Propylbenzene

C9H12

propylbenzene

CAS103-65-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
103-65-1
EC Number
203-132-9
UN Number
2364
Index Number
601-097-00-8
PubChem CID
7668

Physical-chemical properties

Molecular Formula
C9H12
Molar Mass
120.19 g/mol
IUPAC Name
propylbenzene

Chemical Identifiers

InChI
InChI=1S/C9H12/c1-2-6-9-7-4-3-5-8-9/h3-5,7-8H,2,6H2,1H3
InChI Key
ODLMAHJVESYWTB-UHFFFAOYSA-N

Overview

Propylbenzene (CAS 103-65-1) is an aromatic hydrocarbon solvent with flammable properties and industrial applications in chemical synthesis. This colorless liquid compound belongs to the alkylbenzene family and serves as an important intermediate in various chemical processes. With its molecular formula C9H12 and molecular weight of 120.19 g/mol, propylbenzene exhibits typical aromatic characteristics while maintaining distinct solvent properties that make it valuable across multiple industrial sectors. From a safety perspective, propylbenzene requires careful handling due to its classification as a flammable liquid (Category 3) and aspiration toxicant (Category 1). The substance presents respiratory hazards and may cause drowsiness or dizziness upon exposure, necessitating proper ventilation and personal protective equipment during use. Its aquatic chronic toxicity classification also demands responsible environmental management practices during storage, handling, and disposal. The compound finds primary applications in chemical manufacturing as a solvent and reaction medium, particularly in the production of specialty chemicals and pharmaceutical intermediates. Additionally, it serves as a raw material in the synthesis of surfactants and polymer additives. Like related compounds such as 3-ethyl-3-methylpentane, propylbenzene's solvent properties make it suitable for extraction processes and as a carrier fluid in various formulations. Industries utilizing propylbenzene include fine chemicals manufacturing, pharmaceutical production, and specialty polymer synthesis, where its specific solvation characteristics and chemical stability prove advantageous. The substance's aromatic nature allows for selective dissolution of organic compounds while maintaining process efficiency. OYSI maintains reliable supply chains for propylbenzene, ensuring consistent availability for European customers requiring this specialized aromatic solvent for their technical applications.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H335

May cause respiratory irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2364
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namen-Propylbenzen
Marine PollutantNo

Frequently Asked Questions

What is propylbenzene?

Propylbenzene is an aromatic hydrocarbon with the molecular formula C9H12 and CAS number 103-65-1. It consists of a benzene ring attached to a propyl group, with a molecular weight of 120.19 g/mol. This flammable liquid belongs to the alkylbenzene family and is classified as a hazardous substance under CLP regulation due to its flammability, aspiration toxicity, and potential environmental impact.

What are the physicochemical properties of propylbenzene?

Propylbenzene is a colorless to pale yellow liquid at room temperature with a characteristic aromatic odor. It has low water solubility but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound exhibits typical aromatic properties with moderate volatility and is lighter than water. Its physicochemical properties make it suitable for use as a solvent and chemical intermediate in various industrial applications.

What is propylbenzene used for?

Propylbenzene is primarily used as a chemical intermediate in the production of other aromatic compounds and as an industrial solvent. It serves in the manufacture of surfactants, resins, and specialty chemicals. The compound is also utilized in the production of styrene derivatives and as a component in certain formulations requiring aromatic solvents. Its applications span across chemical manufacturing, pharmaceutical intermediates, and specialized industrial processes.

How to handle propylbenzene safely?

Propylbenzene requires careful handling due to its flammable nature and health hazards. Use appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. Work in well-ventilated spaces away from ignition sources, as the substance can form explosive vapor-air mixtures. Avoid skin contact and inhalation, and ensure proper grounding of equipment to prevent static electricity buildup during transfer operations.

How to store propylbenzene correctly?

Propylbenzene must be stored in cool, dry, well-ventilated areas away from heat sources, sparks, and open flames. Use appropriate containers made of compatible materials and ensure proper labeling according to CLP regulations. Keep away from oxidizing agents and strong acids to prevent incompatible reactions. Storage areas should be equipped with fire suppression systems and spill containment measures, with temperatures maintained below the substance's flash point.

What to do in case of contact with propylbenzene?

Propylbenzene exposure requires immediate first aid measures. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air and monitor breathing. Never induce vomiting if swallowed due to aspiration hazard - seek immediate medical attention and provide the safety data sheet to healthcare professionals.

How to dispose of propylbenzene appropriately?

Propylbenzene disposal must comply with local and European waste regulations as hazardous waste. The substance cannot be disposed of down drains or with regular waste due to its environmental classification. Contact licensed waste disposal companies for proper treatment, which typically involves incineration at appropriate facilities. Small quantities should be collected and stored in original or compatible containers until professional disposal, ensuring proper labeling and documentation throughout the process.

How to transport propylbenzene?

Propylbenzene is classified as ADR Class 3 (flammable liquids), Packing Group III for transport purposes. Packages must bear appropriate hazard labels and markings according to ADR regulations. Use UN-approved packaging suitable for flammable liquids and ensure proper documentation including transport documents. Vehicles must comply with ADR requirements for Class 3 substances, including appropriate equipment and driver certification for hazardous goods transport.

Is propylbenzene subject to specific regulations?

Propylbenzene is regulated under European CLP and REACH regulations due to its hazardous classification. It requires safety data sheets and appropriate labeling with danger pictograms GHS02, GHS07, GHS08, and GHS09. The substance is not currently listed as SVHC under REACH but must comply with standard registration requirements. Users must implement appropriate risk management measures and ensure compliance with occupational exposure limits and environmental protection requirements.

Where to buy propylbenzene in Europe?

Propylbenzene is available through OYSI, a specialized European distributor of industrial chemicals. As an established chemical supplier, OYSI can provide propylbenzene with proper documentation, safety data sheets, and regulatory compliance support. Contact OYSI directly to discuss specific requirements, quantities, and delivery options across European markets. Professional chemical distributors ensure product quality, proper packaging, and adherence to transportation and safety regulations for hazardous substances.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.