Styrene

C8H8

styrene

CAS100-42-5
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
100-42-5
EC Number
202-851-5
UN Number
2055
Index Number
601-026-00-0
PubChem CID
7501

Physical-chemical properties

Molecular Formula
C8H8
Molar Mass
104.15 g/mol
IUPAC Name
styrene

Chemical Identifiers

InChI
InChI=1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
InChI Key
PPBRXRYQALVLMV-UHFFFAOYSA-N

Overview

Styrene (CAS 100-42-5) is an aromatic vinyl monomer with high reactivity and distinct sweet odor characteristics. Styrene represents one of the most important industrial monomers in modern chemical manufacturing, serving as a fundamental building block for numerous polymer applications. This colorless to pale yellow liquid belongs to the vinyl aromatic compound family and exhibits exceptional polymerization capabilities that make it indispensable across multiple industries. The compound's molecular structure, featuring both an aromatic benzene ring and a reactive vinyl group, provides the versatility required for extensive chemical modifications and polymer synthesis. From a safety perspective, styrene requires careful handling due to its flammable liquid classification and potential health hazards. The substance carries significant safety considerations including reproductive toxicity concerns, specific target organ toxicity upon repeated exposure, and potential for skin and eye irritation. Proper ventilation systems and personal protective equipment are essential when working with this material, as styrene can polymerize spontaneously under certain conditions, particularly when exposed to heat or light. Industrial applications of styrene are diverse and substantial. The compound serves primarily in polystyrene production, creating everything from disposable food containers to insulation materials. Additionally, styrene plays a crucial role in styrene-butadiene rubber manufacturing and various copolymer synthesis processes. The chemical industry also utilizes styrene alongside related compounds such as ethylbenzene, which serves as a precursor in styrene production, demonstrating the interconnected nature of aromatic chemical manufacturing. OYSI provides technical-grade styrene to European industrial customers, ensuring reliable supply chain management for polymer manufacturers and chemical processors requiring consistent quality standards.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Repr. 2; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2055
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameStyren, Monomer, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is styrene?

Styrene is an organic compound with the chemical formula C8H8, primarily used as a monomer in the production of polystyrene and other synthetic polymers. This colorless, oily liquid has a sweet smell and is classified as a flammable liquid with reproductive toxicity concerns. With a molecular weight of 104.15 g/mol, styrene is an important industrial chemical in the plastics and rubber manufacturing sectors.

What are the physicochemical properties of styrene?

Styrene is a colorless to pale yellow liquid with a characteristic sweet, floral odor at room temperature. It has low water solubility but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound has a tendency to polymerize spontaneously, especially when exposed to heat, light, or peroxides, which is why it requires stabilizers during storage and handling.

What is styrene used for?

Styrene is primarily used as a monomer in the production of polystyrene plastics, expanded polystyrene foam, and styrene-butadiene rubber. It serves as a key raw material in manufacturing synthetic rubber, resins, and various copolymers used in automotive parts, packaging materials, insulation, and consumer goods. Additionally, styrene is utilized in the production of fiberglass-reinforced plastics and as a chemical intermediate in pharmaceutical synthesis.

How to handle styrene safely?

Styrene requires careful handling due to its flammable nature and health hazards. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. Operations should be conducted away from ignition sources, with adequate ventilation to prevent vapor accumulation. Emergency eyewash stations and safety showers should be readily accessible in work areas.

How to store styrene correctly?

Styrene must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and ignition sources. Containers should be kept tightly closed and made of compatible materials to prevent polymerization. Storage areas require temperature control and should be equipped with appropriate fire suppression systems. The substance should be kept away from strong oxidizing agents and peroxide-forming chemicals.

What to do in case of contact with styrene?

Immediate removal from exposure is essential in case of styrene contact. For skin contact, wash thoroughly with soap and water for at least 15 minutes and remove contaminated clothing. In case of eye contact, flush with clean water for 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention in all cases.

How to dispose of styrene properly?

Styrene disposal must comply with local and national hazardous waste regulations as it is classified as hazardous waste. The substance should never be discharged into sewers, waterways, or soil. Disposal should be carried out by licensed waste management companies through appropriate methods such as incineration in approved facilities. Empty containers may also require special handling due to residual vapors and contamination.

How to transport styrene?

Styrene is classified under ADR as Class 3 (flammable liquids), Packing Group III, requiring specific transport regulations compliance. Packages must bear appropriate hazard labels and markings including UN identification numbers. Transport vehicles need proper placarding, and drivers require ADR certification. The substance must be transported in approved containers designed for flammable liquids with adequate venting systems to prevent pressure buildup.

Is styrene subject to specific regulations?

Styrene is subject to comprehensive regulation under REACH and CLP regulations in Europe, requiring registration and classification as a hazardous substance. It carries multiple hazard classifications including reproductive toxicity (Category 2) and specific target organ toxicity. Workplace exposure limits apply, and employers must implement risk management measures. The substance may be subject to additional restrictions depending on specific applications and concentrations.

Where to buy styrene in Europe?

Styrene is available through specialized chemical distributors across Europe, including OYSI, which supplies high-quality industrial chemicals to European markets. As a regulated hazardous substance, purchases typically require compliance verification and may be restricted to qualified industrial users. Buyers should ensure suppliers provide proper safety documentation, certificates of analysis, and comply with REACH registration requirements for commercial transactions.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.