2-ethyloxirane

C4H8O

CAS106-88-7
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
106-88-7
EC Number
203-438-2
UN Number
3022
Index Number
603-102-00-9
PubChem CID
7834

Physical-chemical properties

Molecular Formula
C4H8O
Molar Mass
72.11 g/mol
IUPAC Name
2-ethyloxirane

Chemical Identifiers

InChI
InChI=1S/C4H8O/c1-2-4-3-5-4/h4H,2-3H2,1H3
InChI Key
RBACIKXCRWGCBB-UHFFFAOYSA-N

Overview

2-ethyloxirane (CAS 106-88-7) is an epoxide compound with significant industrial applications and notable safety considerations due to its flammable and potentially carcinogenic properties. This colorless liquid belongs to the oxirane family of cyclic ethers, characterized by a highly strained three-membered ring structure containing one oxygen atom. With its molecular formula C4H8O and molar mass of 72.11 g/mol, 2-ethyloxirane exhibits the typical reactivity profile of epoxides, making it a valuable intermediate in various chemical synthesis processes. The compound's ethyl substituent on the oxirane ring influences both its physical properties and chemical behavior compared to simpler epoxides. The substance presents significant safety challenges, classified under multiple hazard categories including flammable liquid (Category 2), suspected carcinogen (Category 2), and acute toxicity (Category 4). The presence of GHS pictograms GHS02, GHS08, and GHS07 indicates fire hazard, health hazard, and general warning respectively. Its ADR Class 3 classification confirms its status as a dangerous good requiring special handling and transport considerations. Workers must implement strict safety protocols including proper ventilation, personal protective equipment, and fire prevention measures. Industrially, 2-ethyloxirane serves as a crucial building block in polymer chemistry and specialty chemical manufacturing. It functions as a reactive monomer in epoxy resin formulations and as an intermediate in the production of surfactants and pharmaceutical compounds. The compound shares certain applications with related industrial chemicals like ethylbenzene and styrene, particularly in polymer synthesis pathways. OYSI maintains reliable supply chains for 2-ethyloxirane to support European industrial operations requiring this specialized epoxide intermediate.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 2; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H351

Suspected of causing cancer.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3022
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,2-Butylenoxid, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-ethyloxirane?

2-ethyloxirane is an organic chemical compound with the molecular formula C4H8O and CAS number 106-88-7. It belongs to the epoxide family, characterized by a three-membered ring containing an oxygen atom. With a molecular weight of 72.11 g/mol, this substance is classified as a flammable liquid with significant health hazards including carcinogenic potential and acute toxicity. It requires careful handling due to its dangerous properties.

What are the physicochemical properties of 2-ethyloxirane?

2-ethyloxirane is a colorless liquid at room temperature with a characteristic ether-like odor. As an epoxide with molecular formula C4H8O, it exhibits high reactivity due to the strained three-membered ring structure. The compound has moderate volatility and is miscible with most organic solvents. Its epoxide functionality makes it prone to ring-opening reactions, particularly in the presence of acids, bases, or nucleophiles.

What is 2-ethyloxirane used for?

2-ethyloxirane is primarily used as an intermediate in chemical synthesis and as a reactive diluent in epoxy resin formulations. Its epoxide functionality makes it valuable for producing specialty chemicals, surfactants, and polymer additives. The compound serves in the manufacture of glycol ethers, plasticizers, and other industrial chemicals. Due to its carcinogenic classification, its use is restricted to professional industrial applications with appropriate safety measures.

How to handle 2-ethyloxirane safely?

2-ethyloxirane requires strict safety protocols due to its flammable, carcinogenic, and toxic properties. Personnel must wear full chemical-resistant suits, respiratory protection, and safety goggles. Work should be conducted in well-ventilated areas away from ignition sources. Avoid skin and eye contact, and prevent vapor inhalation. Emergency shower and eyewash stations must be readily accessible. Only trained professionals should handle this substance following established safety procedures.

How to store 2-ethyloxirane correctly?

2-ethyloxirane must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use tightly sealed, chemically compatible containers in a dedicated chemical storage facility. Keep away from acids, bases, and oxidizing agents that could trigger dangerous reactions. Storage areas should have appropriate fire suppression systems and spill containment measures. Temperature should be controlled to prevent excessive vapor generation.

What to do in case of contact with 2-ethyloxirane?

Immediate action is required upon contact with 2-ethyloxirane. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes. If inhaled, move person to fresh air immediately. For ingestion, do not induce vomiting. Seek immediate medical attention in all cases and provide the safety data sheet to medical personnel.

How to dispose of 2-ethyloxirane appropriately?

2-ethyloxirane disposal must comply with local and national hazardous waste regulations due to its carcinogenic and toxic properties. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper collection and destruction, typically through high-temperature incineration. Never discharge into drains, soil, or water bodies. Maintain detailed disposal records as required by environmental regulations.

How to transport 2-ethyloxirane?

2-ethyloxirane is classified under ADR Class 3 (flammable liquids), Packing Group II, indicating moderate danger level. Transportation requires compliant packaging, proper labeling with GHS pictograms (GHS02, GHS08, GHS07), and appropriate documentation. Vehicles must be equipped with fire extinguishers and emergency equipment. Drivers need hazardous materials training and certification. Transport should avoid extreme temperatures and ensure proper ventilation to prevent vapor accumulation.

Is 2-ethyloxirane subject to specific regulations?

2-ethyloxirane is subject to extensive European regulations including REACH registration, CLP classification requirements, and workplace exposure limits. Its Carcinogenic Category 2 classification triggers specific occupational health regulations and labeling requirements. The substance requires safety data sheets and proper hazard communication. Industrial users must implement risk management measures and may need authorization for certain uses. Regular monitoring and reporting may be mandatory depending on usage quantities and applications.

Where to buy 2-ethyloxirane in Europe?

2-ethyloxirane is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical distributor, OYSI provides this regulated substance to qualified industrial customers with proper documentation and safety data sheets. Due to the substance's hazardous classification, purchases are restricted to companies with appropriate handling capabilities and regulatory compliance. Contact OYSI's technical team for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.