Hydrazine

H4N2

hydrazine

CAS302-01-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
302-01-2
EC Number
206-114-9
UN Number
2029
Index Number
007-008-00-3
PubChem CID
9321

Physical-chemical properties

Molecular Formula
H4N2
Molar Mass
32.05 g/mol
IUPAC Name
hydrazine

Chemical Identifiers

InChI
InChI=1S/H4N2/c1-2/h1-2H2
InChI Key
OAKJQQAXSVQMHS-UHFFFAOYSA-N

Overview

Hydrazine (CAS 302-01-2) is a highly reactive inorganic compound with strong reducing properties and significant industrial applications. This colorless, fuming liquid represents one of the most versatile yet hazardous chemicals in industrial chemistry. With its molecular formula H4N2 and relatively low molecular weight of 32.046 g/mol, hydrazine exhibits unique chemical properties that make it invaluable across multiple sectors. The compound's high reactivity stems from its nitrogen-nitrogen single bond, which provides exceptional reducing capabilities under various conditions. Safety considerations are paramount when handling hydrazine, as evidenced by its comprehensive hazard classification. The substance carries a "Danger" signal word and displays multiple GHS pictograms including flammability, health hazard, toxicity, corrosiveness, and environmental danger symbols. Its classification as a Category 1B carcinogen requires strict containment protocols, while its corrosive nature (Skin Corr. 1B) and acute toxicity profile demand specialized handling equipment and comprehensive safety training. The compound's primary industrial applications include aerospace propulsion systems, where it serves as a rocket fuel and satellite thruster propellant due to its hypergolic properties. In chemical manufacturing, hydrazine functions as a crucial intermediate for producing pharmaceuticals, agricultural chemicals, and specialty polymers. Water treatment facilities utilize hydrazine as an oxygen scavenger in boiler systems, preventing corrosion in high-pressure steam applications. Unlike related nitrogen-containing compounds such as pentanedial, hydrazine's unique structure enables these specialized applications while requiring enhanced safety protocols. OYSI maintains reliable supply chains for hydrazine, ensuring consistent availability for qualified industrial customers throughout Europe.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Carc. 1B; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; Skin Corr. 1B; Skin Sens....

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H350

May cause cancer.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2029
ADR Class8
Packing GroupI
Tunnel CodeE
Proper Shipping NameHydrazin, wasserfrei
Marine PollutantNo

Frequently Asked Questions

What is hydrazine?

Hydrazine is a highly reactive inorganic compound with the molecular formula H4N2 and CAS number 302-01-2. This colorless liquid serves as a powerful reducing agent and rocket fuel component. With a molecular weight of 32.046 g/mol, hydrazine is classified as a carcinogen (Category 1B) and corrosive substance, requiring extreme caution in handling due to its toxic and flammable properties.

What are the physicochemical properties of hydrazine?

Hydrazine is a colorless, oily liquid with an ammonia-like odor at room temperature. It is highly soluble in water and miscible with alcohols. The compound has a boiling point of 113.5°C and a melting point of 2°C. Hydrazine is hygroscopic, meaning it readily absorbs moisture from air, and exhibits strong basic properties with corrosive characteristics toward metals and organic materials.

What is hydrazine used for?

Hydrazine is primarily used as rocket fuel and satellite propellant due to its high energy density. Industrial applications include use as a reducing agent in metal processing, an oxygen scavenger in boiler water treatment, and a blowing agent for foam rubber production. It also serves as an intermediate in pharmaceutical synthesis and agricultural chemical manufacturing, particularly for pesticides and fungicides.

How to handle hydrazine safely?

Hydrazine requires strict safety protocols including full-face respirators, chemical-resistant gloves, and complete body protection suits. Work must be conducted in well-ventilated areas or fume hoods to prevent inhalation exposure. Avoid contact with skin, eyes, and clothing. Use explosion-proof equipment due to flammability risks. Emergency shower and eyewash stations must be readily accessible, and personnel should be trained in emergency response procedures.

How to store hydrazine correctly?

Hydrazine must be stored in tightly sealed containers made of stainless steel or compatible materials in cool, dry, well-ventilated areas away from heat sources and ignition points. Keep separate from oxidizing agents, acids, and metals like copper or brass. Storage areas should be equipped with appropriate fire suppression systems and spill containment measures. Temperature should be maintained below 25°C to prevent decomposition.

What to do in case of contact with hydrazine?

Hydrazine exposure requires immediate action: for skin contact, remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately and provide oxygen if breathing is difficult. For ingestion, do not induce vomiting and seek immediate medical care.

How to dispose of hydrazine appropriately?

Hydrazine disposal must comply with local and European waste regulations as hazardous chemical waste. The substance cannot be discharged into sewers or waterways due to its toxic and carcinogenic properties. Disposal should be performed by licensed hazardous waste contractors through controlled incineration at high temperatures or chemical neutralization processes. Contact local environmental authorities for specific disposal requirements and approved facilities.

How to transport hydrazine?

Hydrazine is classified under ADR Class 8 (Corrosive substances), Packing Group I, indicating maximum danger level. Transport requires specialized packaging meeting UN specifications, proper labeling with GHS pictograms (GHS02, GHS08, GHS06, GHS05, GHS09), and documentation including safety data sheets. Only authorized carriers with hazardous materials certification can transport hydrazine, following strict routing and emergency response protocols.

Is hydrazine subject to particular regulations?

Hydrazine is subject to extensive European regulations under REACH and CLP classifications. As a Category 1B carcinogen, it requires authorization for specific uses and comprehensive risk assessments. The substance faces restrictions under various industrial chemical directives and requires special licensing for purchase and use. Employers must implement strict occupational exposure limits and health surveillance programs for workers handling hydrazine.

Where to buy hydrazine in Europe?

Hydrazine is available through OYSI, a trusted European distributor of technical chemicals, serving industrial customers across Europe. As a controlled substance requiring special permits and documentation, OYSI ensures compliance with all regulatory requirements and provides proper safety data sheets and handling guidance. Contact OYSI's technical team to discuss specific requirements, quantities, and regulatory compliance for your hydrazine procurement needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.