2-methylprop-2-enoic acid

C4H6O2

CAS79-41-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
79-41-4
EC Number
201-204-4
UN Number
2531
Index Number
607-088-00-5
PubChem CID
4093

Physical-chemical properties

Molecular Formula
C4H6O2
Molar Mass
86.09 g/mol
IUPAC Name
2-methylprop-2-enoic acid

Chemical Identifiers

InChI
InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6)
InChI Key
CERQOIWHTDAKMF-UHFFFAOYSA-N

Overview

2-methylprop-2-enoic acid (CAS 79-41-4) is an unsaturated carboxylic acid with reactive vinyl functionality and strong corrosive properties. This organic compound, commonly known in the chemical industry by its IUPAC designation, represents a critical building block in polymer chemistry and industrial manufacturing. With the molecular formula C4H6O2 and a molecular weight of 86.09 g/mol, this methyl-substituted acrylic acid derivative exhibits both the reactivity of an α,β-unsaturated system and the corrosive nature of carboxylic acids. The compound's structure features a terminal vinyl group adjacent to a carboxyl functionality, making it highly versatile for polymerization reactions and chemical modifications. The substance presents significant safety considerations, classified under GHS pictograms GHS05 and GHS07 with a "Danger" signal word. Its classification as Skin Corr. 1A and Acute Tox. 4 requires careful handling protocols and appropriate personal protective equipment. The ADR Class 8 designation reflects its corrosive transport requirements, necessitating specialized packaging and documentation for safe distribution. Industrial applications leverage the compound's dual functionality for acrylic polymer production, where it serves as a comonomer in various formulations. The chemical industry utilizes it extensively in adhesive systems, coating formulations, and specialty polymer synthesis. Unlike simpler reactive compounds such as thionyl dichloride, this methacrylic acid provides controlled polymerization characteristics while maintaining excellent adhesion properties in final applications. Manufacturing processes often integrate this compound with other reactive intermediates, including specialized amines like 2-(diethylamino)ethanol for pH adjustment and reaction control. Its compatibility with various chemical systems makes it valuable for custom formulation development. OYSI provides reliable access to high-quality 2-methylprop-2-enoic acid for European industrial customers, supporting diverse manufacturing requirements with comprehensive technical documentation and regulatory compliance.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2531
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameMethacrylsäure, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is an organic compound with the molecular formula C4H6O2 and CAS number 79-41-4. Also known as methacrylic acid, it is an unsaturated carboxylic acid with a molecular weight of 86.09 g/mol. This colorless liquid features a double bond in its structure, making it highly reactive for polymerization processes. It belongs to the acrylic acid family and is classified as a corrosive substance with acute toxicity properties, requiring careful handling in industrial applications.

What are the physicochemical properties of 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is a colorless to pale yellow liquid at room temperature with a characteristic pungent, acrid odor. The compound is highly soluble in water and most organic solvents due to its carboxylic acid functionality. It has a relatively low molecular weight of 86.09 g/mol and exhibits typical properties of unsaturated carboxylic acids. The presence of both a carboxyl group and a vinyl group makes it prone to polymerization, especially under heat or in the presence of initiators.

What is 2-methylprop-2-enoic acid used for?

2-methylprop-2-enoic acid is primarily used as a monomer in the production of polymethacrylic acid and its derivatives. It serves as a key raw material for manufacturing acrylic resins, coatings, adhesives, and sealants. The compound is essential in producing superabsorbent polymers, textile treatments, and water treatment chemicals. Additionally, it finds applications in the synthesis of various chemical intermediates and as a crosslinking agent in polymer chemistry, making it valuable across multiple industrial sectors.

How to handle 2-methylprop-2-enoic acid safely?

2-methylprop-2-enoic acid must be handled with extreme caution due to its corrosive nature and acute toxicity. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shields, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid direct skin and eye contact, and ensure emergency eyewash stations and safety showers are readily accessible. Handle containers carefully to prevent spills and always use appropriate tools for transfer operations.

How to store 2-methylprop-2-enoic acid correctly?

2-methylprop-2-enoic acid should be stored in tightly sealed containers made of compatible materials, away from heat sources, direct sunlight, and ignition sources. Storage areas must be cool, dry, and well-ventilated to prevent vapor accumulation. Keep the substance separated from strong oxidizing agents, bases, and polymerization initiators to avoid dangerous reactions. Containers should be properly labeled and stored in secondary containment systems to manage potential leaks. Regular inspection of storage containers is essential to detect any signs of deterioration or contamination.

What to do in case of contact with 2-methylprop-2-enoic acid?

Immediate action is crucial following contact with 2-methylprop-2-enoic acid due to its corrosive properties. For skin contact, remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air and seek medical attention. For ingestion, do not induce vomiting and seek immediate medical care. Always consult a physician after any significant exposure.

How to dispose of 2-methylprop-2-enoic acid appropriately?

2-methylprop-2-enoic acid must be disposed of in accordance with local, national, and international hazardous waste regulations. The substance cannot be discharged into sewers, soil, or water bodies due to its corrosive nature and environmental impact. Disposal should be carried out through licensed hazardous waste contractors who can properly neutralize or incinerate the material at authorized facilities. Small quantities may require neutralization under controlled conditions before disposal, but this should only be performed by trained professionals following established safety protocols.

How to transport 2-methylprop-2-enoic acid?

2-methylprop-2-enoic acid is classified under ADR Class 8 (corrosive substances), Packing Group II, indicating moderate danger level during transport. Packaging must comply with UN specifications for corrosive liquids, using appropriate containers that resist chemical attack. Transport vehicles must display proper hazard placards and carry emergency response information. Drivers require ADR training for handling corrosive materials, and transport documentation must include proper shipping names, hazard classes, and emergency contact information. Segregation from incompatible materials is mandatory during transport operations.

Is 2-methylprop-2-enoic acid subject to specific regulations?

2-methylprop-2-enoic acid is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification as a corrosive substance with acute toxicity. The compound is not currently listed as a Substance of Very High Concern (SVHC) but must comply with standard chemical safety assessments and supply chain communication requirements. Users must maintain safety data sheets, implement appropriate risk management measures, and ensure proper labeling with GHS pictograms GHS05 and GHS07, along with the danger signal word.

Where to buy 2-methylprop-2-enoic acid in Europe?

2-methylprop-2-enoic acid is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across the region. OYSI provides reliable supply chain solutions with proper documentation, safety data sheets, and regulatory compliance support for this corrosive chemical. As a specialized chemical distributor, OYSI ensures product quality, appropriate packaging, and professional handling throughout the supply process. Contact OYSI directly for specific availability, packaging options, and technical support for your 2-methylprop-2-enoic acid requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.