Methylcyclohexane

C7H14

methylcyclohexane

CAS108-87-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
108-87-2
EC Number
203-624-3
UN Number
2296
Index Number
601-018-00-7
PubChem CID
7962

Physical-chemical properties

Molecular Formula
C7H14
Molar Mass
98.19 g/mol
IUPAC Name
methylcyclohexane

Chemical Identifiers

InChI
InChI=1S/C7H14/c1-7-5-3-2-4-6-7/h7H,2-6H2,1H3
InChI Key
UAEPNZWRGJTJPN-UHFFFAOYSA-N

Overview

Methylcyclohexane (CAS 108-87-2) is a saturated cyclic hydrocarbon with flammable properties and moderate toxicity concerns. This colorless liquid belongs to the cycloalkane family and serves as an important industrial solvent and chemical intermediate in various manufacturing processes. With its molecular formula C7H14 and molecular weight of 98.19 g/mol, methylcyclohexane exhibits characteristic properties of saturated hydrocarbons while maintaining the structural stability provided by its six-membered ring structure. From a safety perspective, methylcyclohexane requires careful handling due to its classification as a flammable liquid (Category 2) and aspiration toxicant (Category 1). The substance carries a "Danger" signal word and displays multiple GHS pictograms including flame, health hazard, exclamation mark, and environmental symbols. Operators must implement appropriate fire prevention measures and ensure adequate ventilation, as the compound can cause skin irritation and specific target organ toxicity affecting the central nervous system. Its classification under ADR Class 3 mandates compliance with transportation regulations for flammable liquids. Industrially, methylcyclohexane finds primary application as a solvent in paint formulations, adhesives, and rubber processing operations. The chemical industry also utilizes it as an intermediate in the synthesis of various organic compounds and as a component in specialty cleaning formulations. Its solvent properties make it particularly valuable in applications requiring moderate polarity and good dissolving capacity for organic materials. Like related compounds such as 1,4-dimethylcyclohexane, it serves specialized roles in chemical manufacturing where specific cyclic hydrocarbon characteristics are essential. OYSI maintains reliable supply chains for methylcyclohexane to support diverse industrial applications across European markets.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Asp. Tox. 1; STOT SE 3; Skin Irrit. 2; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H315

Causes skin irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2296
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameMethylcyclohexan
Marine PollutantNo

Frequently Asked Questions

What is methylcyclohexane?

Methylcyclohexane is a cycloalkane hydrocarbon with the molecular formula C7H14 and CAS number 108-87-2. It consists of a cyclohexane ring with one methyl group attached. This organic compound has a molecular weight of 98.19 g/mol and belongs to the family of saturated hydrocarbons. It is classified as a flammable liquid with significant health hazards including aspiration toxicity and skin irritation properties.

What are the physicochemical properties of methylcyclohexane?

Methylcyclohexane is a colorless liquid at room temperature with a characteristic hydrocarbon odor. It has low water solubility due to its nonpolar nature but is miscible with most organic solvents. The compound exhibits typical properties of cycloalkanes with a boiling point around 100°C and density lower than water. Its saturated ring structure provides chemical stability under normal conditions.

What is methylcyclohexane used for?

Methylcyclohexane is primarily used as a solvent in various industrial applications including paint thinners, adhesives, and coating formulations. It serves as an extraction solvent in chemical processes and as a component in fuel blends. The compound is also utilized in chromatography applications and as an intermediate in organic synthesis reactions. Its properties make it suitable for degreasing and cleaning applications in industrial settings.

How to handle methylcyclohexane safely?

Methylcyclohexane requires careful handling due to its flammable and toxic properties. Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation and eliminate ignition sources. Use explosion-proof electrical equipment and grounding procedures. Avoid skin contact and inhalation as the substance can cause skin irritation and has aspiration toxicity hazards.

How to store methylcyclohexane correctly?

Methylcyclohexane must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use appropriate containers made of compatible materials and keep them tightly sealed. Store away from oxidizing agents and incompatible substances. Implement proper fire prevention measures and ensure storage areas comply with local regulations for flammable liquids. Maintain temperatures below flash point and provide spill containment.

What to do in case of contact with methylcyclohexane?

Methylcyclohexane contact requires immediate action depending on exposure route. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes. If inhaled, move to fresh air immediately. Never induce vomiting if ingested due to aspiration toxicity risk. Seek immediate medical attention for any significant exposure or if symptoms develop.

How to dispose of methylcyclohexane properly?

Methylcyclohexane disposal must comply with local and national waste regulations as it is classified as hazardous waste. Contact licensed waste disposal companies for proper treatment and disposal. Do not discharge to sewers, waterways, or soil due to environmental hazards. Small quantities may be disposed of through authorized collection programs. Consider recycling or recovery options where available. Maintain proper documentation of disposal activities as required by regulations.

How to transport methylcyclohexane?

Methylcyclohexane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations. Use appropriate packaging materials and labeling including GHS pictograms (GHS02, GHS08, GHS07, GHS09) and danger signal word. Ensure proper documentation including safety data sheets and transport documents. Drivers must have appropriate training for hazardous materials transport. Vehicles must comply with ADR equipment requirements for Class 3 substances.

Is methylcyclohexane subject to specific regulations?

Methylcyclohexane is regulated under various European chemical legislations including REACH and CLP regulations. It requires safety data sheets and proper classification labeling due to its hazardous properties. The substance is not currently listed as SVHC under REACH. Workplace exposure limits may apply under occupational health regulations. Users must comply with local environmental discharge limits and waste disposal requirements. Industrial users may need to register quantities under REACH provisions.

Where to buy methylcyclohexane in Europe?

Methylcyclohexane is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides reliable supply chains across Europe with proper documentation and regulatory compliance support. When sourcing methylcyclohexane, ensure suppliers provide complete safety data sheets, certificates of analysis, and comply with REACH requirements. Consider factors such as purity grades, packaging options, and delivery logistics when selecting suppliers for industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.