1,4-xylene

C8H10

CAS106-42-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
106-42-3
EC Number
203-396-5
UN Number
1307
Index Number
601-022-00-9
PubChem CID
7809

Physical-chemical properties

Molecular Formula
C8H10
Molar Mass
106.16 g/mol
IUPAC Name
1,4-xylene

Chemical Identifiers

InChI
InChI=1S/C8H10/c1-7-3-5-8(2)6-4-7/h3-6H,1-2H3
InChI Key
URLKBWYHVLBVBO-UHFFFAOYSA-N

Overview

1,4-xylene (CAS 106-42-3) is an aromatic hydrocarbon solvent with excellent dissolving properties and moderate flammability characteristics. 1,4-xylene, also known as para-xylene, represents one of the three isomeric forms of xylene and serves as a crucial intermediate in petrochemical manufacturing. This colorless, flammable liquid belongs to the family of aromatic hydrocarbons and exhibits the characteristic sweet odor typical of benzene derivatives. With its molecular formula C8H10 and molar mass of 106.16 g/mol, para-xylene demonstrates significant commercial importance in industrial applications. From a safety perspective, 1,4-xylene is classified as a flammable liquid category 3 under GHS regulations, requiring appropriate fire prevention measures during handling and storage. The substance exhibits acute toxicity category 4 properties and can cause skin irritation, necessitating proper personal protective equipment including chemical-resistant gloves and adequate ventilation systems. The ADR class 3 classification reflects its flammable nature, requiring compliance with specific transportation regulations. The primary industrial application of 1,4-xylene lies in the production of terephthalic acid and dimethyl terephthalate, essential precursors for polyethylene terephthalate (PET) manufacturing. This makes para-xylene indispensable in the plastic bottle and polyester fiber industries. Additionally, it serves as a high-performance solvent in paint formulations, adhesives, and coating applications. Unlike related compounds such as 1-methoxypropan-2-ol which finds use in different solvent applications, 1,4-xylene's aromatic structure provides superior dissolving power for specific organic compounds. The chemical also functions as an intermediate in specialty chemical synthesis and as a component in fuel blending applications where its octane-enhancing properties prove valuable. OYSI maintains reliable supplies of high-quality 1,4-xylene to support diverse industrial requirements across European markets.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; Acute Tox. 4 *; Acute Tox. 4 *; Skin Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H315

Causes skin irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1307
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namep-Xylen
Marine PollutantNo

Frequently Asked Questions

What is 1,4-xylene?

1,4-xylene is an aromatic hydrocarbon compound with the molecular formula C8H10 and CAS number 106-42-3. It belongs to the xylene family, which consists of three isomeric forms of dimethylbenzene. Also known as para-xylene, this colorless liquid has a molecular weight of 106.16 g/mol and is characterized by its distinctive sweet aromatic odor typical of benzene derivatives.

What are the physicochemical properties of 1,4-xylene?

1,4-xylene is a colorless liquid at room temperature with a characteristic sweet, aromatic odor. It has a boiling point of approximately 138°C and a melting point of 13°C. The compound is practically insoluble in water but readily soluble in organic solvents such as ethanol, ether, and acetone. It has a density lower than water and exhibits flammable properties.

What is 1,4-xylene used for?

1,4-xylene serves primarily as a feedstock in the petrochemical industry for the production of terephthalic acid and dimethyl terephthalate, which are essential precursors for polyester resins, fibers, and PET plastics. It is also used as a solvent in various industrial applications, including paints, coatings, adhesives, and rubber processing. Additionally, it finds use in the production of certain pharmaceuticals and agrochemicals.

How to handle 1,4-xylene safely?

1,4-xylene requires careful handling due to its flammable nature and potential health hazards. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and appropriate respiratory protection when ventilation is inadequate. Work should be conducted in well-ventilated areas away from ignition sources. Avoid skin and eye contact, and prevent inhalation of vapors. Ground all equipment to prevent static electricity buildup.

How to store 1,4-xylene correctly?

1,4-xylene must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Use appropriate containers made of compatible materials and ensure they are tightly sealed to prevent vapor escape. Storage areas should be equipped with fire suppression systems and spill containment measures. Keep away from oxidizing agents and incompatible materials that could cause dangerous reactions.

What to do in case of contact with 1,4-xylene?

Immediate action is required upon contact with 1,4-xylene. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of clean water for at least 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention in all cases.

How to dispose of 1,4-xylene properly?

1,4-xylene disposal must comply with local, national, and international waste regulations. The substance cannot be disposed of in regular waste streams due to its hazardous classification. It should be collected by licensed waste management companies specializing in hazardous chemical disposal. Incineration at appropriate high-temperature facilities or recovery through distillation are common disposal methods. Empty containers may also require special handling.

How to transport 1,4-xylene?

1,4-xylene is classified under ADR as Class 3 (flammable liquids), Packing Group III. Transportation must comply with dangerous goods regulations, requiring appropriate packaging, labeling, and documentation. Vehicles must be equipped with proper safety equipment and drivers need hazardous materials training. The substance requires UN specification packaging and proper placarding during transport. Emergency response information must accompany shipments.

Is 1,4-xylene subject to specific regulations?

1,4-xylene is subject to various European regulations including REACH registration requirements and CLP classification as Flam. Liq. 3 and Acute Tox. 4. It carries Warning signal word and requires GHS02 and GHS07 pictograms on labels. The substance is not currently listed as an SVHC (Substance of Very High Concern). Users must comply with workplace exposure limits and safety data sheet requirements.

Where to buy 1,4-xylene in Europe?

1,4-xylene is available through OYSI, a European distributor of technical chemicals serving various industries across the continent. OYSI provides quality chemical products with proper documentation, safety data sheets, and regulatory compliance support. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical support for industrial customers requiring 1,4-xylene for their manufacturing processes and applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.