Ethyl formate

C3H6O2

ethyl formate

CAS109-94-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
109-94-4
EC Number
203-721-0
UN Number
1190
Index Number
607-015-00-7
PubChem CID
8025

Physical-chemical properties

Molecular Formula
C3H6O2
Molar Mass
74.08 g/mol
IUPAC Name
ethyl formate

Chemical Identifiers

InChI
InChI=1S/C3H6O2/c1-2-5-3-4/h3H,2H2,1H3
InChI Key
WBJINCZRORDGAQ-UHFFFAOYSA-N

Overview

Ethyl formate (CAS 109-94-4) is a volatile organic ester compound with characteristic fruity odor and high flammability properties. This colorless liquid represents one of the simplest formate esters, formed through the combination of formic acid and ethanol. With its molecular formula C3H6O2 and molecular weight of 74.08 g/mol, ethyl formate exhibits typical ester characteristics while maintaining unique properties that make it valuable across various industrial applications. The compound's distinctive sweet, rum-like aroma has made it particularly sought after in flavor and fragrance formulations. From a safety perspective, ethyl formate requires careful handling due to its classification as a Category 2 flammable liquid with ADR Class 3 transportation requirements. The substance presents moderate acute toxicity risks and can cause serious eye irritation, necessitating appropriate personal protective equipment during handling. Its high volatility contributes to potential respiratory exposure risks, requiring adequate ventilation systems in workplace environments. The GHS02 and GHS07 pictograms with "Danger" signal word reflect these significant hazard considerations. Industrial applications of ethyl formate span multiple sectors, including its use as a solvent in coating formulations, as an intermediate in pharmaceutical synthesis, and as a flavoring agent in food processing. The compound shares certain application areas with related esters, though it offers distinct advantages over compounds like ethylbenzene in specific formulations requiring lower toxicity profiles. Its rapid evaporation rate and excellent solvency properties make it particularly valuable in specialty chemical processes. OYSI maintains reliable supply chains for ethyl formate, ensuring consistent availability for European industrial customers requiring this versatile ester compound.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1190
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEthylformiat
Marine PollutantNo

Frequently Asked Questions

What is ethyl formate?

Ethyl formate is an organic chemical compound with the molecular formula C3H6O2 and CAS number 109-94-4. It belongs to the ester family and has a molecular weight of 74.08 g/mol. This flammable liquid is characterized by its fruity, rum-like odor and is commonly used as a flavoring agent and solvent. Ethyl formate is classified as a hazardous substance with multiple safety classifications including flammable liquid category 2 and acute toxicity category 4.

What are the physicochemical properties of ethyl formate?

Ethyl formate is a colorless, volatile liquid with a characteristic pleasant, fruity odor reminiscent of rum or peach. It has a relatively low boiling point of approximately 54°C and is miscible with most organic solvents. The compound is slightly soluble in water and has a density lower than water. Its volatile nature makes it evaporate readily at room temperature, contributing to its strong odor and flammability characteristics.

What is ethyl formate used for?

Ethyl formate is primarily used as a flavoring agent in the food and beverage industry, providing fruity notes to various products. It serves as an effective solvent in pharmaceutical formulations, coatings, and adhesives. The compound is also utilized in pesticide formulations as both an active ingredient and carrier solvent. Additionally, it finds applications in the production of synthetic leather, plastics, and as an intermediate in organic synthesis processes.

How to handle ethyl formate safely?

Ethyl formate requires careful handling due to its flammability and toxicity. Personal protective equipment must include safety goggles, chemical-resistant gloves, and appropriate clothing to prevent skin contact. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation. Keep away from ignition sources, heat, and sparks. Ground all equipment to prevent static electricity buildup. Avoid contact with eyes and skin, and prevent vapor accumulation in confined spaces.

How to store ethyl formate correctly?

Ethyl formate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use appropriate containers made of compatible materials and keep tightly closed when not in use. Storage temperature should be maintained below 25°C to minimize vapor pressure. Keep away from oxidizing agents and incompatible materials. Store in areas equipped with appropriate fire suppression systems and ensure proper grounding of storage containers to prevent static buildup.

What to do in case of contact with ethyl formate?

Ethyl formate exposure requires immediate action depending on the contact route. For skin contact, immediately remove contaminated clothing and wash affected area with soap and water for at least 15 minutes. In case of eye contact, flush immediately with water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately and seek medical help if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of ethyl formate properly?

Ethyl formate disposal must comply with local, national, and international waste regulations. The substance cannot be disposed of in regular waste streams due to its hazardous classification. Contact licensed waste disposal companies specialized in hazardous chemical waste management. Small quantities may be allowed for controlled incineration in approved facilities. Always consult local environmental authorities for specific disposal requirements and ensure proper documentation of waste disposal activities.

How to transport ethyl formate?

Ethyl formate is classified as ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations compliance. Vehicles must be equipped with appropriate safety equipment and drivers must hold ADR certification. Use UN-approved packaging and labeling with proper shipping documents. Transport vehicles should be grounded and equipped with fire extinguishers. Avoid transport during extreme temperatures and ensure proper ventilation. Follow all applicable dangerous goods transport regulations for road, rail, air, and sea transport.

Is ethyl formate subject to specific regulations?

Ethyl formate is regulated under various European and international frameworks. Under REACH regulation, it requires registration for import/manufacture above certain tonnages. The CLP regulation mandates specific classification and labeling requirements with GHS02 and GHS07 pictograms and 'Danger' signal word. It is not currently listed as an SVHC substance. Workplace exposure limits may apply under occupational health regulations. Food-grade applications must comply with food additive regulations.

Where to buy ethyl formate in Europe?

Ethyl formate is available through OYSI, a specialized European distributor of technical chemicals serving various industries across Europe. OYSI provides high-quality ethyl formate with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical supplier, OYSI ensures proper handling, storage, and transport of hazardous materials according to European regulations. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.