Acetaldehyde

C2H4O

acetaldehyde

CAS75-07-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-07-0
EC Number
200-836-8
UN Number
1089
Index Number
605-003-00-6
PubChem CID
177

Physical-chemical properties

Molecular Formula
C2H4O
Molar Mass
44.05 g/mol
IUPAC Name
acetaldehyde

Chemical Identifiers

InChI
InChI=1S/C2H4O/c1-2-3/h2H,1H3
InChI Key
IKHGUXGNUITLKF-UHFFFAOYSA-N

Overview

Acetaldehyde (CAS 75-07-0) is an organic aldehyde compound with a characteristic pungent odor and high volatility at room temperature. This colorless, flammable liquid represents one of the most important aldehydes in industrial chemistry, serving as a crucial intermediate in numerous chemical processes. With its molecular formula C2H4O and relatively low molecular weight of 44.05 g/mol, acetaldehyde exhibits high reactivity due to its carbonyl functional group, making it valuable for synthetic applications across multiple industries. The compound presents significant safety considerations, classified as a Category 1B carcinogen and Category 2 mutagen under GHS classification. Its extremely flammable nature (Flammable Liquid Category 1) requires stringent handling protocols, while its potential for eye irritation and specific target organ toxicity demands appropriate personal protective equipment during use. The ADR Class 3 designation reflects its hazardous transport requirements. Acetaldehyde finds extensive application in the production of acetic acid through oxidation processes, serving as a key building block in chemical manufacturing. The pharmaceutical and fragrance industries utilize this compound for synthesizing various organic molecules, while it also functions as an important intermediate in plastic and resin production. Unlike related aromatic compounds such as ethylbenzene and styrene, acetaldehyde's aliphatic aldehyde structure provides distinct reactivity patterns particularly valuable in carbonyl chemistry applications. The compound's high vapor pressure and miscibility with water and organic solvents make it versatile for numerous industrial formulations, though its handling requires specialized equipment due to safety considerations. OYSI maintains reliable supply chains for acetaldehyde, ensuring consistent availability for industrial customers across European markets.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Carc. 1B; Muta. 2; STOT SE 3; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H350

May cause cancer.

H341

Suspected of causing genetic defects.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1089
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameAcetaldehyd
Marine PollutantNo

Frequently Asked Questions

What is acetaldehyde?

Acetaldehyde is an organic chemical compound with the molecular formula C2H4O and CAS number 75-07-0. This aldehyde has a molecular weight of 44.05 g/mol and appears as a colorless liquid with a characteristic pungent, fruity odor. It is classified as extremely flammable and poses significant health hazards including carcinogenic and mutagenic properties, requiring careful handling in industrial applications.

What are the physicochemical properties of acetaldehyde?

Acetaldehyde is a colorless, volatile liquid with a sharp, penetrating fruity odor at room temperature. It has a low boiling point of 20.2°C and is highly soluble in water, alcohol, and most organic solvents. The compound is extremely flammable with a very low flash point, making it highly reactive. Its vapor is heavier than air and can travel considerable distances to ignition sources.

What is acetaldehyde used for?

Acetaldehyde is primarily used as an intermediate in the production of acetic acid, pyridine derivatives, and various chemical compounds. It serves as a precursor in manufacturing perfumes, flavoring agents, aniline dyes, and plastics. The compound is also utilized in the production of acetate esters, chloral, and other aldehydes. Additionally, it finds applications in the pharmaceutical industry and as a reducing agent in various chemical processes.

How to handle acetaldehyde safely?

Acetaldehyde requires strict safety measures due to its extreme flammability and health hazards. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work in well-ventilated areas away from heat sources, sparks, and open flames. Use grounding and bonding procedures when transferring the liquid. Avoid skin and eye contact, and prevent inhalation of vapors due to carcinogenic properties.

How to store acetaldehyde correctly?

Acetaldehyde must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat, sparks, and ignition sources. Keep containers in a fireproof storage area with appropriate fire suppression systems. Store away from oxidizing agents, acids, bases, and incompatible materials. Maintain storage temperatures below 4°C when possible and ensure containers are properly grounded to prevent static electricity buildup.

What to do in case of contact with acetaldehyde?

Immediate action is required upon acetaldehyde contact. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately and seek medical help. For ingestion, do not induce vomiting and contact emergency services immediately.

How to dispose of acetaldehyde appropriately?

Acetaldehyde disposal must comply with local, national, and international waste regulations due to its hazardous classification. The substance should be collected in suitable containers and disposed of through licensed hazardous waste disposal facilities. Never pour down drains or release into the environment. Small quantities may be neutralized under controlled conditions by qualified personnel. Always consult local environmental authorities for specific disposal requirements and procedures.

How to transport acetaldehyde?

Acetaldehyde is classified under ADR Class 3 (Flammable Liquids), Packing Group I, indicating maximum transport danger level. It requires specialized packaging, labeling with appropriate hazard symbols, and transport by trained personnel with proper documentation. Vehicles must be equipped with appropriate safety equipment and emergency procedures. Transportation must comply with international dangerous goods regulations including proper segregation from incompatible substances.

Is acetaldehyde subject to specific regulations?

Acetaldehyde is subject to extensive regulation under multiple frameworks including REACH registration, CLP classification as carcinogenic (Category 1B) and mutagenic (Category 2). It requires safety data sheets and appropriate hazard communication. The substance faces restrictions in certain applications due to its health hazards and must comply with occupational exposure limits. Industrial users must implement risk management measures and report usage under chemical safety regulations.

Where to buy acetaldehyde in Europe?

Acetaldehyde is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide acetaldehyde with proper documentation, safety data sheets, and regulatory compliance support. Given the substance's hazardous classification, purchase is typically restricted to qualified industrial users with appropriate handling facilities and safety measures. Contact OYSI directly for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.