2-methylbutane

C5H12

CAS78-78-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
78-78-4
EC Number
201-142-8
UN Number
1265
Index Number
601-085-00-2
PubChem CID
6556

Physical-chemical properties

Molecular Formula
C5H12
Molar Mass
72.15 g/mol
IUPAC Name
2-methylbutane

Chemical Identifiers

InChI
InChI=1S/C5H12/c1-4-5(2)3/h5H,4H2,1-3H3
InChI Key
QWTDNUCVQCZILF-UHFFFAOYSA-N

Overview

2-methylbutane (CAS 78-78-4) is a branched-chain alkane hydrocarbon with highly flammable properties and low boiling point characteristics. This pentane isomer, also known as isopentane, represents one of the three structural isomers of C5H12 hydrocarbons. With its molecular weight of 72.15 g/mol and branched carbon chain structure, 2-methylbutane exhibits distinct physical and chemical properties that differentiate it from its linear counterpart, n-pentane. The compound belongs to the saturated hydrocarbon family, sharing structural similarities with other branched alkanes such as 3-ethyl-3-methylpentane, though with significantly different molecular complexity. The substance presents considerable safety considerations due to its classification as a Category 1 flammable liquid and Category 1 aspiration toxicant. Its extremely low flash point and high volatility require strict handling protocols under ADR Class 3 transportation regulations. The GHS hazard pictograms indicate multiple risk categories including fire hazard, health hazard, and environmental concerns, with chronic aquatic toxicity classification requiring careful environmental management. Industrial applications of 2-methylbutane primarily center on its use as a blowing agent in polyurethane foam production, where its low boiling point and expansion properties prove valuable. The petrochemical industry utilizes this isomer as a specialty solvent and as an intermediate in organic synthesis processes. Additionally, it serves as a component in certain fuel formulations where its octane-enhancing properties contribute to improved combustion characteristics. OYSI maintains reliable European distribution channels for 2-methylbutane, ensuring consistent supply for industrial applications while adhering to stringent safety and regulatory compliance standards.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Asp. Tox. 1; STOT SE 3; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1265
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameIsopentan, flüssig
Marine PollutantNo

Frequently Asked Questions

What is 2-methylbutane?

2-methylbutane is a branched-chain alkane hydrocarbon with the molecular formula C5H12 and CAS number 78-78-4. It is an isomer of pentane, featuring a methyl group attached to the second carbon of a four-carbon chain. This colorless, highly flammable liquid has a molecular weight of 72.15 g/mol and belongs to the family of saturated hydrocarbons, making it a volatile organic compound commonly used in industrial applications.

What are the physicochemical properties of 2-methylbutane?

2-methylbutane is a colorless liquid with a characteristic gasoline-like odor at room temperature. It has a low boiling point and high volatility, making it readily evaporable. The compound is practically insoluble in water but highly soluble in organic solvents like alcohols and ethers. Its branched structure gives it different physical properties compared to its straight-chain isomer n-pentane, including slightly lower boiling point and different octane rating characteristics.

What is 2-methylbutane used for?

2-methylbutane is primarily used as a component in gasoline blends due to its favorable octane properties. It serves as a solvent in various industrial processes and as a raw material in petrochemical synthesis. The compound is also utilized in the production of other chemicals through cracking and reforming processes. Additionally, it finds applications in laboratory settings as an extraction solvent and in calibration standards for analytical instruments.

How to handle 2-methylbutane safely?

2-methylbutane requires careful handling due to its extreme flammability and health hazards. Use appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and flame-resistant clothing. Work in well-ventilated areas or under fume hoods to prevent vapor accumulation. Eliminate all ignition sources including static electricity, open flames, and hot surfaces. Ground all equipment to prevent static discharge and use explosion-proof electrical equipment when working with this substance.

How to store 2-methylbutane correctly?

2-methylbutane must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and ignition points. Use appropriate storage containers designed for flammable liquids and ensure proper grounding to prevent static electricity buildup. Keep away from oxidizing agents and strong acids. Storage areas should be equipped with appropriate fire suppression systems and maintained below recommended temperature limits to minimize vapor formation and explosion risks.

What to do in case of contact with 2-methylbutane?

In case of skin contact with 2-methylbutane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and monitor for respiratory distress. In case of ingestion, do not induce vomiting due to aspiration toxicity risks and seek immediate medical attention.

How to dispose of 2-methylbutane properly?

2-methylbutane must be disposed of as hazardous waste according to local and national environmental regulations. Never pour it down drains, toilets, or onto soil as it poses environmental risks to aquatic systems. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities can be disposed of through solvent recovery programs or incineration at appropriate high-temperature facilities equipped with pollution control systems to prevent environmental contamination.

How to transport 2-methylbutane?

2-methylbutane is classified as ADR Class 3 (flammable liquid) Packing Group I, indicating high danger level for transport. It requires appropriate UN-specification packaging and proper labeling with flammable liquid hazard labels. Transport vehicles must be equipped with appropriate safety equipment and drivers must have ADR certification. Shipping documents must include proper shipping names, hazard classes, and emergency contact information. Follow all applicable transport regulations for dangerous goods.

Is 2-methylbutane subject to specific regulations?

2-methylbutane is subject to various European chemical regulations including CLP (Classification, Labelling and Packaging) and REACH registration requirements. It is not classified as a Substance of Very High Concern (SVHC) but requires appropriate hazard communication through safety data sheets and product labeling. Workplace exposure limits may apply, and users must comply with environmental discharge regulations due to its aquatic toxicity classification and flammability restrictions.

Where to buy 2-methylbutane in Europe?

2-methylbutane is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. As a specialized chemical distributor, OYSI provides quality 2-methylbutane with appropriate documentation including safety data sheets and certificates of analysis. Contact OYSI directly for availability, technical specifications, packaging options, and delivery throughout European markets. Professional technical support is available to assist with product selection and regulatory compliance requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.