1,4-xylene

C8H10

CAS106-42-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
106-42-3
EC Number
203-396-5
UN Number
1307
Index Number
601-022-00-9
PubChem CID
7809

Physical-chemical properties

Molecular Formula
C8H10
Molar Mass
106.16 g/mol
IUPAC Name
1,4-xylene

Chemical Identifiers

InChI
InChI=1S/C8H10/c1-7-3-5-8(2)6-4-7/h3-6H,1-2H3
InChI Key
URLKBWYHVLBVBO-UHFFFAOYSA-N

Overview

1,4-Xylene (CAS 106-42-3) is an aromatic hydrocarbon solvent with excellent dissolving properties and moderate volatility. 1,4-Xylene, also known as para-xylene, represents one of the three xylene isomers widely used in industrial applications. This colorless liquid belongs to the family of aromatic hydrocarbons and serves as a crucial intermediate in chemical synthesis and solvent applications. With its molecular formula C8H10 and molecular weight of 106.16 g/mol, this compound exhibits characteristic properties that make it valuable across multiple industrial sectors. The substance is classified as a flammable liquid (Category 3) and carries acute toxicity warnings, requiring careful handling protocols in professional environments. Its GHS02 and GHS07 pictograms indicate both fire hazards and health risks, necessitating appropriate safety measures during storage, handling, and transportation. The ADR Class 3 classification confirms its flammable nature for shipping purposes. Key industrial applications include its use as a solvent in paints, coatings, and adhesives, where its excellent solvency power proves essential. The chemical industry utilizes 1,4-xylene as a starting material for various synthetic processes, particularly in polymer production. Additionally, it finds application in the formulation of specialty chemicals and as a component in cleaning products for industrial use. While structurally different from compounds like 1-methoxypropan-2-ol, 1,4-xylene shares certain solvent characteristics that make it suitable for similar applications in specific formulations. Its aromatic nature distinguishes it from aliphatic solvents, providing unique dissolving capabilities for aromatic and petroleum-based materials. OYSI maintains reliable supplies of 1,4-xylene to support European industrial customers' technical requirements and manufacturing processes.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; Acute Tox. 4 *; Acute Tox. 4 *; Skin Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H315

Causes skin irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1307
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namep-Xylen
Marine PollutantNo

Frequently Asked Questions

What is 1,4-xylene?

1,4-xylene is an aromatic hydrocarbon compound with the molecular formula C8H10 and CAS number 106-42-3. It belongs to the xylene isomer family, featuring a benzene ring with two methyl groups positioned at the 1 and 4 positions (para-xylene). With a molecular weight of 106.16 g/mol, this flammable liquid is commonly used as an industrial solvent and chemical intermediate in various manufacturing processes.

What are the physicochemical properties of 1,4-xylene?

1,4-xylene is a colorless liquid at room temperature with a characteristic sweet aromatic odor. It has a boiling point of approximately 138°C and a melting point of 13°C. The compound is practically insoluble in water but readily dissolves in most organic solvents including alcohols, ethers, and other hydrocarbons. It has a density lower than water and exhibits moderate volatility at ambient temperatures.

What is 1,4-xylene used for?

1,4-xylene serves primarily as a solvent in industrial applications including paints, coatings, adhesives, and printing inks. It is extensively used as a chemical intermediate in the production of terephthalic acid, which is essential for manufacturing polyethylene terephthalate (PET) plastics and polyester fibers. Additionally, it finds application in the pharmaceutical industry, rubber processing, and as a component in various chemical synthesis processes.

How to handle 1,4-xylene safely?

1,4-xylene requires careful handling due to its flammable nature and potential health hazards. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when necessary. Work in well-ventilated areas or under fume extraction systems to prevent vapor accumulation. Keep away from ignition sources, hot surfaces, and oxidizing materials. Avoid skin contact and inhalation of vapors during handling operations.

How to store 1,4-xylene correctly?

1,4-xylene must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and direct sunlight. Keep containers in secondary containment to prevent spills and maintain storage temperatures below 25°C when possible. Store separately from oxidizing agents, strong acids, and bases to prevent incompatible reactions. Ensure storage areas are equipped with appropriate fire suppression systems and spill containment measures.

What to do in case of contact with 1,4-xylene?

In case of skin contact with 1,4-xylene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, flush eyes with clean water for 15 minutes while holding eyelids open. For inhalation exposure, move the person to fresh air immediately. If ingestion occurs, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist.

How to dispose of 1,4-xylene appropriately?

1,4-xylene waste must be disposed of according to local and national hazardous waste regulations as it is classified as a flammable liquid. Contact licensed waste disposal companies for proper collection and treatment. Never pour down drains, sewers, or onto soil. Small quantities may be suitable for solvent recovery or incineration at appropriate high-temperature facilities. Always consult local environmental authorities for specific disposal requirements in your region.

How to transport 1,4-xylene?

1,4-xylene is classified under ADR transport regulations as Class 3 (Flammable Liquids), Packing Group III. Transport must comply with dangerous goods regulations including proper packaging, labeling with appropriate hazard diamonds, and documentation. Vehicles must carry appropriate emergency equipment and drivers require hazardous materials training certification. Ensure containers are properly secured and compatible with the chemical to prevent leaks during transit.

Is 1,4-xylene subject to particular regulations?

1,4-xylene is regulated under European REACH and CLP regulations, requiring safety data sheets and hazard classification. It is not currently listed as a Substance of Very High Concern (SVHC). The compound must be labeled with GHS pictograms GHS02 and GHS07, along with the signal word 'Warning'. Industrial users must comply with workplace exposure limits and may require authorization for certain uses depending on quantities and applications.

Where to buy 1,4-xylene in Europe?

1,4-xylene is available through OYSI, a reliable European distributor of chemical products. OYSI provides high-quality 1,4-xylene with proper documentation including safety data sheets and certificates of analysis. As a specialized chemical distributor, OYSI ensures compliance with European regulations and offers professional technical support for industrial customers across Europe. Contact OYSI directly for availability, specifications, and delivery options in your region.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.