Ethylbenzene

C8H10

ethylbenzene

CAS100-41-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
100-41-4
EC Number
202-849-4
UN Number
1175
Index Number
601-023-00-4
PubChem CID
7500

Physical-chemical properties

Molecular Formula
C8H10
Molar Mass
106.16 g/mol
IUPAC Name
ethylbenzene

Chemical Identifiers

InChI
InChI=1S/C8H10/c1-2-8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChI Key
YNQLUTRBYVCPMQ-UHFFFAOYSA-N

Overview

Ethylbenzene (CAS 100-41-4) is an aromatic hydrocarbon compound characterized by high flammability and significant toxicological properties requiring careful handling protocols. This colorless liquid organic compound consists of a benzene ring with an ethyl group substituent, making it a fundamental building block in petrochemical manufacturing processes. Ethylbenzene exhibits typical aromatic characteristics with a distinctive sweet, gasoline-like odor and demonstrates significant industrial importance as both an intermediate chemical and solvent application. The compound presents notable safety considerations due to its classification as a flammable liquid category 2 and aspiration toxicity category 1, requiring implementation of strict fire prevention measures and respiratory protection protocols. Its vapor can form explosive mixtures with air, necessitating proper ventilation systems and elimination of ignition sources during handling and storage operations. The substance also shows potential for repeated dose toxicity, particularly affecting target organs through prolonged exposure scenarios. Ethylbenzene serves primarily as a precursor in styrene production, which represents approximately 99% of its commercial consumption globally. The dehydrogenation process converts ethylbenzene to styrene, an essential monomer for polystyrene plastics, synthetic rubber, and various polymer applications. Secondary industrial applications include its use as a solvent in paint formulations, adhesives, and coating systems where its aromatic properties provide excellent dissolving characteristics for resins and other organic compounds. Within the broader aromatic hydrocarbon family, ethylbenzene shares structural similarities with propylbenzene, though each compound exhibits distinct physical properties and industrial applications suited to specific manufacturing requirements. OYSI maintains reliable European supply chains for ethylbenzene, ensuring consistent availability for industrial customers requiring this essential aromatic intermediate.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 4 *; Asp. Tox. 1; STOT RE 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H332

Harmful if inhaled.

H304

May be fatal if swallowed and enters airways.

H373

May cause damage to organs through prolonged or repeated exposure.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1175
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEthylbenzen
Marine PollutantNo

Frequently Asked Questions

What is ethylbenzene?

Ethylbenzene is an aromatic hydrocarbon compound with the molecular formula C8H10 and CAS number 100-41-4. It consists of a benzene ring with an ethyl group attached, forming a colorless liquid with a molecular weight of 106.16 g/mol. This chemical is classified as a flammable liquid and poses several health hazards including acute toxicity and aspiration toxicity. It is widely used in industrial applications as a chemical intermediate and solvent.

What are the physicochemical properties of ethylbenzene?

Ethylbenzene is a colorless liquid at room temperature with a sweet, gasoline-like odor. It has limited solubility in water but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound has a boiling point of approximately 136°C and a melting point of -95°C. Its density is lower than water at about 0.87 g/cm³, and it exhibits typical aromatic compound characteristics with high chemical stability under normal conditions.

What is ethylbenzene used for?

Ethylbenzene is primarily used as a chemical intermediate in the production of styrene, which is essential for manufacturing polystyrene plastics and synthetic rubber. It serves as a solvent in various industrial processes including paint thinners, varnishes, and inks. Additionally, ethylbenzene is used in the production of diethylbenzene and acetophenone. The compound also finds applications in the petroleum industry as a component in gasoline and as a solvent for aluminum chloride in Friedel-Crafts reactions.

How to handle ethylbenzene safely?

Ethylbenzene requires careful handling due to its flammable nature and health hazards. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. Work should be conducted in well-ventilated spaces away from ignition sources, sparks, and open flames. Emergency eyewash stations and safety showers should be readily available. Due to its acute toxicity and aspiration hazard classification, avoid inhalation and skin contact at all times.

How to store ethylbenzene correctly?

Ethylbenzene must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames due to its Flam. Liq. 2 classification. Use only approved containers and ensure proper grounding to prevent static electricity buildup. Store away from strong oxidizing agents and incompatible materials. Maintain temperatures below 25°C when possible and ensure storage areas have appropriate fire suppression systems. Regular inspection of containers for leaks or damage is essential for safe storage.

What to do in case of contact with ethylbenzene?

Ethylbenzene exposure requires immediate action due to its acute toxicity. For skin contact, remove contaminated clothing and rinse affected areas with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. For ingestion, do NOT induce vomiting due to aspiration hazard - seek immediate medical attention and provide supportive care.

How to dispose of ethylbenzene appropriately?

Ethylbenzene disposal must comply with local and national hazardous waste regulations due to its classification as dangerous goods. The substance cannot be disposed of in regular waste streams or sewage systems. Approved methods include incineration at licensed hazardous waste facilities or recovery/recycling through authorized chemical waste management companies. Small quantities should be collected in appropriate containers and labeled for hazardous waste pickup. Always consult local environmental authorities for specific disposal requirements and authorized waste management facilities.

How to transport ethylbenzene?

Ethylbenzene is classified under ADR Class 3 (Flammable Liquids), Packing Group II, requiring specific transport protocols. Packages must bear proper hazard labels including GHS02, GHS07, and GHS08 pictograms with 'Danger' signal word. Transport vehicles need appropriate placarding and drivers require ADR certification. Use UN-approved packaging designed for flammable liquids and ensure proper documentation including transport emergency cards. Vehicle equipment must include fire extinguishers and emergency response materials suitable for flammable liquid incidents.

Is ethylbenzene subject to specific regulations?

Ethylbenzene is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification as Flam. Liq. 2; Acute Tox. 4; Asp. Tox. 1; STOT RE 2. While not currently listed as a Substance of Very High Concern (SVHC), it requires safety data sheets and appropriate hazard communication. Industrial users must comply with workplace exposure limits and occupational health regulations. Transport falls under ADR dangerous goods requirements, and disposal must follow hazardous waste legislation across EU member states.

Where to buy ethylbenzene in Europe?

Ethylbenzene is available through OYSI, a leading European distributor of industrial chemicals serving customers across the continent. OYSI provides reliable supply chains for laboratory and industrial quantities with proper documentation including safety data sheets and certificates of analysis. As a specialized chemical distributor, OYSI ensures compliance with European regulations including REACH and CLP requirements. Contact OYSI directly for availability, specifications, and delivery options to your location within Europe for professional and industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.