Benzene-1,2-diamine
C6H8N2
benzene-1,2-diamine
Consulting for Benzene-1,2-diamine
Our experts support you with application, dosage, and compliance.
Identification
- CAS Number
- 95-54-5
- EC Number
- 202-430-6
- UN Number
- 1673
- Index Number
- 612-145-00-2
- PubChem CID
- 7243
Physical-chemical properties
- Molecular Formula
- C6H8N2
- Molar Mass
- 108.14 g/mol
- IUPAC Name
- benzene-1,2-diamine
Chemical Identifiers
- InChI
- InChI=1S/C6H8N2/c7-5-3-1-2-4-6(5)8/h1-4H,7-8H2
- InChI Key
- GEYOCULIXLDCMW-UHFFFAOYSA-N
Overview
Benzene-1,2-diamine (CAS 95-54-5) is an aromatic diamine compound with two adjacent amino groups on a benzene ring. This organic chemical, also known by its IUPAC designation benzene-1,2-diamine, represents a fundamental aromatic amine structure with significant industrial relevance. With the molecular formula C6H8N2 and a molecular weight of 108.14 g/mol, this compound features two amino groups positioned ortho to each other on the benzene ring, creating unique chemical reactivity patterns that distinguish it from other diamine isomers. The substance requires careful handling due to its classification under multiple hazard categories, including carcinogenicity (Category 2) and mutagenicity (Category 2), as indicated by the GHS08 pictogram. Additional safety concerns include acute toxicity across multiple exposure routes and skin sensitization potential, necessitating appropriate protective measures during industrial processing. The ADR classification of 6.1 reflects its toxic nature for transportation purposes. Benzene-1,2-diamine serves primarily as a chemical intermediate in the production of various industrial compounds. Its most significant application lies in the manufacture of benzimidazole derivatives, which are essential components in pharmaceutical synthesis and polymer chemistry. The compound also finds use in the production of specialty dyes and pigments, where its aromatic diamine structure provides crucial color-forming properties. Additionally, it serves as a building block for certain corrosion inhibitors and rubber chemicals. This compound belongs to the same chemical family as other aromatic amines such as N-methylaniline, sharing similar reactivity patterns but offering distinct positioning advantages due to its ortho-diamine configuration. Unlike phenylhydrazine, which contains a hydrazine functional group, benzene-1,2-diamine provides dual amino functionality for enhanced cross-linking applications. OYSI maintains reliable supply chains for benzene-1,2-diamine to support European industrial applications requiring this specialized aromatic intermediate.
Safety & Classification
Carc. 2; Muta. 2; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 3 *; Eye Irrit. 2; Skin Sens. 1; Aqu...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing cancer.
Suspected of causing genetic defects.
Harmful if inhaled.
Harmful in contact with skin.
Toxic if swallowed.
Causes serious eye irritation.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1673 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | o-Phenylendiamin, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzene-1,2-diamine?
Benzene-1,2-diamine is an aromatic organic compound with the molecular formula C6H8N2 and CAS number 95-54-5. Also known as o-phenylenediamine, it consists of a benzene ring with two adjacent amino groups (-NH2) attached to carbon atoms 1 and 2. With a molecular weight of 108.14 g/mol, this chemical is classified as hazardous with multiple danger classifications including carcinogenic and mutagenic properties, requiring careful handling in industrial applications.
What are the physicochemical properties of benzene-1,2-diamine?
Benzene-1,2-diamine appears as crystalline solid at room temperature, typically exhibiting a pale yellow to brown coloration that darkens upon exposure to air and light. The compound has a characteristic amine-like odor and demonstrates good solubility in water, alcohol, and other polar solvents. Due to its aromatic structure with two amino groups, it exhibits basic properties and can form salts with acids, making it reactive in various chemical processes.
What is benzene-1,2-diamine used for?
Benzene-1,2-diamine serves primarily as an intermediate in the production of dyes, pigments, and polymers in industrial applications. It is extensively used in the manufacture of hair dyes, textile dyes, and as a curing agent for epoxy resins. Additionally, it functions as a building block for pharmaceuticals, antioxidants, and corrosion inhibitors. The compound also finds application in analytical chemistry as a reagent for detecting various substances.
How to handle benzene-1,2-diamine safely?
Benzene-1,2-diamine requires strict safety measures due to its carcinogenic and mutagenic properties. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Skin contact and inhalation must be avoided completely. Work should be conducted in fume hoods with proper ventilation systems, and all safety data sheet recommendations must be followed rigorously to prevent exposure and potential health risks.
How to store benzene-1,2-diamine correctly?
Benzene-1,2-diamine must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from direct sunlight and heat sources. The storage area should be separated from incompatible materials such as strong oxidizing agents and acids. Containers should be kept upright and properly labeled according to GHS requirements. Temperature control is essential to prevent degradation, and storage facilities must comply with local regulations for hazardous chemicals handling and containment.
What to do in case of contact with benzene-1,2-diamine?
Immediate action is required for any contact with benzene-1,2-diamine. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, rinse with clean water for at least 15 minutes. In all cases of exposure, seek immediate medical attention and provide the safety data sheet to healthcare professionals.
How to dispose of benzene-1,2-diamine properly?
Benzene-1,2-diamine disposal must comply with local and national hazardous waste regulations due to its toxic and potentially carcinogenic nature. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment facilities. Waste should be collected in appropriate containers, properly labeled, and handled by licensed waste disposal companies. Incineration at high temperatures in approved facilities is typically the preferred disposal method for this chemical.
How to transport benzene-1,2-diamine?
Benzene-1,2-diamine is classified under ADR Class 6.1 (Toxic substances) Group III for transportation purposes. Packages must comply with specific packing instructions and display appropriate hazard labels including GHS pictograms GHS06, GHS08, and GHS09. Vehicles must carry proper documentation, emergency response information, and drivers require hazardous materials training. Transportation must follow all applicable dangerous goods regulations to ensure safe handling during transit.
Is benzene-1,2-diamine subject to specific regulations?
Benzene-1,2-diamine is subject to comprehensive regulatory oversight under REACH, CLP, and various national chemical safety regulations. The substance carries multiple hazard classifications including Carcinogenic Category 2, Mutagenic Category 2, and Acute Toxicity warnings. While not currently listed as an SVHC, it requires strict compliance with occupational exposure limits, proper labeling, and safety data sheet provisions. Users must ensure full regulatory compliance before handling or processing this chemical.
Where to buy benzene-1,2-diamine in Europe?
Benzene-1,2-diamine is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. As an established chemical supplier, OYSI ensures proper handling, documentation, and regulatory compliance for this hazardous substance. Customers must provide appropriate credentials and intended use information due to the chemical's restricted nature. Professional buyers can contact OYSI directly to discuss availability, specifications, and delivery arrangements for their specific industrial applications.
Services for Benzene-1,2-diamine
Order Benzene-1,2-diamine
Fast delivery across Europe
SDS Service
Request Safety Data Sheet for Benzene-1,2-diamine
Technical Consulting
Application advice for Benzene-1,2-diamine
REACH Safety Data Sheet
REACH Compliance Service
Digital Product Passport
EU-compliant product documentation
ADR Consulting for Benzene-1,2-diamine
Benzene-1,2-diamine is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.