2-methylprop-2-enoic acid

C4H6O2

CAS79-41-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
79-41-4
EC Number
201-204-4
UN Number
2531
Index Number
607-088-00-5
PubChem CID
4093

Physical-chemical properties

Molecular Formula
C4H6O2
Molar Mass
86.09 g/mol
IUPAC Name
2-methylprop-2-enoic acid

Chemical Identifiers

InChI
InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6)
InChI Key
CERQOIWHTDAKMF-UHFFFAOYSA-N

Overview

2-methylprop-2-enoic acid (CAS 79-41-4) is an unsaturated carboxylic acid with reactive vinyl functionality and strong polymerization tendency. This organic compound, commonly known as methacrylic acid, represents a fundamental building block in polymer chemistry and industrial manufacturing. With its molecular formula C4H6O2 and molar mass of 86.09 g/mol, this alpha,beta-unsaturated carboxylic acid features both acidic and vinyl functionalities, making it highly versatile for chemical synthesis and polymerization reactions. The presence of a methyl group adjacent to the double bond significantly influences its reactivity compared to acrylic acid. The substance exhibits corrosive properties classified under GHS pictograms GHS05 and GHS07, with a danger signal word reflecting its Skin Corr. 1A classification and acute toxicity potential. As an ADR class 8 material, it requires careful handling protocols due to its corrosive nature and potential for severe skin and eye damage. The compound's tendency to undergo spontaneous polymerization, particularly under heat or in the presence of catalysts, necessitates appropriate storage conditions and stabilization measures. Primary industrial applications include the production of methacrylic acid esters, particularly methyl methacrylate for acrylic plastics and resins. It serves as a crucial monomer in manufacturing superabsorbent polymers, coatings, adhesives, and textile treatment agents. The chemical industry also utilizes this compound alongside substances like thionyl dichloride in various synthetic pathways for specialty chemical production. OYSI maintains reliable supplies of 2-methylprop-2-enoic acid with comprehensive technical documentation and safety data sheets to support European industrial customers' manufacturing requirements.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2531
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameMethacrylsäure, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is an organic compound with the molecular formula C4H6O2 and CAS number 79-41-4. Also known as methacrylic acid, it is an unsaturated carboxylic acid with a molecular weight of 86.09 g/mol. This colorless liquid is characterized by its acrylic odor and corrosive properties. It belongs to the family of α,β-unsaturated carboxylic acids and contains a vinyl group that makes it highly reactive for polymerization reactions.

What are the physicochemical properties of 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is a colorless to pale yellow liquid at room temperature with a characteristic pungent, acrid odor. It has a boiling point of approximately 163°C and a melting point of 16°C. The compound is highly soluble in water and most organic solvents including alcohols, ethers, and acetone. It exhibits corrosive properties due to its acidic nature and can undergo polymerization reactions, especially when exposed to heat, light, or in the presence of initiators.

What is 2-methylprop-2-enoic acid used for?

2-methylprop-2-enoic acid is primarily used as a monomer in the production of polymethyl methacrylate (PMMA) and other acrylic polymers. It serves as a key raw material in manufacturing acrylic resins, coatings, adhesives, and sealants. The compound is also utilized in the production of superabsorbent polymers, textile treatments, and as an intermediate in organic synthesis. Its reactive double bond makes it valuable for creating cross-linked polymer networks in various industrial applications.

How to handle 2-methylprop-2-enoic acid safely?

2-methylprop-2-enoic acid must be handled with extreme caution due to its corrosive and toxic properties. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shield, and acid-resistant clothing. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation exposure. Avoid contact with skin, eyes, and clothing. Use appropriate spill containment materials and ensure emergency eyewash stations and safety showers are readily accessible. Never work alone when handling this corrosive substance.

How to store 2-methylprop-2-enoic acid correctly?

2-methylprop-2-enoic acid should be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and ignition sources. Use corrosion-resistant containers with tight-fitting lids to prevent contamination and polymerization. Store separately from bases, oxidizing agents, and reducing agents to avoid dangerous reactions. Maintain storage temperature below 25°C and add appropriate inhibitors to prevent unwanted polymerization. Ensure storage areas have appropriate spill containment measures and are equipped with suitable fire suppression systems.

What to do in case of contact with 2-methylprop-2-enoic acid?

Immediate action is critical due to the corrosive nature of 2-methylprop-2-enoic acid. For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. For eye contact, rinse immediately with water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air and seek medical help if breathing difficulties occur. If ingested, do not induce vomiting; rinse mouth and seek immediate medical attention. Always consult a physician after any significant exposure.

How to dispose of 2-methylprop-2-enoic acid appropriately?

2-methylprop-2-enoic acid must be disposed of as hazardous waste in accordance with local, national, and EU regulations. Never discharge into sewers, waterways, or soil due to its corrosive and toxic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized carefully with appropriate bases under controlled conditions by trained personnel. Always consult current waste disposal regulations and safety data sheets before disposal. Maintain proper documentation for all waste disposal activities.

How to transport 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is classified as ADR Class 8 (corrosive substances), Packing Group II, indicating high corrosive hazard during transport. It must be packaged in UN-approved containers suitable for corrosive liquids and properly labeled with appropriate hazard placards. Transport vehicles must carry emergency response information and appropriate spill control materials. Drivers require ADR certification for hazardous materials transport. Ensure compliance with all applicable transport regulations including proper documentation, vehicle requirements, and route restrictions for corrosive materials.

Is 2-methylprop-2-enoic acid subject to particular regulations?

2-methylprop-2-enoic acid is subject to comprehensive EU chemical regulations including REACH registration requirements and CLP classification as Acute Tox. 4 and Skin Corr. 1A with danger signal word. It requires safety data sheets and appropriate hazard labeling with GHS07 and GHS05 pictograms. The substance is not currently listed as SVHC under REACH. Workplace exposure limits may apply, and specific industrial emission controls might be required. Companies must ensure compliance with occupational health regulations and environmental discharge limits.

Where to buy 2-methylprop-2-enoic acid in Europe?

2-methylprop-2-enoic acid is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality, appropriate packaging, and adherence to transport regulations. Their technical expertise helps customers with handling recommendations and regulatory requirements. Contact OYSI directly for availability, specifications, and delivery options throughout European markets for your methacrylic acid requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.