Propylbenzene

C9H12

propylbenzene

CAS103-65-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
103-65-1
EC Number
203-132-9
UN Number
2364
Index Number
601-097-00-8
PubChem CID
7668

Physical-chemical properties

Molecular Formula
C9H12
Molar Mass
120.19 g/mol
IUPAC Name
propylbenzene

Chemical Identifiers

InChI
InChI=1S/C9H12/c1-2-6-9-7-4-3-5-8-9/h3-5,7-8H,2,6H2,1H3
InChI Key
ODLMAHJVESYWTB-UHFFFAOYSA-N

Overview

Propylbenzene (CAS 103-65-1) is an aromatic hydrocarbon compound characterized by its flammable properties and industrial solvent applications. This organic chemical belongs to the alkylbenzene family, consisting of a benzene ring with a three-carbon propyl chain attached. With the molecular formula C9H12 and a molecular weight of 120.19 g/mol, propylbenzene presents as a colorless liquid with characteristic aromatic odor. The compound is classified under multiple hazard categories, requiring careful handling protocols due to its flammable nature (Flam. Liq. 3), aspiration toxicity potential (Asp. Tox. 1), and specific target organ toxicity (STOT SE 3). The substance exhibits typical properties of aromatic hydrocarbons, showing limited water solubility but good miscibility with organic solvents. Its safety profile demands attention to fire prevention measures, proper ventilation systems, and appropriate personal protective equipment during handling. The classification as ADR Class 3 substance requires compliance with transportation regulations for flammable liquids. Environmental considerations include its Aquatic Chronic 2 classification, necessitating prevention of environmental releases. Primary industrial applications include its use as a chemical intermediate in pharmaceutical and fine chemical synthesis, as a solvent in various manufacturing processes, and as a component in specialty chemical formulations. The compound shares structural similarities with other alkylbenzene derivatives and hydrocarbons like 3-ethyl-3-methylpentane, though each exhibits distinct physical and chemical properties suited to specific applications. OYSI maintains reliable supply chains for propylbenzene, ensuring consistent availability to meet diverse industrial requirements across European markets.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H335

May cause respiratory irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2364
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namen-Propylbenzen
Marine PollutantNo

Frequently Asked Questions

What is propylbenzene?

Propylbenzene is an aromatic hydrocarbon compound with the molecular formula C9H12 and CAS number 103-65-1. It consists of a benzene ring with a propyl group attached, having a molecular weight of 120.19 g/mol. This flammable liquid belongs to the alkylbenzene family and is classified as a hazardous substance requiring careful handling due to its flammability and potential health effects.

What are the physicochemical properties of propylbenzene?

Propylbenzene is a colorless liquid with a characteristic aromatic odor typical of benzene derivatives. It has low water solubility but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound has a relatively low vapor pressure and moderate volatility at room temperature, making it suitable for various industrial applications while requiring appropriate ventilation during use.

What is propylbenzene used for?

Propylbenzene is primarily used as an intermediate in chemical synthesis and as a solvent in various industrial processes. It serves as a precursor for the production of other aromatic compounds, including pharmaceuticals, dyes, and specialty chemicals. Additionally, it finds application in the manufacture of surfactants, polymer additives, and as a component in certain formulations requiring aromatic solvents with specific properties.

How to handle propylbenzene safely?

Propylbenzene requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems to prevent inhalation exposure. Avoid contact with skin and eyes, eliminate ignition sources due to its flammable nature, and ensure proper grounding of equipment to prevent static electricity buildup during transfer operations.

How to store propylbenzene correctly?

Propylbenzene should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Storage areas must be equipped with appropriate fire suppression systems and spill containment measures. Keep containers away from incompatible materials such as strong oxidizing agents and ensure storage temperatures remain within recommended limits to maintain product stability and safety.

What to do in case of contact with propylbenzene?

Propylbenzene contact requires immediate action: for skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting due to aspiration toxicity risk and seek immediate medical care.

How to dispose of propylbenzene appropriately?

Propylbenzene disposal must comply with local and national waste regulations as it is classified as hazardous waste. The substance should be collected in appropriate containers and disposed of through licensed hazardous waste treatment facilities. Incineration at high temperatures in authorized facilities is typically the preferred disposal method. Never discharge into sewers, waterways, or soil due to its environmental impact classification.

How to transport propylbenzene?

Propylbenzene is classified under ADR Class 3 (flammable liquids), Packing Group III for transportation. It requires appropriate UN-specification packaging, proper labeling with hazard pictograms, and transport documentation including safety data sheets. Vehicles must be equipped with appropriate fire extinguishing equipment, and drivers require ADR training certification. Emergency response information must accompany shipments during transport.

Is propylbenzene subject to specific regulations?

Propylbenzene is subject to various European regulations including REACH registration requirements and CLP classification obligations. It must be labeled with GHS pictograms (GHS02, GHS08, GHS07, GHS09) and carry the signal word 'Danger'. While not currently listed as a SVHC substance, it requires compliance with occupational exposure limits and environmental protection measures in accordance with national implementations of EU directives.

Where to buy propylbenzene in Europe?

Propylbenzene is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality propylbenzene with complete documentation including safety data sheets, certificates of analysis, and regulatory compliance information. Their technical expertise ensures proper handling guidance and regulatory support for customers requiring this aromatic compound for industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.