Styrene

C8H8

styrene

CAS100-42-5
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
100-42-5
EC Number
202-851-5
UN Number
2055
Index Number
601-026-00-0
PubChem CID
7501

Physical-chemical properties

Molecular Formula
C8H8
Molar Mass
104.15 g/mol
IUPAC Name
styrene

Chemical Identifiers

InChI
InChI=1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
InChI Key
PPBRXRYQALVLMV-UHFFFAOYSA-N

Overview

Styrene (CAS 100-42-5) is an aromatic hydrocarbon monomer with a characteristic sweet odor used primarily in polymer production. This important industrial chemical, also known by its IUPAC name styrene, serves as a fundamental building block in the manufacture of numerous synthetic materials. With the molecular formula C8H8 and a molecular weight of 104.15 g/mol, styrene consists of a vinyl group attached to a benzene ring, making it highly reactive for polymerization processes. The compound appears as a colorless to pale yellow liquid that can polymerize spontaneously, particularly when exposed to heat, light, or peroxides, which is why it typically contains inhibitors during storage and transport. From a safety perspective, styrene requires careful handling due to its classification under multiple hazard categories. The substance presents flammability risks as a Class 3 flammable liquid under ADR regulations, while also being classified as a reproductive toxicant (Repr. 2) and causing specific target organ toxicity with repeated exposure (STOT RE 1). Additional concerns include acute toxicity, skin irritation, and eye irritation properties, necessitating appropriate personal protective equipment and ventilation systems during handling. The primary industrial applications of styrene include the production of polystyrene plastics, styrene-butadiene rubber, and various copolymers used in automotive, construction, and packaging industries. Unlike related aromatic compounds such as ethylbenzene, styrene's vinyl functionality makes it particularly valuable for creating cross-linked polymer networks. The compound also serves as an intermediate in manufacturing synthetic resins and as a solvent in certain specialized applications. OYSI provides high-quality styrene to meet diverse industrial requirements across European markets, ensuring reliable supply chain management for polymer manufacturers and chemical processors.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Repr. 2; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2055
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameStyren, Monomer, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is styrene?

Styrene is an aromatic hydrocarbon with the molecular formula C8H8 and CAS number 100-42-5. This organic compound has a molecular weight of 104.15 g/mol and appears as a colorless to slightly yellow liquid with a sweet, floral odor. Styrene is classified as a hazardous substance with multiple danger classifications including flammable liquid, reproductive toxicant, and potential carcinogen. It is widely used in the chemical industry as a monomer for polymer production.

What are the physicochemical properties of styrene?

Styrene is a colorless to slightly yellow liquid at room temperature with a characteristic sweet, penetrating odor. It has a molecular weight of 104.15 g/mol and is practically insoluble in water but miscible with most organic solvents. The substance has a boiling point of approximately 145°C and a flash point around 31°C. Styrene tends to polymerize readily, especially when exposed to heat, light, or peroxides, which is why it typically contains stabilizers.

What is styrene used for?

Styrene is primarily used as a monomer in the production of polystyrene plastics, synthetic rubber, and resins. It serves as a key raw material for manufacturing expanded polystyrene (EPS), high-impact polystyrene, and styrene-butadiene rubber. The compound is also utilized in the production of polyester resins, styrene-acrylonitrile copolymers, and as a chemical intermediate in various industrial processes. Additionally, it finds applications in the manufacture of synthetic latex and specialty chemicals.

How to handle styrene safely?

Styrene must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when adequate ventilation is not available. Work should be conducted in well-ventilated areas or under fume hoods due to its volatile nature and potential health effects. Avoid skin and eye contact, and prevent inhalation of vapors. Keep away from heat sources, sparks, and open flames as styrene is flammable. Always follow proper industrial hygiene practices when working with this substance.

How to store styrene correctly?

Styrene should be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and ignition sources. The storage temperature should be kept below 25°C to prevent polymerization. Use appropriate containers made of compatible materials and ensure they are tightly sealed. Store away from oxidizing agents, peroxides, and strong acids. Regular monitoring for signs of polymerization and proper inventory rotation following first-in-first-out principles are essential for safe storage.

What to do in case of contact with styrene?

In case of skin contact with styrene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician in any exposure case.

How to dispose of styrene properly?

Styrene must be disposed of as hazardous waste in accordance with local, national, and EU regulations. The substance cannot be discharged into drains, water courses, or onto the ground. Disposal should only be carried out by licensed waste management companies specialized in hazardous chemical waste. Small quantities should be collected in appropriate containers and labeled clearly. Always consult local environmental authorities for specific disposal requirements and approved waste treatment facilities in your area.

How to transport styrene?

Styrene is classified under ADR as Class 3 (flammable liquid), Packing Group III, requiring specific transport regulations compliance. The substance must be transported in UN-approved packaging with proper labeling including GHS pictograms GHS02, GHS07, and GHS08. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR certification for dangerous goods transport. The shipment must be accompanied by safety data sheets and emergency response information. Professional logistics companies experienced in chemical transport should handle the shipment.

Is styrene subject to specific regulations?

Styrene is subject to extensive EU regulations including REACH registration requirements and CLP classification as Flam. Liq. 3, Repr. 2, Acute Tox. 4, STOT RE 1, Skin Irrit. 2, and Eye Irrit. 2. While not currently listed as a Substance of Very High Concern (SVHC), it requires safety data sheets and appropriate risk management measures. The substance is also regulated under various national occupational exposure limits and environmental protection laws. Industrial users must comply with worker protection and emission control requirements.

Where to buy styrene in Europe?

Styrene is available through OYSI, a professional European distributor of technical chemicals serving industrial customers across Europe. As an established chemical supplier, OYSI provides styrene with proper documentation, safety data sheets, and regulatory compliance support. The company offers reliable supply chains and technical expertise for industrial applications. For purchasing inquiries, pricing, and availability information, customers can contact OYSI directly through their European distribution network to discuss specific requirements and delivery options.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.