Lithium

Li

lithium

CAS7439-93-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7439-93-2
EC Number
231-102-5
UN Number
1415
Index Number
003-001-00-4
PubChem CID
3028194

Physical-chemical properties

Molecular Formula
Li
Molar Mass
7.00 g/mol
IUPAC Name
lithium

Chemical Identifiers

InChI
InChI=1S/Li
InChI Key
WHXSMMKQMYFTQS-UHFFFAOYSA-N

Overview

Lithium (CAS 7439-93-2) is an alkali metal with exceptional reactivity and the lowest density of all metals. As the lightest metal in the periodic table, lithium represents a critical element in modern industrial applications, particularly in energy storage and specialized chemical processes. This silvery-white alkali metal belongs to Group 1 of the periodic table, sharing chemical characteristics with sodium and potassium, though it exhibits unique properties that distinguish it from its heavier counterparts. With a molecular weight of just 7 g/mol, lithium demonstrates remarkable reactivity, especially with water, earning it the Water-react. 1 classification under GHS standards. The metal's exceptional electrochemical properties make it indispensable in lithium-ion battery manufacturing, where its high electrochemical potential and low atomic weight contribute to superior energy density. Lithium's reactivity with moisture and oxygen requires careful handling protocols, as indicated by its Skin Corr. 1B classification and corresponding GHS02 and GHS05 pictograms. Storage and transportation fall under ADR Class 4.3, reflecting its water-reactive nature that can generate flammable hydrogen gas. Industrial applications primarily focus on battery production for electric vehicles and energy storage systems, where lithium compounds serve as essential cathode and electrolyte components. The pharmaceutical industry utilizes lithium salts in specialized therapeutic applications, while the ceramics and glass industries employ lithium compounds as flux agents to reduce melting temperatures and improve thermal shock resistance. OYSI maintains reliable supply chains for lithium and related alkali metals, ensuring consistent availability for European industrial customers requiring high-quality reactive metals for specialized applications.

Safety & Classification

Danger
Classification:

Water-react. 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H260

In contact with water releases flammable gases which may ignite spontaneously.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1415
ADR Class4.3
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameLithium, nicht pyrophor
Marine PollutantNo

Frequently Asked Questions

What is lithium?

Lithium is a soft, silvery-white alkali metal with the chemical symbol Li and CAS number 7439-93-2. It is the lightest metal in the periodic table with a molecular weight of 7 g/mol. This highly reactive element belongs to Group 1 of the periodic table and exhibits strong water-reactive properties, making it a dangerous substance requiring careful handling and storage protocols.

What are the physicochemical properties of lithium?

Lithium is a soft, silvery-white metal that can be cut with a knife at room temperature. It has the lowest density of all metals (0.534 g/cm³) and floats on water while reacting vigorously with it. The metal tarnishes quickly in air, forming a dull coating, and is highly reactive with moisture and oxygen, requiring storage under inert conditions.

What is lithium used for?

Lithium is primarily used in rechargeable lithium-ion batteries for electronics, electric vehicles, and energy storage systems. It serves as an important component in ceramics, glass manufacturing, and aluminum production. Additionally, lithium compounds are utilized in pharmaceuticals, lubricating greases, and as a flux in metallurgy and welding applications.

How to handle lithium safely?

Lithium requires strict safety protocols due to its water-reactive and corrosive properties. Personnel must wear protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Handle only in dry, inert atmosphere conditions, keep away from water and moisture sources, and ensure adequate ventilation. Emergency shower and eyewash stations should be readily accessible.

How to store lithium correctly?

Lithium must be stored under inert gas (argon or nitrogen) or mineral oil to prevent reaction with air and moisture. Use airtight, corrosion-resistant containers in a cool, dry, well-ventilated area away from water sources. Keep separated from oxidizing agents, acids, and halogenated compounds. Storage areas should be equipped with appropriate fire suppression systems.

What to do in case of contact with lithium?

Lithium contact requires immediate emergency response due to its corrosive nature. For skin contact, brush off any solid particles gently without using water, then flush with large amounts of water. For eye contact, rinse immediately with water for at least 15 minutes. If ingested, do not induce vomiting and seek immediate medical attention. Remove contaminated clothing carefully.

How to dispose of lithium appropriately?

Lithium disposal must comply with local and European waste regulations as hazardous waste. Small quantities can be neutralized by careful reaction with alcohol under controlled conditions, followed by proper disposal of resulting compounds. Larger quantities require specialized hazardous waste disposal services. Never dispose of lithium in regular waste streams or pour down drains.

How to transport lithium?

Lithium is classified under ADR Class 4.3 (water-reactive substances), Packing Group I, indicating high danger level. Transportation requires UN-approved packaging, proper labeling with GHS02 and GHS05 pictograms, and 'Danger' signal word. Vehicles must carry appropriate emergency equipment and drivers need specialized training for hazardous materials transport.

Is lithium subject to particular regulations?

Lithium is regulated under European CLP Regulation as Water-react. 1 and Skin Corr. 1B, requiring specific labeling and safety data sheets. It falls under REACH registration requirements for commercial use. The substance is not classified as SVHC (Substance of Very High Concern), but strict handling, storage, and transport regulations apply due to its hazardous properties.

Where to buy lithium in Europe?

Lithium is available through OYSI, a European distributor of technical chemicals, ensuring reliable supply across European markets. As a specialized chemical distributor, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for lithium purchases. Professional customers can contact OYSI for availability, technical specifications, and delivery throughout Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.