Lithium hypochlorite

ClLiO

lithium hypochlorite

CAS13840-33-0

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Identification

CAS Number
13840-33-0
EC Number
237-558-1
UN Number
1471
PubChem CID
23665767

Physical-chemical properties

Molecular Formula
ClLiO
Molar Mass
58.40 g/mol
IUPAC Name
lithium hypochlorite

Chemical Identifiers

InChI
InChI=1S/ClO.Li/c1-2;/q-1;+1
InChI Key
LWXVCCOAQYNXNX-UHFFFAOYSA-N

Overview

Lithium hypochlorite (CAS 13840-33-0) is an inorganic oxidizing compound with strong bleaching and disinfecting properties. This lithium-based hypochlorite salt represents a specialized alternative to more common hypochlorite compounds in industrial applications. With the molecular formula ClLiO and a molecular weight of 58.4 g/mol, lithium hypochlorite offers unique advantages in specific chemical processes where lithium compatibility is required or where reduced cation interference is beneficial. As a member of the hypochlorite family, this compound shares oxidizing characteristics with related materials, though it differs significantly from compounds like calcium dichlorate dihydrate in terms of solubility profiles and cation effects. The lithium cation provides distinct advantages in certain electrochemical applications and specialized synthesis procedures. Lithium hypochlorite is classified under ADR Class 5.1 as an oxidizing substance, requiring appropriate handling protocols during transportation and storage. The compound exhibits typical hypochlorite reactivity, including sensitivity to heat, light, and incompatibility with reducing agents and organic materials. Proper storage conditions include cool, dry environments away from direct sunlight and incompatible substances. Industrial applications include specialized water treatment systems where lithium tolerance is essential, certain electrochemical processes, and niche chemical synthesis applications where conventional sodium or calcium hypochlorites may interfere with desired reactions. The compound also finds use in specific battery technologies and advanced materials processing where lithium-based chemistry is preferred. Additional applications encompass controlled oxidation reactions in pharmaceutical intermediates and specialty chemical manufacturing, particularly where precise pH control and minimal metallic impurities are critical parameters. OYSI provides lithium hypochlorite to European industrial customers requiring this specialized oxidizing agent for technical applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1471
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameLithiumhypochlorit, trocken, entzündend (oxidierend) wirkend
Marine PollutantNo

Frequently Asked Questions

What is lithium hypochlorite?

Lithium hypochlorite is an inorganic compound with the chemical formula ClLiO and CAS number 13840-33-0. It has a molecular weight of 58.4 g/mol and belongs to the family of hypochlorite salts. This compound is primarily used as an oxidizing agent and disinfectant in various industrial applications. Like other hypochlorites, it releases chlorine when dissolved in water, making it effective for sanitization purposes.

What are the physicochemical properties of lithium hypochlorite?

Lithium hypochlorite is typically a white or slightly yellowish crystalline solid at room temperature. It is highly soluble in water, forming alkaline solutions that release available chlorine. The compound is hygroscopic, meaning it readily absorbs moisture from the air. It has a characteristic chlorine-like odor, particularly when in contact with moisture or acids. The compound is thermally unstable and can decompose when heated or exposed to acidic conditions.

What is lithium hypochlorite used for?

Lithium hypochlorite is primarily used as a disinfectant and bleaching agent in industrial applications. It serves as an effective sanitizer in water treatment processes and swimming pool maintenance systems. The compound is also utilized in textile bleaching operations and as an oxidizing agent in various chemical synthesis processes. Additionally, it finds application in cleaning formulations where controlled chlorine release is required for antimicrobial activity.

How to handle lithium hypochlorite safely?

Lithium hypochlorite requires careful handling using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas to avoid inhalation of chlorine vapors. Avoid contact with acids, organic materials, and reducing agents as these can cause dangerous reactions. Use non-metallic tools and containers to prevent corrosion. Ensure emergency eyewash stations and safety showers are readily accessible when handling this oxidizing compound.

How to store lithium hypochlorite correctly?

Lithium hypochlorite must be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed and use corrosion-resistant materials for storage. Store separately from acids, organic materials, flammable substances, and reducing agents to prevent incompatible reactions. Maintain storage temperatures below 25°C to minimize decomposition. Regularly inspect containers for signs of deterioration and ensure proper labeling according to local regulations.

What to do in case of contact with lithium hypochlorite?

Lithium hypochlorite contact requires immediate action depending on exposure route. For skin contact, remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific first aid measures.

How to dispose of lithium hypochlorite appropriately?

Lithium hypochlorite disposal must comply with local and national waste regulations as it is classified as hazardous waste. Small quantities can be neutralized carefully with reducing agents under controlled conditions before disposal. Never mix with acids or organic waste streams. Contact licensed hazardous waste disposal companies for proper handling and treatment. Empty containers should be triple-rinsed and disposed of according to local packaging waste regulations. Always consult local environmental authorities for specific disposal requirements.

How to transport lithium hypochlorite?

Lithium hypochlorite is classified under ADR Class 5.1 (Oxidizing Substances), Packing Group II, indicating it presents moderate oxidizing hazards during transport. Use appropriate UN-specification packaging designed for oxidizing materials. Vehicles must carry proper placarding and documentation. Drivers require ADR training for Class 5.1 substances. Ensure packages are properly labeled, marked, and secured to prevent damage during transit. Avoid transport with incompatible materials such as flammable substances or acids.

Is lithium hypochlorite subject to particular regulations?

Lithium hypochlorite is subject to various chemical regulations including REACH registration requirements in Europe. It must be classified and labeled according to CLP regulation, though specific harmonized classification may not be established. The compound is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational health and safety regulations, environmental discharge limits, and proper waste disposal requirements. Always consult current regulatory databases for the most up-to-date compliance information.

Where to buy lithium hypochlorite in Europe?

Lithium hypochlorite is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides this oxidizing compound to qualified industrial users with proper technical documentation and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality and proper handling throughout the supply chain. Contact OYSI directly for availability, specifications, and delivery options tailored to your industrial requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.