Cyclohexanol
C6H12O
cyclohexanol
Consulting for Cyclohexanol
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Identification
- CAS Number
- 108-93-0
- EC Number
- 203-630-6
- UN Number
- 1987
- Index Number
- 603-009-00-3
- PubChem CID
- 7966
Physical-chemical properties
- Molecular Formula
- C6H12O
- Molar Mass
- 100.16 g/mol
- IUPAC Name
- cyclohexanol
Chemical Identifiers
- InChI
- InChI=1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
- InChI Key
- HPXRVTGHNJAIIH-UHFFFAOYSA-N
Overview
Cyclohexanol (CAS 108-93-0) is a cyclic secondary alcohol with characteristic hydroxyl functionality and moderate toxicity properties. This versatile organic compound represents an important member of the cyclohexane derivatives family, featuring a six-membered saturated carbon ring with a single hydroxyl group attached. With its molecular formula C6H12O and molecular weight of 100.16 g/mol, cyclohexanol serves as a crucial intermediate in numerous industrial processes and chemical syntheses. The compound exhibits typical alcohol properties while maintaining the structural stability provided by its cyclic framework. From a safety perspective, cyclohexanol is classified under multiple hazard categories including Acute Toxicity Category 4 and Skin Irritation Category 2, requiring careful handling protocols. The substance carries a Warning signal word and displays the GHS07 pictogram, indicating its potential health hazards upon exposure. Its ADR Class 3 classification identifies it as a flammable liquid, necessitating appropriate storage and transportation measures. These safety considerations make cyclohexanol comparable to other industrial solvents, though it generally presents lower volatility than compounds like 1,4-xylene. Industrial applications of cyclohexanol span multiple sectors, with its primary use as an intermediate in nylon production through conversion to cyclohexanone. The compound also serves as a solvent in various manufacturing processes and finds application in the production of plasticizers and other specialty chemicals. Its chemical reactivity, similar to that of other alcohols but with enhanced stability due to its cyclic structure, makes it valuable for controlled chemical transformations. OYSI maintains reliable supply chains for cyclohexanol to support diverse European industrial requirements, ensuring consistent availability for technical applications across various sectors.
Safety & Classification
Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1987 |
| ADR Class | 3 |
| Packing Group | III |
| Tunnel Code | D/E |
| Proper Shipping Name | Cyclohexanol, technisch, flüssig, entzündbar, Flp. <= 60 °C |
| Marine Pollutant | No |
Frequently Asked Questions
What is cyclohexanol?
Cyclohexanol is a saturated cyclic alcohol with the molecular formula C6H12O and CAS number 108-93-0. It consists of a six-membered cyclohexane ring with one hydroxyl (-OH) group attached. With a molecular weight of 100.16 g/mol, cyclohexanol appears as a colorless, viscous liquid or white crystalline solid at room temperature. It has a characteristic camphor-like odor and is classified as a secondary alcohol due to the hydroxyl group's position on the ring structure.
What are the physicochemical properties of cyclohexanol?
Cyclohexanol is a colorless to pale yellow liquid or white crystalline solid at room temperature with a melting point around 25°C and boiling point of 161°C. It has a distinctive camphor-like or menthol-like odor and is moderately soluble in water (approximately 3-4% by weight). The compound is readily soluble in most organic solvents including ethanol, ether, and acetone. It has a density of approximately 0.96 g/cm³ and exhibits typical alcohol properties including hydrogen bonding capabilities.
What is cyclohexanol used for?
Cyclohexanol is primarily used as an intermediate in the production of adipic acid and caprolactam, which are essential raw materials for manufacturing nylon-6 and nylon-6,6 polymers. It serves as a solvent for lacquers, paints, and varnishes in various industrial applications. Additionally, cyclohexanol is utilized in the textile industry for fabric processing and as a chemical intermediate in the synthesis of plasticizers, pharmaceuticals, and other organic compounds. It also finds use in metal cleaning and degreasing operations.
How to handle cyclohexanol safely?
Cyclohexanol requires careful handling due to its Acute Tox. 4, Skin Irrit. 2, and STOT SE 3 classifications with GHS07 pictogram. Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin contact. Ensure adequate ventilation to avoid inhalation of vapors. Avoid contact with eyes, skin, and clothing. Use in well-ventilated areas away from ignition sources as it's classified as ADR Class 3 (flammable liquid). Handle containers carefully to prevent spills and always follow workplace safety protocols.
How to store cyclohexanol correctly?
Cyclohexanol should be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames due to its flammable nature (ADR Class 3). Keep containers tightly closed and upright to prevent leakage. Store away from strong oxidizing agents and acids which may cause incompatible reactions. Maintain storage temperature below 25°C to prevent melting if stored as solid. Use appropriate secondary containment and ensure storage areas comply with local fire safety regulations for flammable liquids. Regularly inspect containers for signs of damage or deterioration.
What to do in case of contact with cyclohexanol?
Cyclohexanol contact requires immediate first aid measures due to its irritant properties. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, flush immediately with clean water for 15-20 minutes and remove contact lenses if present. For inhalation, move the person to fresh air immediately. If ingested, do not induce vomiting and seek medical attention. Always consult a physician if symptoms persist or in case of significant exposure.
How to dispose of cyclohexanol properly?
Cyclohexanol disposal must comply with local, national, and EU waste regulations as it's classified as hazardous waste. The substance cannot be disposed of in regular waste streams or sewage systems due to its flammable and potentially harmful properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be suitable for solvent recovery programs. Always consult local environmental authorities for specific disposal requirements and ensure proper waste classification codes are used during the disposal process.
How to transport cyclohexanol?
Cyclohexanol is classified under ADR Class 3 (flammable liquids), Packing Group III, requiring specific transport regulations compliance. Use appropriate packaging that meets UN specification requirements for Class 3 substances. Vehicles must carry proper hazard placards and documentation including transport documents with correct shipping names and hazard information. Drivers need ADR certification for dangerous goods transport. Ensure packages are properly sealed, labeled, and secured during transport. Follow routing restrictions and emergency response procedures as specified in ADR regulations.
Is cyclohexanol subject to specific regulations?
Cyclohexanol is subject to several European regulations including REACH registration requirements for manufacturers and importers. It must be classified and labeled according to CLP Regulation with appropriate hazard statements and precautionary measures (GHS07 pictogram, Warning signal word). The substance is not currently listed as an SVHC (Substance of Very High Concern). Transport is regulated under ADR for dangerous goods. Workplace exposure limits may apply under occupational health regulations. Users must comply with national chemical safety legislation and maintain appropriate safety data sheets.
Where to buy cyclohexanol in Europe?
Cyclohexanol is available throughout Europe from specialized chemical distributors like OYSI, which supplies high-quality industrial chemicals to European markets. OYSI offers cyclohexanol for various industrial applications with proper documentation including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures compliance with European regulations and provides technical support for customers. Contact OYSI directly for specific grades, packaging options, and availability in your region. Other chemical suppliers and trading companies also distribute cyclohexanol across European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.