Acetic Acid

C2H4O2

acetic acid

CAS64-19-7
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
64-19-7
EC Number
200-580-7
UN Number
2789
Index Number
607-001-00-0
PubChem CID
176

Physical-chemical properties

Molecular Formula
C2H4O2
Molar Mass
60.05 g/mol
IUPAC Name
acetic acid

Chemical Identifiers

InChI
InChI=1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)
InChI Key
QTBSBXVTEAMEQO-UHFFFAOYSA-N

Overview

Acetic Acid (CAS 64-19-7) is a carboxylic acid with strong corrosive properties and characteristic pungent odor. This fundamental organic compound, systematically known as ethanoic acid, represents one of the most important carboxylic acids in industrial chemistry. With the molecular formula C2H4O2 and a molecular weight of 60.05 g/mol, acetic acid serves as a crucial building block in numerous chemical processes and manufacturing applications across diverse industries. The substance exhibits significant safety considerations due to its classification as a flammable liquid (Category 3) and skin corrosive material (Category 1A). The GHS02 and GHS05 pictograms indicate both fire and corrosion hazards, requiring careful handling protocols and appropriate personal protective equipment. Its ADR classification as Class 8 reflects its corrosive nature during transportation, necessitating specialized packaging and documentation procedures. Acetic acid demonstrates excellent solubility in water and most organic solvents, making it highly versatile for chemical synthesis and purification processes. Its acidic properties, with a pKa of approximately 4.76, position it as a moderately strong acid suitable for controlled chemical reactions. Unlike more complex amine compounds such as 2-(diethylamino)ethanol, acetic acid maintains stability under standard storage conditions while providing reliable reactivity profiles. Key industrial applications include vinyl acetate monomer production for polymer manufacturing, cellulose acetate synthesis for textiles and films, and pharmaceutical intermediate production. The compound also serves extensively in chemical purification processes and as a pH adjustment agent in various manufacturing operations. OYSI maintains reliable supply channels for technical-grade acetic acid, supporting European industrial customers with consistent quality and comprehensive technical documentation.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2789
ADR Class8
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEisessig, technisch rein, Konz. >= 99,7 %
Marine PollutantNo

Frequently Asked Questions

What is Acetic Acid?

Acetic acid is a colorless organic compound with the chemical formula C2H4O2 and molecular weight of 60.05 g/mol. It is a carboxylic acid characterized by its distinctive pungent, vinegar-like odor. Known for its corrosive properties, acetic acid is classified as a flammable liquid and skin corrosive substance. It occurs naturally in vinegar and is widely used in industrial applications as a chemical intermediate and solvent.

What are the physicochemical properties of Acetic Acid?

Acetic acid is a colorless liquid at room temperature with a characteristic sharp, pungent odor reminiscent of vinegar. It has a molecular formula C2H4O2 and molecular weight of 60.05 g/mol. The substance is highly soluble in water and miscible with most organic solvents. It has a boiling point of 118°C and freezing point of 16.6°C, making it liquid under normal conditions.

What is Acetic Acid used for?

Acetic acid serves multiple industrial and commercial purposes as a versatile chemical intermediate. It is primarily used in the production of vinyl acetate monomer, acetic anhydride, and cellulose acetate. The substance also functions as a solvent in chemical processes, a pH regulator in various applications, and a raw material for manufacturing plastics, textiles, and pharmaceuticals. Additionally, it finds use in food processing and preservation.

How to handle Acetic Acid safely?

Acetic acid requires careful handling due to its corrosive and flammable nature, as indicated by GHS pictograms GHS02 and GHS05. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation. Keep away from heat sources, sparks, and open flames due to its flammable properties (Flam. Liq. 3). Always handle with appropriate tools to prevent direct contact.

How to store Acetic Acid correctly?

Acetic acid must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Use corrosion-resistant containers made of suitable materials like stainless steel or certain plastics. Keep containers tightly sealed to prevent evaporation and contamination. Store away from strong bases, oxidizing agents, and metals that may react. Ensure storage areas are equipped with appropriate spill containment and fire suppression systems.

What to do in case of contact with Acetic Acid?

Immediate action is required due to acetic acid's skin corrosive properties (Skin Corr. 1A). For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. For eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek medical attention promptly. Always consult safety data sheets for complete emergency procedures.

How to dispose of Acetic Acid appropriately?

Acetic acid disposal must comply with local and national waste regulations as it is classified as hazardous waste. Small quantities can be neutralized carefully with appropriate bases under controlled conditions by trained personnel. Larger quantities require disposal through licensed hazardous waste contractors. Never dispose of acetic acid down drains or in regular waste streams. Contaminated materials and containers must also be treated as hazardous waste and disposed of accordingly.

How to transport Acetic Acid?

Acetic acid is regulated for transport under ADR classification as Class 8 (corrosive substance), Packing Group II. It requires appropriate UN-approved packaging and labeling with proper hazard markings. Transport documents must include the correct shipping name and UN number. Vehicles must carry appropriate emergency equipment and placards. Only trained and certified personnel should handle transportation, following all ADR regulations for corrosive substances.

Is Acetic Acid subject to specific regulations?

Acetic acid is subject to various European regulations including REACH registration requirements and CLP classification obligations. It is classified under GHS as Flam. Liq. 3 and Skin Corr. 1A, requiring appropriate labeling with danger signal word and pictograms GHS02 and GHS05. The substance is not listed as SVHC (Substance of Very High Concern). Users must comply with workplace safety regulations and provide appropriate safety data sheets to downstream users.

Where to buy Acetic Acid in Europe?

Acetic acid is available throughout Europe from specialized chemical distributors like OYSI, which supplies high-quality chemical products to industrial customers across European markets. When purchasing, ensure suppliers provide complete documentation including safety data sheets, certificates of analysis, and regulatory compliance information. Choose established distributors with proper handling capabilities and regulatory expertise to ensure product quality and safe delivery to your facility.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.