3-chloroprop-1-ene
C3H5Cl
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Identification
- CAS Number
- 107-05-1
- EC Number
- 203-457-6
- UN Number
- 1100
- Index Number
- 602-029-00-X
- PubChem CID
- 7850
Physical-chemical properties
- Molecular Formula
- C3H5Cl
- Molar Mass
- 76.52 g/mol
- IUPAC Name
- 3-chloroprop-1-ene
Chemical Identifiers
- InChI
- InChI=1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
- InChI Key
- OSDWBNJEKMUWAV-UHFFFAOYSA-N
Overview
3-chloroprop-1-ene (CAS 107-05-1) is an organochlorine compound with high reactivity and significant industrial utility in chemical synthesis applications. This volatile organic compound, also known as allyl chloride, represents a crucial building block in the chemical industry due to its unique structural properties combining an alkene double bond with a chlorine substituent. With the molecular formula C3H5Cl and a molecular weight of 76.52 g/mol, 3-chloroprop-1-ene exhibits characteristics typical of both halogenated hydrocarbons and unsaturated compounds. The presence of both reactive functional groups makes it particularly valuable for various synthetic pathways and industrial processes. The compound presents significant safety considerations, classified under multiple hazard categories including flammable liquid (Category 2), carcinogenic potential (Category 2), and mutagenic properties (Category 2). Its classification under ADR Class 3 reflects its flammable nature, requiring specialized handling and storage protocols. The GHS pictograms (GHS02, GHS08, GHS07, GHS09) indicate fire hazard, health hazard, harmful effects, and environmental concerns respectively, emphasizing the need for comprehensive safety measures during handling and transport. Primary industrial applications include its use as an intermediate in the production of epichlorohydrin, synthetic glycerin, and various pharmaceutical compounds. The chemical industry also utilizes 3-chloroprop-1-ene in manufacturing specialty polymers and as a starting material for producing other chlorinated derivatives. Unlike simpler hydrocarbons such as propylbenzene, this compound's dual functionality enables more complex synthetic transformations. OYSI provides reliable access to 3-chloroprop-1-ene for qualified industrial customers across Europe, ensuring compliance with all relevant safety and regulatory requirements.
Safety & Classification
Flam. Liq. 2; Carc. 2; Muta. 2; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; STOT R...
GHS Pictograms
Flame
GHS02
Flammable. May ignite on contact with air, water, or heat sources.
Health Hazard
GHS08
Serious health hazard. May cause cancer, organ damage, or genetic defects.
Exclamation Mark
GHS07
Harmful. May cause irritation, allergic reactions, or drowsiness.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Highly flammable liquid and vapour.
Suspected of causing cancer.
Suspected of causing genetic defects.
Harmful if inhaled.
Harmful in contact with skin.
Harmful if swallowed.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.
Causes serious eye irritation.
Very toxic to aquatic life.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1100 |
| ADR Class | 3 |
| Packing Group | I |
| Tunnel Code | C/E |
| Proper Shipping Name | Allylchlorid |
| Marine Pollutant | No |
Frequently Asked Questions
What is 3-chloroprop-1-ene?
3-chloroprop-1-ene is an organochlorine compound with the molecular formula C3H5Cl and CAS number 107-05-1. This chemical substance has a molecular weight of 76.52 g/mol and belongs to the allyl chloride family. It is classified as a highly hazardous chemical with multiple danger classifications including flammable liquid, carcinogenic, and mutagenic properties, requiring careful handling and specialized safety measures in industrial applications.
What are the physicochemical properties of 3-chloroprop-1-ene?
3-chloroprop-1-ene is a colorless liquid at room temperature with a characteristic pungent odor. It has a low boiling point and high volatility, making it highly flammable. The compound is slightly soluble in water but readily miscible with organic solvents. Its molecular structure contains a vinyl group attached to a chloromethyl group, giving it reactive properties typical of both alkenes and alkyl halides.
What is 3-chloroprop-1-ene used for?
3-chloroprop-1-ene serves primarily as an intermediate in organic synthesis and chemical manufacturing. It is used in the production of epichlorohydrin, glycerol, and various pharmaceutical intermediates. The compound also finds application in the synthesis of specialty chemicals, resins, and as a building block for agrochemical products. Due to its high reactivity and hazardous nature, its use is typically restricted to professional industrial settings with appropriate safety controls.
How to handle 3-chloroprop-1-ene safely?
3-chloroprop-1-ene requires strict safety protocols including use of full chemical-resistant protective equipment, respiratory protection, and eye protection. Work must be conducted in well-ventilated areas or under fume hoods due to its toxic vapors. Avoid all ignition sources as it is highly flammable (Class 3 ADR, Group I). Personnel handling this substance should be trained in emergency procedures and have immediate access to safety showers and eyewash stations.
How to store 3-chloroprop-1-ene correctly?
3-chloroprop-1-ene must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use only approved containers made of compatible materials, typically stainless steel or specially lined vessels. Store separately from oxidizing agents, acids, and bases to prevent dangerous reactions. The storage area should be equipped with appropriate fire suppression systems and spill containment measures due to its flammable and toxic nature.
What to do in case of contact with 3-chloroprop-1-ene?
Immediate action is required for any contact with 3-chloroprop-1-ene. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always contact emergency services and provide the safety data sheet to medical personnel.
How to dispose of 3-chloroprop-1-ene appropriately?
3-chloroprop-1-ene disposal must comply with local and international hazardous waste regulations. The substance cannot be disposed of in regular waste streams due to its carcinogenic and mutagenic properties. Professional hazardous waste disposal companies should handle the elimination process, typically through high-temperature incineration in specialized facilities. All containers must be properly labeled and documented according to waste tracking requirements. Never attempt to neutralize or treat this substance without professional expertise.
How to transport 3-chloroprop-1-ene?
3-chloroprop-1-ene is classified under ADR Class 3 (flammable liquids), Packing Group I, indicating the highest level of danger for transport. Transportation requires specialized vehicles equipped for hazardous materials, proper placarding, and certified drivers with hazmat training. Packages must meet strict UN specification standards and be properly labeled with GHS pictogrammes (GHS02, GHS08, GHS07, GHS09). All transport documentation must include emergency response information and 24-hour emergency contact numbers.
Is 3-chloroprop-1-ene subject to specific regulations?
3-chloroprop-1-ene is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification obligations. The substance carries multiple hazard classifications (Flam. Liq. 2, Carc. 2, Muta. 2, Acute Tox. 4) requiring detailed safety data sheets and risk assessments. While not currently listed as SVHC, its carcinogenic and mutagenic properties make it subject to strict occupational exposure limits and potential future regulatory restrictions.
Where to buy 3-chloroprop-1-ene in Europe?
3-chloroprop-1-ene is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous substances. OYSI provides comprehensive documentation including safety data sheets, certificates of analysis, and regulatory compliance information. As a professional chemical distributor, OYSI ensures proper packaging, labeling, and transportation of this highly regulated substance while supporting customers with technical expertise and regulatory guidance for safe handling and use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.