Acetaldehyde
C2H4O
acetaldehyde
Consulting for Acetaldehyde
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Identification
- CAS Number
- 75-07-0
- EC Number
- 200-836-8
- UN Number
- 1089
- Index Number
- 605-003-00-6
- PubChem CID
- 177
Physical-chemical properties
- Molecular Formula
- C2H4O
- Molar Mass
- 44.05 g/mol
- IUPAC Name
- acetaldehyde
Chemical Identifiers
- InChI
- InChI=1S/C2H4O/c1-2-3/h2H,1H3
- InChI Key
- IKHGUXGNUITLKF-UHFFFAOYSA-N
Overview
Acetaldehyde (CAS 75-07-0) is a highly flammable organic aldehyde with a characteristic pungent odor and significant industrial importance as a chemical intermediate. This colorless liquid compound, with the molecular formula C2H4O and a molecular weight of 44.05 g/mol, represents one of the most fundamental aldehydes in organic chemistry. Acetaldehyde occurs naturally in various biological processes and is produced industrially through multiple synthetic routes, primarily the oxidation of ethanol or the hydration of acetylene. Its reactive carbonyl group makes it an essential building block for numerous chemical syntheses, positioning it as a crucial intermediate in the production of various downstream chemicals. The substance exhibits highly flammable properties, classified under ADR Class 3, and requires careful handling due to its low flash point and wide explosive limits. Safety considerations are paramount when working with acetaldehyde, as it is classified as a Category 1B carcinogen and Category 2 mutagen under GHS regulations. The compound also presents risks as an eye irritant and can cause specific target organ toxicity following single exposure, particularly affecting the respiratory system. These hazard classifications necessitate stringent safety protocols during storage, handling, and transportation. Industrially, acetaldehyde serves primarily in the manufacture of acetic acid through oxidation processes, accounting for a significant portion of global consumption. It also functions as an intermediate in the production of various chemicals including pyridines, pentaerythritol, and crotonaldehyde. Additionally, acetaldehyde finds application in the synthesis of certain pharmaceuticals and agrochemicals. Unlike aromatic compounds such as ethylbenzene or styrene, acetaldehyde's aliphatic aldehyde structure provides unique reactivity patterns that make it indispensable for specific synthetic pathways. OYSI maintains reliable supply chains for acetaldehyde to support European industrial customers requiring this essential chemical intermediate.
Safety & Classification
Flam. Liq. 1; Carc. 1B; Muta. 2; STOT SE 3; Eye Irrit. 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1089 |
| ADR Class | 3 |
| Packing Group | I |
| Tunnel Code | D/E |
| Proper Shipping Name | Acetaldehyd |
| Marine Pollutant | No |
Frequently Asked Questions
What is acetaldehyde?
Acetaldehyde is an organic chemical compound with the molecular formula C2H4O and a molar mass of 44.05 g/mol. It is a highly flammable liquid classified as a carcinogenic substance (Category 1B) and mutagen (Category 2). This aldehyde is characterized by its volatility and reactivity, making it an important intermediate in various chemical processes. Due to its hazardous properties, it requires careful handling and is subject to strict safety regulations.
What are the physicochemical properties of acetaldehyde?
Acetaldehyde is a colorless, highly volatile liquid with a characteristic pungent, fruity odor. It has a low boiling point and is miscible with water, ethanol, and most organic solvents. The compound is highly flammable (Flammable Liquid Category 1) and readily evaporates at room temperature. Its molecular structure (C2H4O) makes it chemically reactive, particularly prone to oxidation and polymerization reactions under certain conditions.
What is acetaldehyde used for?
Acetaldehyde is primarily used as an intermediate in the production of acetic acid, ethyl acetate, and other organic compounds. It serves as a building block in the manufacture of plastics, synthetic resins, and pharmaceuticals. The chemical industry utilizes it for producing perfumes, flavoring agents, and dyes. Additionally, it finds applications in the synthesis of pyridine derivatives and as a reducing agent in various chemical processes.
How to handle acetaldehyde safely?
Acetaldehyde requires strict safety measures due to its flammable and carcinogenic properties. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Eliminate all ignition sources as it forms explosive vapor-air mixtures. Ground all equipment to prevent static discharge and use explosion-proof electrical equipment in handling areas.
How to store acetaldehyde correctly?
Acetaldehyde must be stored in a cool, dry, well-ventilated area away from heat sources and ignition points. Use appropriate containers resistant to the chemical and ensure proper grounding to prevent static buildup. Store separately from oxidizing agents, acids, and bases to prevent dangerous reactions. Temperature should be kept low to minimize evaporation and maintain product stability. Implement fire prevention measures and ensure storage areas comply with local fire safety regulations.
What to do in case of contact with acetaldehyde?
Immediate removal from exposure is essential when contact with acetaldehyde occurs. For skin contact, rinse thoroughly with water for at least 15 minutes and remove contaminated clothing. In case of eye contact, flush with clean water for 15-20 minutes. If inhaled, move to fresh air immediately and seek medical attention if breathing difficulties persist. For ingestion, do not induce vomiting and seek immediate medical care. Always consult emergency services for serious exposures.
How to dispose of acetaldehyde properly?
Acetaldehyde disposal must comply with local environmental regulations as it is classified as hazardous waste. The substance should be collected in appropriate containers and handed over to licensed waste disposal companies. Never discharge into sewers, waterways, or soil due to its toxic and environmental impact. Small quantities may be neutralized through controlled oxidation in specialized facilities. Always consult local authorities and waste management experts for proper disposal procedures.
How to transport acetaldehyde?
Acetaldehyde is classified under ADR Class 3 (Flammable Liquids), Packing Group I, indicating high danger level for transport. Specialized packaging meeting UN specifications is required, along with proper labeling including GHS02, GHS07, and GHS08 pictograms with 'Danger' signal word. Vehicles must comply with ADR regulations for flammable substances, including appropriate fire extinguishing equipment. Drivers require hazardous materials training and ADR certification for legal transportation.
Is acetaldehyde subject to specific regulations?
Acetaldehyde is subject to comprehensive European regulations including REACH registration requirements and CLP classification as Flam. Liq. 1, Carc. 1B, and Muta. 2. While not currently listed as an SVHC substance, its carcinogenic classification means strict occupational exposure limits apply. Companies must implement risk management measures, provide safety data sheets, and ensure worker protection. Additional national restrictions may apply for certain uses or concentrations across EU member states.
Where to buy acetaldehyde in Europe?
Acetaldehyde is available through OYSI, a specialized European distributor of chemical products. As a professional chemical supplier, OYSI can provide technical-grade acetaldehyde with appropriate documentation including safety data sheets and certificates of analysis. Given the substance's hazardous classification, purchases typically require demonstration of proper handling capabilities and intended professional use. Contact OYSI directly for availability, specifications, and regulatory compliance support for your specific application requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.