2-methylbutane

C5H12

CAS78-78-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
78-78-4
EC Number
201-142-8
UN Number
1265
Index Number
601-085-00-2
PubChem CID
6556

Physical-chemical properties

Molecular Formula
C5H12
Molar Mass
72.15 g/mol
IUPAC Name
2-methylbutane

Chemical Identifiers

InChI
InChI=1S/C5H12/c1-4-5(2)3/h5H,4H2,1-3H3
InChI Key
QWTDNUCVQCZILF-UHFFFAOYSA-N

Overview

2-methylbutane (CAS 78-78-4) is a branched-chain alkane hydrocarbon with highly flammable properties and low boiling point characteristics. This pentane isomer represents a significant component in the petroleum industry, distinguished by its branched molecular structure that imparts unique physical and chemical properties compared to its linear counterpart, n-pentane. As a volatile organic compound with the molecular formula C5H12, 2-methylbutane exhibits exceptional volatility and flammability characteristics that make it valuable across multiple industrial applications while requiring careful handling protocols. The substance presents as a colorless liquid at room temperature with a characteristic petroleum-like odor. Its branched structure results in a lower boiling point compared to straight-chain pentanes, enhancing its utility as a blowing agent and extraction solvent. The compound's classification under GHS includes Flammable Liquid Category 1 and Aspiration Toxicity Category 1, necessitating stringent safety measures during storage, handling, and transportation under ADR Class 3 regulations. Key industrial applications include its use as a blowing agent in foam production, where its controlled volatility enables precise cellular structure formation. The chemical also serves as an extraction solvent in specialized processes and as a component in fuel formulations where its octane-enhancing properties prove beneficial. Unlike more complex hydrocarbons such as propylbenzene, 2-methylbutane's simple branched structure provides predictable behavior in industrial processes. The compound requires careful environmental consideration due to its Aquatic Chronic Category 2 classification, demanding appropriate containment and waste management procedures. Its STOT SE 3 classification indicates potential for specific target organ toxicity following single exposure, particularly affecting the central nervous system. OYSI maintains reliable supply chains for 2-methylbutane, ensuring consistent availability for European industrial customers requiring this specialized hydrocarbon for their manufacturing processes.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1265
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameIsopentan, flüssig
Marine PollutantNo

Frequently Asked Questions

What is 2-methylbutane?

2-methylbutane is a branched-chain alkane hydrocarbon with the molecular formula C5H12 and CAS number 78-78-4. It is an isomer of pentane, characterized by a methyl group attached to the second carbon of a four-carbon chain. With a molecular weight of 72.15 g/mol, this volatile organic compound is classified as a highly flammable liquid and poses significant safety risks including aspiration toxicity and narcotic effects at high concentrations.

What are the physicochemical properties of 2-methylbutane?

2-methylbutane is a colorless liquid at room temperature with a characteristic gasoline-like odor. It has a relatively low boiling point and high volatility, making it readily evaporable. The compound is practically insoluble in water but miscible with most organic solvents. Its branched structure gives it different physical properties compared to its linear isomer n-pentane, including slightly different boiling and melting points, while maintaining similar density and flammability characteristics.

What is 2-methylbutane used for?

2-methylbutane is primarily used as a component in gasoline blending due to its high octane rating and favorable combustion properties. It serves as a solvent in various industrial processes and chemical syntheses. The compound is also utilized in the production of other chemicals through cracking and reforming processes in petrochemical industries. Additionally, it can be used as a reference standard in analytical chemistry and as a blowing agent in some specialized applications.

How to handle 2-methylbutane safely?

2-methylbutane requires strict safety measures due to its extreme flammability and health hazards. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. All ignition sources must be eliminated, and only explosion-proof electrical equipment should be used. Work areas must be well-ventilated, and static electricity buildup should be prevented through proper grounding. Emergency procedures and spill response materials must be readily available.

How to store 2-methylbutane correctly?

2-methylbutane must be stored in cool, well-ventilated areas away from heat sources, sparks, and open flames. Storage containers should be made of compatible materials and kept tightly sealed to prevent vapor release. The storage area must be equipped with explosion-proof electrical equipment and proper fire suppression systems. Keep away from oxidizing agents and other incompatible materials. Regular inspection of containers for leaks is essential, and storage should comply with local flammable liquid regulations.

What to do in case of contact with 2-methylbutane?

Skin contact with 2-methylbutane requires immediate removal of contaminated clothing and washing the affected area with soap and water. For eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and monitor for respiratory difficulties. In case of ingestion, do not induce vomiting due to aspiration hazard - seek immediate medical attention. Remove all ignition sources and ensure proper ventilation in the contaminated area.

How to dispose of 2-methylbutane properly?

2-methylbutane disposal must comply with local and European waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or released into the environment due to its aquatic toxicity. Disposal should be handled by licensed waste management companies through appropriate methods such as incineration in specialized facilities. Empty containers may still contain hazardous residues and require proper cleaning or disposal. Consult local authorities for specific disposal requirements and approved facilities.

How to transport 2-methylbutane?

2-methylbutane is classified as ADR Class 3 (flammable liquids), Packing Group I, indicating high danger during transport. Transportation requires UN-specification packaging and proper hazard labeling with appropriate placards. Vehicles must comply with ADR requirements including electrical equipment specifications and emergency equipment. Transport documents must include proper shipping names, hazard classes, and emergency response information. Only trained personnel should handle transportation, and routes should avoid populated areas where possible.

Is 2-methylbutane subject to specific regulations?

2-methylbutane is subject to various European regulations including CLP (Classification, Labelling and Packaging) requiring specific hazard pictogrammes (GHS02, GHS07, GHS08, GHS09) and danger signal word. It falls under REACH regulation for chemical registration and evaluation, though it is not currently listed as a SVHC (Substance of Very High Concern). Users must comply with occupational safety regulations, environmental protection laws, and transport regulations (ADR). Industrial emissions may be subject to additional environmental permits and monitoring requirements.

Where to buy 2-methylbutane in Europe?

2-methylbutane is available through OYSI, a trusted European distributor of technical chemicals serving various industries across the continent. As a specialized chemical distributor, OYSI can provide proper documentation, safety data sheets, and regulatory compliance information required for this hazardous substance. Professional buyers should ensure their supplier meets all regulatory requirements for handling and distributing flammable chemicals. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.