulations?

Pentane is regulated under various European legislations including REACH registration requirements and CLP classification as Flam. Liq. 2, Asp. Tox. 1, STOT SE 3, and Aquatic Chronic 2. It carries the signal word 'Danger' and requires safety data sheets for commercial use. While not currently listed as an SVHC substance, users must comply with occupational exposure limits and environmental discharge restrictions.

Where to buy pentane in Europe?

Pentane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality pentane with complete documentation including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures regulatory compliance and reliable supply chains for industrial users requiring pentane for various applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.