2-methylbuta-1,3-diene

C5H8

CAS78-79-5
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
78-79-5
EC Number
201-143-3
UN Number
1218
Index Number
601-014-00-5
PubChem CID
6557

Physical-chemical properties

Molecular Formula
C5H8
Molar Mass
68.12 g/mol
IUPAC Name
2-methylbuta-1,3-diene

Chemical Identifiers

InChI
InChI=1S/C5H8/c1-4-5(2)3/h4H,1-2H2,3H3
InChI Key
RRHGJUQNOFWUDK-UHFFFAOYSA-N

Overview

2-methylbuta-1,3-diene (CAS 78-79-5) is a conjugated diene hydrocarbon with high flammability and significant industrial polymerization applications. This organic compound, also known by its IUPAC designation 2-methylbuta-1,3-diene, represents a critical building block in synthetic rubber and polymer chemistry. With the molecular formula C5H8 and a molecular weight of 68.12 g/mol, this colorless liquid exhibits the characteristic properties of conjugated dienes, featuring two carbon-carbon double bonds in alternating positions that provide enhanced reactivity for polymerization processes. The substance's chemical structure makes it particularly valuable in industrial applications, though it requires careful handling due to its classification under multiple hazard categories. As a Flammable Liquid Category 1 with GHS02 and GHS08 pictograms, 2-methylbuta-1,3-diene demands stringent safety protocols during storage, transportation, and processing. Its ADR Class 3 classification reflects its significant fire hazard, while its carcinogenic (Category 1B) and mutagenic (Category 2) properties necessitate appropriate occupational exposure controls. In industrial applications, 2-methylbuta-1,3-diene serves primarily as a monomer in synthetic rubber production, particularly in the manufacture of specialty elastomers and copolymers. The compound finds extensive use in the production of adhesives, sealants, and various polymer formulations where its conjugated diene structure provides enhanced cross-linking capabilities. Similar to other industrial monomers like styrene, it plays a crucial role in developing materials with specific mechanical and chemical properties. The substance also contributes to the production of thermoplastic elastomers and serves as an intermediate in various chemical synthesis processes, making it indispensable for manufacturers requiring high-performance polymer solutions. OYSI provides reliable access to 2-methylbuta-1,3-diene for qualified industrial customers across Europe, ensuring consistent quality and comprehensive technical support for specialized chemical applications.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Carc. 1B; Muta. 2; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H350

May cause cancer.

H341

Suspected of causing genetic defects.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1218
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameIsopren, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-methylbuta-1,3-diene?

2-methylbuta-1,3-diene is an organic compound with the molecular formula C5H8 and CAS number 78-79-5. This conjugated diene has a molecular weight of 68.12 g/mol and belongs to the family of unsaturated hydrocarbons. It features two double bonds in conjugation with a methyl substituent, making it highly reactive and useful in polymer chemistry. The compound is classified as extremely flammable and potentially carcinogenic, requiring careful handling in industrial applications.

What are the physicochemical properties of 2-methylbuta-1,3-diene?

2-methylbuta-1,3-diene is a volatile liquid at room temperature with characteristic properties typical of conjugated dienes. As a C5H8 hydrocarbon, it exhibits low water solubility but good solubility in organic solvents. The compound is highly flammable due to its unsaturated structure and low flash point. Its conjugated diene system makes it prone to polymerization and oxidation reactions. The substance requires storage under inert atmosphere to prevent unwanted reactions.

What is 2-methylbuta-1,3-diene used for?

2-methylbuta-1,3-diene serves primarily as a monomer in synthetic rubber production and polymer manufacturing. It is extensively used in the production of synthetic elastomers and specialty polymers through polymerization reactions. The compound finds applications in adhesive formulations, sealants, and as an intermediate in organic synthesis. Its conjugated diene structure makes it valuable for Diels-Alder reactions and other chemical transformations in fine chemical manufacturing and research applications.

How to handle 2-methylbuta-1,3-diene safely?

2-methylbuta-1,3-diene requires strict safety measures due to its extreme flammability and carcinogenic properties. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas away from ignition sources. Grounding and bonding of equipment is essential to prevent static discharge. Emergency shower and eyewash stations must be readily accessible, and only trained personnel should handle this substance.

How to store 2-methylbuta-1,3-diene correctly?

2-methylbuta-1,3-diene must be stored in a cool, dry, well-ventilated area away from heat, sparks, and open flames. Storage containers should be made of compatible materials and kept tightly sealed under inert atmosphere to prevent polymerization. The storage area must be equipped with appropriate fire suppression systems and maintained below recommended temperature limits. Incompatible materials such as strong oxidizers, acids, and peroxides must be stored separately to prevent dangerous reactions.

What to do in case of contact with 2-methylbuta-1,3-diene?

Immediate action is required upon contact with 2-methylbuta-1,3-diene due to its hazardous nature. For skin contact, remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately and seek medical care. For ingestion, do not induce vomiting and seek immediate medical attention while providing safety data sheet information.

How to dispose of 2-methylbuta-1,3-diene appropriately?

2-methylbuta-1,3-diene disposal must comply with local, national, and international hazardous waste regulations due to its carcinogenic and flammable properties. The substance should never be discharged into drains, water courses, or soil. Disposal must be carried out by licensed hazardous waste contractors through approved methods such as controlled incineration at high temperatures. Empty containers may also require special disposal as hazardous waste. Consult local environmental authorities for specific disposal requirements.

How to transport 2-methylbuta-1,3-diene?

2-methylbuta-1,3-diene is classified as ADR Class 3 (Flammable Liquids), Packing Group I, indicating the highest level of danger for flammable liquids. Transportation requires UN-approved packaging and proper hazard labeling including flammable and health hazard pictograms. Drivers must hold ADR certification for dangerous goods transport. Vehicles must be equipped with appropriate safety equipment and emergency procedures. Shipping documentation must include proper shipping names, hazard classes, and emergency contact information.

Is 2-methylbuta-1,3-diene subject to specific regulations?

2-methylbuta-1,3-diene is subject to extensive regulations under REACH and CLP regulations in Europe due to its carcinogenic and mutagenic properties. The substance requires safety data sheets and hazard classification with appropriate GHS pictograms (GHS02, GHS08). While not currently listed as a Substance of Very High Concern (SVHC), its Carc. 1B and Muta. 2 classifications mandate strict handling protocols. Users must comply with occupational exposure limits and implement risk management measures.

Where to buy 2-methylbuta-1,3-diene in Europe?

2-methylbuta-1,3-diene is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this regulated substance to qualified industrial customers with proper safety documentation and regulatory compliance support. Due to the hazardous nature of this compound, purchases require verification of intended use and appropriate handling capabilities. Contact OYSI directly for availability, technical specifications, and regulatory guidance for your specific application requirements in the European market.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.