N'-(2-aminoethyl)ethane-1,2-diamine

C4H13N3

CAS111-40-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
111-40-0
EC Number
203-865-4
UN Number
2079
Index Number
612-058-00-X
PubChem CID
8111

Physical-chemical properties

Molecular Formula
C4H13N3
Molar Mass
103.17 g/mol
IUPAC Name
N'-(2-aminoethyl)ethane-1,2-diamine

Chemical Identifiers

InChI
InChI=1S/C4H13N3/c5-1-3-7-4-2-6/h7H,1-6H2
InChI Key
RPNUMPOLZDHAAY-UHFFFAOYSA-N

Overview

N'-(2-aminoethyl)ethane-1,2-diamine (CAS 111-40-0) is a triamine compound with strong alkaline properties and excellent chelating capabilities. This linear triamine, also known as diethylenetriamine (DETA), represents a crucial building block in industrial chemistry with its three primary amino groups providing exceptional reactivity and versatility. With the molecular formula C4H13N3 and a molecular weight of 103.17 g/mol, this compound exhibits highly basic characteristics due to its multiple amine functionalities, making it an invaluable intermediate for numerous chemical processes. The substance appears as a colorless to pale yellow liquid with a characteristic ammonia-like odor. Its strong alkaline nature and corrosive properties require careful handling, as indicated by its GHS05 and GHS07 pictogrammes and "Danger" signal word. The compound is classified as Skin Corr. 1B and Skin Sens. 1, necessitating appropriate personal protective equipment during handling and storage. Transportation falls under ADR Class 8, reflecting its corrosive nature. N'-(2-aminoethyl)ethane-1,2-diamine finds extensive application as a curing agent for epoxy resins, where its multiple amino groups create robust cross-linked networks essential for high-performance coatings and adhesives. The compound also serves as a key intermediate in the production of chelating agents and corrosion inhibitors, leveraging its ability to form stable complexes with metal ions. Additionally, it functions as a building block for polyamide synthesis and various specialty chemicals. Unlike simpler amines such as phenylmethanamine, this triamine offers superior chelating properties due to its multiple coordination sites. OYSI maintains reliable supply chains for N'-(2-aminoethyl)ethane-1,2-diamine to support diverse industrial applications across Europe.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2079
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameDiethylentriamin
Marine PollutantNo

Frequently Asked Questions

What is N'-(2-aminoethyl)ethane-1,2-diamine?

N'-(2-aminoethyl)ethane-1,2-diamine is a linear triamine organic compound with the molecular formula C4H13N3 and CAS number 111-40-0. This chemical features three amino groups connected by ethylene bridges, making it a versatile building block in chemical synthesis. With a molecular weight of 103.17 g/mol, it serves as an important intermediate in various industrial applications and chemical processes.

What are the physicochemical properties of N'-(2-aminoethyl)ethane-1,2-diamine?

N'-(2-aminoethyl)ethane-1,2-diamine is typically a colorless to pale yellow liquid at room temperature with a characteristic amine odor. The compound is highly soluble in water and polar solvents due to its multiple amino groups, which can form hydrogen bonds. It exhibits basic properties due to the presence of three amine functional groups and has a tendency to absorb moisture from air.

What is N'-(2-aminoethyl)ethane-1,2-diamine used for?

N'-(2-aminoethyl)ethane-1,2-diamine serves as a crucial intermediate in the production of chelating agents, corrosion inhibitors, and fuel additives. It is widely used in the synthesis of epoxy curing agents, polyamide resins, and as a building block for pharmaceuticals. The compound also finds applications in water treatment chemicals, textile auxiliaries, and as a cross-linking agent in polymer chemistry.

How to handle N'-(2-aminoethyl)ethane-1,2-diamine safely?

N'-(2-aminoethyl)ethane-1,2-diamine requires careful handling due to its corrosive and sensitizing properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent inhalation exposure. Avoid skin and eye contact as the substance is classified as Skin Corr. 1B and may cause severe burns and allergic reactions.

How to store N'-(2-aminoethyl)ethane-1,2-diamine correctly?

N'-(2-aminoethyl)ethane-1,2-diamine should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep away from oxidizing agents and acids to prevent dangerous reactions. Store in original containers made of compatible materials and ensure proper labeling. Maintain storage temperature below 25°C and protect from moisture to prevent degradation.

What to do in case of contact with N'-(2-aminoethyl)ethane-1,2-diamine?

N'-(2-aminoethyl)ethane-1,2-diamine contact requires immediate action due to its corrosive nature. For skin contact, immediately flush with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical help immediately.

How to dispose of N'-(2-aminoethyl)ethane-1,2-diamine properly?

N'-(2-aminoethyl)ethane-1,2-diamine disposal must comply with local and national hazardous waste regulations due to its classification as a corrosive substance. The compound should be collected in appropriate containers and disposed of through licensed waste management companies. Never discharge into sewers, water bodies, or soil. Consider neutralization or incineration at authorized facilities as appropriate disposal methods following regulatory guidelines.

How to transport N'-(2-aminoethyl)ethane-1,2-diamine?

N'-(2-aminoethyl)ethane-1,2-diamine is classified under ADR Class 8 (corrosive substances) Packing Group II for transportation purposes. The substance must be packaged in UN-approved containers with appropriate hazard labels and documentation. Transport vehicles must comply with ADR requirements including proper placarding, emergency equipment, and driver certification. Ensure proper segregation from incompatible materials during transport.

Is N'-(2-aminoethyl)ethane-1,2-diamine subject to specific regulations?

N'-(2-aminoethyl)ethane-1,2-diamine is subject to REACH regulation requiring registration for manufacture or import above specified tonnages in the EU. The substance must be classified and labeled according to CLP regulation with appropriate hazard statements and precautionary measures. While not currently listed as a SVHC, it requires compliance with occupational safety regulations and may be subject to national restrictions for specific uses.

Where to buy N'-(2-aminoethyl)ethane-1,2-diamine in Europe?

N'-(2-aminoethyl)ethane-1,2-diamine is available through OYSI, a trusted European distributor of specialty chemicals. OYSI provides reliable supply chains across Europe with proper documentation, quality assurance, and regulatory compliance. As experienced chemical distributors, OYSI ensures proper packaging, labeling, and transportation according to European standards while offering technical support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.