Calcium

Ca

calcium

CAS7440-70-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
Danger

Consulting for Calcium

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Identification

CAS Number
7440-70-2
EC Number
231-179-5
UN Number
1401
Index Number
020-001-00-X
PubChem CID
5460341

Physical-chemical properties

Molecular Formula
Ca
Molar Mass
40.08 g/mol
IUPAC Name
calcium

Chemical Identifiers

InChI
InChI=1S/Ca
InChI Key
OYPRJOBELJOOCE-UHFFFAOYSA-N

Overview

Calcium (CAS 7440-70-2) is an alkaline earth metal with high reactivity toward water and strong reducing properties. As the fifth most abundant element in Earth's crust, calcium plays a fundamental role in numerous industrial processes and technical applications. This silvery-white metallic element belongs to Group 2 of the periodic table and exhibits characteristic properties of alkaline earth metals, including high chemical reactivity and the tendency to form ionic compounds readily. The metal's most notable safety characteristic is its vigorous reaction with water, producing calcium hydroxide and hydrogen gas, which poses significant fire and explosion hazards. This water-reactive behavior classifies calcium as a Class 4.3 dangerous good under ADR regulations, requiring specialized handling and storage procedures. The substance carries the GHS02 pictogram indicating flammability risks and requires a "Danger" signal word on safety labels. Calcium's strong reducing properties make it particularly valuable in metallurgical applications, where it serves as a deoxidizing agent in steel production and as a reducing agent for extracting other metals from their compounds. The chemical industry utilizes calcium in the synthesis of calcium compounds and as a getter material in vacuum tubes to remove trace gases. Additionally, calcium finds application in the production of calcium-lead alloys for battery grids and specialized applications requiring controlled reactivity. In industrial chemistry, calcium shares certain applications with related compounds such as trimagnesium bis(phosphorus(3-)) and tricalcium bis(phosphorus(3-)), particularly in metallurgical processes where alkaline earth metals provide essential reducing or alloying properties. OYSI supplies technical-grade calcium to European industrial customers, ensuring compliance with safety regulations and providing comprehensive technical support for specialized applications.

Safety & Classification

Danger
Classification:

Water-react. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H261

In contact with water releases flammable gases.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1401
ADR Class4.3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameCalcium, nicht pyrophor
Marine PollutantNo

Frequently Asked Questions

What is calcium?

Calcium is a metallic chemical element with the symbol Ca and atomic number 20, classified as an alkaline earth metal. It has a molecular weight of 40.08 g/mol and CAS number 7440-70-2. Calcium is highly reactive, particularly with water, which classifies it as Water-react. 2 under GHS classification. In its pure metallic form, calcium appears as a silvery-white metal that tarnishes rapidly when exposed to air and moisture.

What are the physicochemical properties of calcium?

Calcium is a soft, silvery-white metallic solid at room temperature with a relatively low density of 1.55 g/cm³. It has a melting point of 842°C and boiling point of 1484°C. Calcium reacts vigorously with water to produce calcium hydroxide and hydrogen gas, making it highly water-reactive. It also oxidizes rapidly in air, forming a white oxide layer. The metal is relatively soft and can be cut with a knife.

What is calcium used for?

Calcium serves as a reducing agent in the extraction of metals like thorium, uranium, and zirconium from their oxides. It is used in the production of calcium-lead alloys for battery grids and as a deoxidizer in steel manufacturing. Calcium also finds applications in the production of calcium hydride, which serves as a portable hydrogen source, and in specialized metallurgical processes where its strong reducing properties are valuable.

How to handle calcium safely?

Calcium must be handled with extreme caution due to its water-reactive nature and flammability risk (GHS02 pictogram). Always wear appropriate personal protective equipment including safety goggles, gloves, and protective clothing. Work in a dry, well-ventilated area away from water and moisture. Use inert gas atmosphere when possible and have dry sand or specialized extinguishing agents available for fire suppression. Never use water to extinguish calcium fires.

How to store calcium correctly?

Calcium must be stored in airtight containers under inert gas (nitrogen or argon) to prevent contact with moisture and oxygen. Store in a cool, dry location away from water sources, acids, and oxidizing agents. Use specialized storage facilities designed for water-reactive materials. Containers should be clearly labeled and stored in areas with restricted access. Regular inspection of storage containers is essential to ensure integrity and prevent moisture ingress.

What to do in case of contact with calcium?

Calcium exposure requires immediate action due to its reactive nature. For skin contact, remove contaminated clothing and brush off any solid particles before flushing with large amounts of water. For eye contact, rinse immediately with water for at least 15 minutes. If inhaled, move to fresh air immediately. In case of fire involving calcium, do not use water - use dry sand or specialized extinguishing agents. Seek medical attention for all exposures.

How to dispose of calcium properly?

Calcium disposal must follow strict hazardous waste regulations due to its water-reactive classification. Small quantities can be carefully neutralized by controlled reaction with dry sand or inert materials under expert supervision. Larger quantities require specialized hazardous waste disposal services. Never dispose of calcium in regular waste streams or down drains. Contact licensed waste disposal companies familiar with water-reactive materials and follow local environmental regulations for proper disposal documentation.

How to transport calcium?

Calcium is classified as ADR Class 4.3 (water-reactive substances) Packing Group II, requiring specialized transportation procedures. It must be packaged in UN-approved containers that prevent moisture ingress and are clearly labeled with appropriate hazard markings. Transport vehicles must carry emergency equipment and documentation. Only certified carriers experienced in handling water-reactive materials should transport calcium, following strict ADR regulations for dangerous goods transport.

Is calcium subject to specific regulations?

Calcium is subject to various European regulations including CLP (Classification, Labelling and Packaging) requirements due to its water-reactive nature and flammability. It falls under REACH registration requirements for chemical substances. Transport is governed by ADR regulations for dangerous goods Class 4.3. Workplace exposure is regulated under occupational safety directives. However, calcium is not currently listed as a Substance of Very High Concern (SVHC) under REACH.

Where to buy calcium in Europe?

Calcium is available through OYSI, a European distributor specializing in technical chemicals and hazardous materials. As an experienced supplier, OYSI can provide calcium with proper documentation, safety data sheets, and compliance with European regulations. Their expertise in handling water-reactive substances ensures safe packaging and delivery. Contact OYSI directly for availability, technical specifications, and pricing information tailored to your specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.