Ethenyl acetate

C4H6O2

ethenyl acetate

CAS108-05-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
108-05-4
EC Number
203-545-4
UN Number
1301
Index Number
607-023-00-0
PubChem CID
7904

Physical-chemical properties

Molecular Formula
C4H6O2
Molar Mass
86.09 g/mol
IUPAC Name
ethenyl acetate

Chemical Identifiers

InChI
InChI=1S/C4H6O2/c1-3-6-4(2)5/h3H,1H2,2H3
InChI Key
XTXRWKRVRITETP-UHFFFAOYSA-N

Overview

Ethenyl acetate (CAS 108-05-4) is a vinyl ester monomer with high reactivity and flammable properties used in polymer production. This colorless liquid compound, also known as vinyl acetate monomer (VAM), represents one of the most important industrial monomers in modern chemical manufacturing. With its molecular formula C4H6O2 and molecular weight of 86.09 g/mol, ethenyl acetate serves as a fundamental building block for numerous polymer applications across diverse industries. The compound features a characteristic vinyl group that enables rapid polymerization reactions, making it particularly valuable for producing polyvinyl acetate (PVA) and various copolymers. From a safety perspective, ethenyl acetate requires careful handling due to its classification as a flammable liquid (Category 2) and suspected carcinogen (Category 2). The substance carries danger signal words and displays GHS pictograms for flammability (GHS02), health hazards (GHS08), and acute toxicity (GHS07). Its ADR Class 3 classification reflects its flammable nature during transportation. Proper ventilation, fire prevention measures, and personal protective equipment are essential when working with this material. Primary industrial applications include the manufacture of polyvinyl acetate for adhesives, paints, and coatings, as well as the production of polyvinyl alcohol through hydrolysis processes. The compound also finds use in textile finishing and paper coating formulations. Unlike related aromatic compounds such as styrene or ethylbenzene, ethenyl acetate offers unique advantages in water-based formulations due to its eventual hydrolysis products. OYSI maintains reliable supplies of ethenyl acetate to support European industrial customers across polymer manufacturing, adhesives, and specialty chemical sectors.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 2; Acute Tox. 4; STOT SE 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H351

Suspected of causing cancer.

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1301
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameVinylacetat, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is ethenyl acetate?

Ethenyl acetate is an organic chemical compound with the molecular formula C4H6O2 and CAS number 108-05-4. It has a molecular weight of 86.09 g/mol and belongs to the acetate ester family. This substance is classified as a flammable liquid with carcinogenic properties, requiring careful handling due to its hazardous nature. It appears as a colorless liquid with a characteristic sweet odor and is widely used in industrial applications for polymer production.

What are the physicochemical properties of ethenyl acetate?

Ethenyl acetate is a colorless, volatile liquid with a sweet, fruity odor characteristic of acetate esters. It has a molecular weight of 86.09 g/mol and is moderately soluble in water while being fully miscible with most organic solvents. The compound exhibits high volatility at room temperature and is highly flammable. Its chemical structure makes it reactive toward polymerization, especially under heat or in the presence of catalysts.

What is ethenyl acetate used for?

Ethenyl acetate is primarily used as a monomer in the production of polyvinyl acetate (PVA) and various copolymers. It serves as a key raw material in manufacturing adhesives, paints, coatings, and textile finishes. The compound is also utilized in the production of chewing gum base, paper coatings, and as an intermediate in organic synthesis. Its polymerization properties make it valuable for creating films, fibers, and other plastic materials in industrial applications.

How to handle ethenyl acetate safely?

Ethenyl acetate requires strict safety protocols due to its flammable and carcinogenic properties. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Handle only in well-ventilated areas or under fume hoods to prevent inhalation. Eliminate all ignition sources as the substance is highly flammable. Use grounding and bonding techniques during transfer operations to prevent static electricity buildup and potential fire hazards.

How to store ethenyl acetate correctly?

Ethenyl acetate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use only approved containers and keep them tightly sealed to prevent vapor escape. Store separate from strong oxidizing agents, acids, and bases to avoid dangerous reactions. Maintain storage temperature below 25°C and implement fire suppression systems. Regular inspection of containers for leaks or damage is essential due to the substance's volatile and flammable nature.

What to do in case of contact with ethenyl acetate?

Immediate action is required upon contact with ethenyl acetate. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult emergency services for serious exposures.

How to dispose of ethenyl acetate appropriately?

Ethenyl acetate disposal must comply with local and European waste regulations as it is classified as hazardous waste. The substance cannot be discharged into sewers, waterways, or regular waste streams. Contact licensed hazardous waste disposal companies for proper treatment, which typically involves incineration at high temperatures in specialized facilities. Small quantities may be recovered through distillation if economically viable. Always maintain proper documentation of disposal activities as required by environmental authorities.

How to transport ethenyl acetate?

Ethenyl acetate is classified under ADR Class 3 (Flammable Liquids), Packing Group II, requiring specialized transport procedures. Use only UN-approved packaging and containers specifically designed for flammable liquids. Vehicles must carry appropriate fire extinguishing equipment and emergency response information. Drivers need ADR certification for dangerous goods transport. Ensure proper labeling with GHS02, GHS07, and GHS08 pictograms and 'Danger' signal word during shipping throughout Europe.

Is ethenyl acetate subject to specific regulations?

Ethenyl acetate is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification as Flam. Liq. 2, Carc. 2, Acute Tox. 4, and STOT SE 3. It requires safety data sheets and proper labeling with danger pictograms. While not currently listed as an SVHC substance, its carcinogenic classification means potential future restrictions. Industrial users must implement risk management measures and may need authorization for certain uses under REACH regulations.

Where to buy ethenyl acetate in Europe?

Ethenyl acetate is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across the continent. OYSI provides reliable supply chains, proper documentation, and regulatory compliance support for hazardous chemicals. As a specialized chemical distributor, OYSI ensures product quality, appropriate packaging, and adherence to ADR transport requirements. Contact OYSI directly for pricing, availability, and technical support for your ethenyl acetate requirements in European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.