Magnesium peroxide

MgO2

magnesium peroxide

CAS14452-57-4

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Identification

CAS Number
14452-57-4
EC Number
238-438-1
UN Number
1476
PubChem CID
61745

Physical-chemical properties

Molecular Formula
MgO2
Molar Mass
56.30 g/mol
IUPAC Name
magnesium peroxide

Chemical Identifiers

InChI
InChI=1S/Mg.O2/c;1-2/q+2;-2
InChI Key
SPAGIJMPHSUYSE-UHFFFAOYSA-N

Overview

Magnesium peroxide (CAS 14452-57-4) is an inorganic oxidizing compound with notable oxygen-releasing properties and thermal stability characteristics. This white crystalline powder represents an important member of the alkaline earth metal peroxides family, distinguished by its controlled oxidizing capabilities and relatively stable nature under standard storage conditions. Unlike more reactive peroxides, magnesium peroxide offers a balanced approach to oxidation applications where controlled oxygen release is essential. The compound's molecular structure features magnesium in its +2 oxidation state bonded to a peroxide anion, resulting in the characteristic MgO2 formula with a molecular weight of 56.304 g/mol. From a safety perspective, magnesium peroxide is classified under ADR class 5.1 as an oxidizing substance, requiring appropriate handling protocols to prevent contact with combustible materials. While it does not carry specific GHS pictograms or signal words, proper storage away from reducing agents and organic compounds remains essential. The compound demonstrates good thermal stability compared to other peroxides, decomposing gradually to release oxygen when heated, making it suitable for controlled oxidation processes. Industrial applications of magnesium peroxide span several sectors, including its use as an oxygen source in soil remediation projects where controlled oxidation helps break down organic contaminants. The compound also finds application in the food industry as a flour treatment agent, where it serves as a dough conditioner and bleaching agent. Additionally, it functions effectively in water treatment processes, similar to applications where barium(2+) dinitrate or calcium;dichlorate;dihydrate might be considered for oxidation purposes. OYSI maintains reliable supply chains for magnesium peroxide, ensuring consistent availability for European industrial customers requiring this specialized oxidizing compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1476
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameMagnesiumperoxid
Marine PollutantNo

Frequently Asked Questions

What is magnesium peroxide?

Magnesium peroxide is an inorganic chemical compound with the formula MgO2 and CAS number 14452-57-4. It has a molecular weight of 56.304 g/mol and serves as an oxidizing agent in various industrial applications. This white crystalline solid releases oxygen when it decomposes, making it valuable in applications requiring controlled oxygen release or bleaching properties.

What are the physicochemical properties of magnesium peroxide?

Magnesium peroxide is a white to off-white crystalline powder that is odorless and stable under normal conditions. It is sparingly soluble in water but decomposes slowly in aqueous solutions to release oxygen and form magnesium hydroxide. The compound is thermally stable but decomposes at elevated temperatures, releasing oxygen gas and forming magnesium oxide.

What is magnesium peroxide used for?

Magnesium peroxide is used as an oxidizing agent in various industrial applications including bleaching processes, environmental remediation, and as an oxygen source in soil conditioning. It finds application in textile processing, paper manufacturing, and water treatment systems. The compound is also utilized in agricultural applications for soil aeration and in some specialized chemical syntheses requiring controlled oxygen release.

How to handle magnesium peroxide safely?

Magnesium peroxide should be handled with standard laboratory safety equipment including safety glasses, gloves, and protective clothing. Work in well-ventilated areas to prevent dust accumulation and avoid contact with incompatible materials such as reducing agents and organic materials. Use appropriate dust control measures and ensure personnel are trained in handling oxidizing substances to prevent fire or explosion hazards.

How to store magnesium peroxide correctly?

Magnesium peroxide should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly sealed and store separately from reducing agents, combustible materials, and organic substances. The storage area should be designed for oxidizing materials and equipped with appropriate fire suppression systems. Regular inspection of storage containers is recommended.

What to do in case of contact with magnesium peroxide?

In case of skin contact with magnesium peroxide, immediately remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes. For eye contact, flush immediately with water for 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if respiratory irritation occurs. In case of ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of magnesium peroxide appropriately?

Magnesium peroxide disposal must comply with local and national waste regulations as it is classified as an oxidizing substance. Contact licensed waste disposal companies experienced in handling oxidizing materials. Small quantities may be neutralized by careful dissolution in water under controlled conditions, but this should only be done by trained personnel. Never dispose of in regular waste streams or mix with organic materials.

How to transport magnesium peroxide?

Magnesium peroxide is classified under ADR as Class 5.1 (Oxidizing substances) Packing Group II, requiring specific packaging and labeling requirements for transport. Use UN-approved packaging suitable for oxidizing substances and ensure proper documentation including transport documents and emergency response information. Vehicles must be equipped according to ADR regulations and drivers must hold appropriate dangerous goods certificates.

Is magnesium peroxide subject to specific regulations?

Magnesium peroxide is regulated under various chemical safety frameworks including REACH registration requirements in Europe and CLP classification for oxidizing properties. It is not listed as a Substance of Very High Concern (SVHC) under REACH. Transport is regulated under ADR/RID/ADN as a Class 5.1 oxidizing substance, and workplace exposure limits may apply depending on national regulations.

Where to buy magnesium peroxide in Europe?

Magnesium peroxide is available through OYSI, a European distributor of technical chemicals serving various industries across Europe. OYSI provides high-quality magnesium peroxide with proper documentation including safety data sheets and certificates of analysis. As a specialized chemical distributor, OYSI ensures compliance with European regulations and provides technical support for industrial applications requiring this oxidizing agent.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.